This article presents a sensor for detecting the distribution of forces on a surface. The device with nine buttons consisted of an elastomer-based layer as a touch interface resting on a substrate of patterned metallized paper. The elastomer-based layer included a three-by-three array of deformable, hemispherical elements/reliefs, facing down toward an array of interdigitated capacitive sensing units on patterned metallized paper. Each hemispherical element is 20 mm in diameter and 8 mm in height. When a user applied pressure to the elastomer-based layer, the contact area between the hemispherical elements and the interdigitated capacitive sensing units increased with the deformation of the hemispherical elements. To enhance the sensitivity of the sensors, embedded particles of hydrogel in the elastomer-based layer increased the measured electrical responses. The measured capacitance increased because the effective dielectric permittivity of the hydrogel was greater than that of air. Electromechanical characterization verified that the hydrogel-filled elastomer was more sensitive to force at a low range of loads (23.4 pF/N) than elastomer alone without embedded hydrogel (3.4 pF/N), as the hydrogel reduced the effective elastic modulus of the composite material by a factor of seven. A simple demonstration suggests that the force-sensing array has the potential to contribute to wearable and soft robotic devices.
more »
« less
Paper-Based Supercapacitive Mechanical Sensors
Paper has been pursued as an interesting substrate material for sensors in applications such as microfuidics, bio-sensing of analytes and printed microelectronics. It offers advantages of being inexpensive, lightweight, environmentally friendly and easy to use. However, currently available paper-based mechanical sensors suffer from inadequate range and accuracy. Here, using the principle of supercapacitive sensing, we fabricate force sensors from paper with ultra-high sensitivity and unprecedented configurability. The high sensitivity comes from the sensitive dependence of a supercapacitor’s response on the contact area between a deformable electrolyte and a pair of electrodes. As a key component, we develop highly deformable electrolytes by coating ionic gel on paper substrates which can be cut and shaped into complex three-dimensional geometries. Paper dissolves in the ionic gel after determining the shape of the electrolytes, leaving behind transparent electrolytes with micro-structured fissures responsible for their high deformability. Exploiting this simple paper-based fabrication process, we construct diverse sensors of different configurations that can measure not just force but also its normal and shear components. The new sensors have range and sensitivity several orders of magnitude higher than traditional MEMS capacitive sensors, in spite of their being easily fabricated from paper with no cleanroom facilities.
more »
« less
- Award ID(s):
- 1830958
- PAR ID:
- 10113491
- Date Published:
- Journal Name:
- Scientific reports
- Volume:
- 8
- Issue:
- 16284
- ISSN:
- 2045-2322
- Page Range / eLocation ID:
- 1-10
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
In this paper, we report the development of tailored 3D-structured (engineered) polymer-metal interfaces to create enhanced ‘engineered ionic polymer metal composite’ (eIPMC) sensors towards soft, self-powered, high sensitivity strain sensor applications. We introduce a novel advanced additive manufacturing approach to tailor the morphology of the polymer-electrode interfaces via inkjet-printed polymer microscale features. We hypothesize that these features can promote inhomogeneous strain within the material upon the application of external pressure, responsible for improved compression sensing performance. We formalize a minimal physics-based chemoelectromechanical model to predict the linear sensor behavior of eIPMCs in both open-circuit and short-circuit sensing conditions. The model accounts for polymer-electrode interfacial topography to define the inhomogeneous mechanical response driving electrochemical transport in the eIPMC. Electrochemical experiments demonstrate improved electrochemical properties of the inkjet-printed eIPMCs as compared to the standard IPMC sensors fabricated from Nafion polymer sheets. Similarly, compression sensing results show a significant increase in sensing performance of inkjet-printed eIPMC. We also introduce two alternative methods of eIPMC fabrication for sub-millimeter features, namely filament-based fused-deposition manufacturing and stencil printing, and experimentally demonstrate their improved sensing performance. Our results demonstrate increasing voltage output associated to increasing applied mechanical pressure and enhanced performance of the proposed eIPMC sensors against traditional IPMC based compression sensors.more » « less
-
In this paper, we report the development of tailored 3D-structured (engineered) polymer-metal interfaces to create enhanced 'engineered ionic polymer metal composite' (eIPMC) sensors towards soft, self-powered, high sensitivity strain sensor applications. We introduce a novel advanced additive manufacturing approach to tailor the morphology of the polymer-electrode interfaces via inkjet-printed polymer microscale features. We hypothesize that these features can promote inhomogeneous strain within the material upon the application of external pressure, responsible for improved compression sensing performance. We formalize a minimal physics-based chemoelectromechanical model to predict the linear sensor behavior of eIPMCs in both open-circuit and short-circuit sensing conditions. The model accounts for polymer-electrode interfacial topography to define the inhomogeneous mechanical response driving electrochemical transport in the eIPMC. Electrochemical experiments demonstrate improved electrochemical properties of the inkjet-printed eIPMCs as compared to the standard IPMC sensors fabricated from Nafion polymer sheets. Similarly, compression sensing results show a significant increase in sensing performance of inkjet-printed eIPMC. We also introduce two alternative methods of eIPMC fabrication for sub-millimeter features, namely filament-based fused-deposition manufacturing and stencil printing, and experimentally demonstrate their improved sensing performance. Our results demonstrate increasing voltage output associated to increasing applied mechanical pressure and enhanced performance of the proposed eIPMC sensors against traditional IPMC based compression sensors.more » « less
-
Abstract Atmospheric NO2is of great concern due to its adverse effects on human health and the environment, motivating research on NO2detection and remediation. Existing low-cost room-temperature NO2sensors often suffer from low sensitivity at the ppb level or long recovery times, reflecting the trade-off between sensor response and recovery time. Here, we report an atomically dispersed metal ion strategy to address it. We discover that bimetallic PbCdSe quantum dot (QD) gels containing atomically dispersed Pb ionic sites achieve the optimal combination of strong sensor response and fast recovery, leading to a high-performance room-temperature p-type semiconductor NO2sensor as characterized by a combination of ultra–low limit of detection, high sensitivity and stability, fast response and recovery. With the help of theoretical calculations, we reveal the high performance of the PbCdSe QD gel arises from the unique tuning effects of Pb ionic sites on NO2binding at their neighboring Cd sites.more » « less
-
A stretchable pressure sensor is a necessary tool for perceiving physical interactions that take place on soft/deformable skins present in human bodies, prosthetic limbs, or soft robots. However, all existing types of stretchable pressure sensors have an inherent limitation, which is the interference of stretching with pressure sensing accuracy. Here, we present a design for a highly stretchable and highly sensitive pressure sensor that can provide unaltered sensing performance under stretching, which is realized through the synergistic creations of an ionic capacitive sensing mechanism and a mechanically hierarchical microstructure. Via this optimized structure, our sensor exhibits 98% strain insensitivity up to 50% strain and a low pressure detection limit of 0.2 Pa. With the capability to provide all the desired characteristics for quantitative pressure sensing on a deformable surface, this sensor has been used to realize the accurate sensation of physical interactions on human or soft robotic skin.more » « less
An official website of the United States government

