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1. Crystal structures of [Cu(phen)(H 2 O) 3 ( M F 6 )]·H 2 O ( M = Ti, Zr, Hf) and [Cu(phen)(H 2 O) 2 F] 2 [HfF 6 ]·H 2 O

   https://doi.org/10.1107/S2056989021000645  

   Nisbet, Matthew L. ; Poeppelmeier, Kenneth R. ( February 2021 , Acta Crystallographica Section E Crystallographic Communications)

   The crystal structures of three bridged bimetallic molecular compounds, namely, triaqua-2κ 3 O -μ-fluorido-pentafluorido-1κ 5 F -(1,10-phenanthroline-2κ 2 N , N ′)copper(II)titanium(IV) monohydrate, [Cu(TiF 6 )(phen)(H 2 O) 3 ]·H 2 O (phen is 1,10-phenanthroline, C 12 H 8 N 2 ), (I), triaqua-2κ 3 O -μ-fluorido-pentafluorido-1κ 5 F -(1,10-phenanthroline-2κ 2 N , N ′)copper(II)zirconium(IV) monohydrate, [Cu(ZrF 6 )(phen)(H 2 O) 3 ]·H 2 O, (II), and triaqua-2κ 3 O -μ-fluorido-pentafluorido-1κ 5 F -(1,10-phenanthroline-2κ 2 N , N ′)copper(II)hafnium(IV) monohydrate, [Cu(HfF 6 )(phen)(H 2 O) 3 ]·H 2 O, (III), and one molecular salt, bis[diaquafluorido(1,10-phenanthroline-κ 2 N , N ′)copper(II)] hexafluoridohafnate(IV) dihydrate, [CuF(phen)(H 2 O) 2 ] 2 [HfF 6 ]·2H 2 O, (IV), are reported. The bridged bimetallic compounds adopt Λ-shaped configurations, with the octahedrally coordinated copper(II) center linked to the fluorinated early transition metal via a fluoride linkage. The extended structures of these Λ-shaped compounds are organized through both intra- and intermolecular hydrogen bonds and intermolecular π–π stacking. The salt compound [Cu(phen)(H 2 O) 2 F] 2 [HfF 6 ]·H 2 O displays an isolated square-pyramidal Cu(phen)(H 2 O) 2 F + complex linked to other cationic complexes and isolated HfF 6 2− anions through intermolecular hydrogen-bonding interactions.
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   https://doi.org/10.1002/chem.201700049  

   Yamada, Michio ; Abe, Tsuneyuki ; Saito, Chiharu ; Yamazaki, Toshiki ; Sato, Satoru ; Mizorogi, Naomi ; Slanina, Zdenek ; Uhlík, Filip ; Suzuki, Mitsuaki ; Maeda, Yutaka ; et al ( May 2017 , Chemistry - A European Journal)
5. A Shock-Tube Study of the Rate Constant of PH ₃ + M ⇄ PH ₂ + H + M (M = Ar) Using PH ₃ Laser Absorption

   https://doi.org/10.1021/acs.jpca.0c04917  

   Mulvihill, Clayton R. ; Juárez, Raquel ; Mathieu, Olivier ; Petersen, Eric L. ( September 2020 , The Journal of Physical Chemistry A)