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Abstract. Measurements of multiple cosmogenic nuclides in a single sample are valuable for various applications of cosmogenic nuclide exposure dating and allow for correcting exposure ages for surface weathering and erosion and establishing exposure–burial history. Here we provide advances in the measurement of cosmogenic 10Be in pyroxene and constraints on the production rate that provide new opportunities for measurements of multi-nuclide systems, such as 10Be/3He, in pyroxene-bearing samples. We extracted and measured cosmogenic 10Be in pyroxene from two sets of Ferrar Dolerite samples collected from the Transantarctic Mountains in Antarctica. One set of samples has 10Be concentrations close to saturation, which allows for the production rate calibration of 10Be in pyroxene by assuming production–decay equilibrium. The other set of samples, which has a more recent exposure history, is used to determine if a rapid fusion method can be successfully applied to samples with Holocene to Last Glacial Maximum exposure ages. From measured 10Be concentrations in the near-saturation sample set we find the production rate of 10Be in pyroxene to be 3.74 ± 0.10 atoms g−1 yr−1, which is consistent with 10Be/3He paired nuclide ratios from samples assumed to have simple exposure. Given the high 10Be concentration measured in this sample set, a sample mass of ∼ 0.5 g of pyroxene is sufficient for the extraction of cosmogenic 10Be from pyroxene using a rapid fusion method. However, for the set of samples that have low 10Be concentrations, measured concentrations were higher than expected. We attribute spuriously high 10Be concentrations to failure in removing all meteoric 10Be and/or a highly variable and poorly quantified procedural blank background correction.
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Cosmogenic 3He production rate in ilmenite and the redistribution of spallation 3He in fine-grained minerals
Cosmogenic nuclide surface exposure dating and erosion rate measurements in basaltic landscapes rely primarily on measurement of 3He in olivine or pyroxene. However, geochemical investigations using 3He have been impossible in the substantial fraction of basalts that lack separable olivine or pyroxene crystals, or where such crystals were present, but have been chemically weathered. Fine-textured basalts often contain small grains of ilmenite, a weathering-resistant mineral that is a target for cosmogenic 3He production with good He retention and straightforward mineral separation, but with a poorly constrained production rate. Here we empirically calibrate the cosmogenic 3He production rate in ilmenite by measuring 3He concentrations in basalts with fine-grained (~20 lm cross-section) ilmenite and co-existing pyroxene or olivine from the Columbia River and Snake River Plain basalt provinces in the western United States. The concentration ratio of ilmenite to pyroxene and olivine is 0.78 ± 0.02, yielding an apparent cosmogenic 3He production rate of 93.6 ± 7.7 atom g-1 yr-1 that is 20–30% greater than expected from prior theoretical and empirical estimates for compositionally similar minerals. The production rate discrepancy arises from the high energy with which cosmic ray spallation reactions emit tritium and 3He and the associated long stopping distances that cause them to redistribute within a rock. Fine-grained phases with low cosmogenic 3He production rates, like ilmenite, will have anomalously high production rates owing to net implantation of 3He from the surrounding, higher 3He production rate, matrix. Semi-quantitative modeling indicates implantation of spallation 3He increases with decreasing ilmenite grain size, leading to production rates that exceed those in a large grain by ~10% when grain radii are <150 lm. The modeling predicts that for the ilmenite grain size in our samples, implantation causes production rates to be ~20% greater than expected for a large grain, and within uncertainty resolves the discrepancy between our calibrated production rate, theory, and rates from previous work. The redistribution effect is maximized when the host rock and crystals differ substantially in mean atomic number, as they do between whole-rock basalt and ilmenite.
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- Award ID(s):
- 1529528
- PAR ID:
- 10120685
- Date Published:
- Journal Name:
- Geochimica et cosmochimica acta
- Volume:
- 265
- ISSN:
- 0016-7037
- Page Range / eLocation ID:
- 19-31
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/https://doi.org/10.1016/j.gca.2019.08.025
