Abstract. To understand the erosivity of the eastern portion of the Laurentide Ice Sheet and the isotopic characteristics of the sediment it transported, we sampled buried sand from deglacial features (eskers and deltas) across eastern Canada (n = 10), a landscape repeatedly covered by the Quebec-Labrador Ice Dome. We measured concentrations of 10Be and 26Al in quartz isolated from the sediment and, after correcting for sub-surface cosmic-ray exposure after Holocene deglaciation, used these results to determine nuclide concentrations at the time the ice sheet deposited the sediment. To determine what percentage of sediment moving through streams and rivers currently draining the field area was derived from incision of thick glacial deposits as opposed to surface erosion, we used 10Be and 26Al as tracers by collecting and analyzing modern river sand sourced from Holocene-exposed landscapes (n = 11). We find that all ten deglacial sediment samples contain measurable concentrations of 10Be and 26Al equivalent on average to several thousand years of surface exposure – after correction, based on sampling depth, for Holocene nuclide production after deposition. Error-weighted averages (1 standard deviation errors) of measured 26Al/10Be ratios for both corrected deglacial (6.1 ± 1.2) and modern sediment samples (6.6 ± 0.5) are slightly lower than the production ratio at high latitudes (7.3 ± 0.3) implying burial and preferential decay of 26Al, the shorter-lived nuclide. However, five deglacial samples collected closer to the center of the former Quebec-Labrador Ice Dome have much lower corrected 26Al/10Be ratios (5.2 ± 0.8) than five samples collected closer to the former ice margins (7.0 ± 0.7). Modern river sand contains on average about 1.75 times the concentration of both nuclides compared to deglacial sediment corrected for Holocene exposure. The ubiquitous presence of 10Be and 26Al in eastern Quebec deglacial sediment is consistent with many older-than-expected exposure ages, reported here and by others, for bedrock outcrops and boulders once covered by the Quebec-Labrador Ice Dome. Together, these data suggest that glacial erosion and sediment transport in eastern Canada were insufficient to remove material containing cosmogenic nuclides produced during prior interglacial periods both from at least some bedrock outcrops and from all glacially transported sediment we sampled. Near the center of the Quebec-Labrador Ice Dome, ratios of 26Al/10Be are below those characteristic of surface production at high latitude. This suggests burial of the glacially transported sediment for at least many hundreds of thousands of years and the possibility that ice at the center of the Quebec-Labrador Ice Dome survived many interglacials when more distal ice melted away.
more »
« less
This content will become publicly available on August 15, 2025
Production rate calibration for cosmogenic 10 Be in pyroxene by applying a rapid fusion method to 10 Be-saturated samples from the Transantarctic Mountains, Antarctica
Abstract. Measurements of multiple cosmogenic nuclides in a single sample are valuable for various applications of cosmogenic nuclide exposure dating and allow for correcting exposure ages for surface weathering and erosion and establishing exposure–burial history. Here we provide advances in the measurement of cosmogenic 10Be in pyroxene and constraints on the production rate that provide new opportunities for measurements of multi-nuclide systems, such as 10Be/3He, in pyroxene-bearing samples. We extracted and measured cosmogenic 10Be in pyroxene from two sets of Ferrar Dolerite samples collected from the Transantarctic Mountains in Antarctica. One set of samples has 10Be concentrations close to saturation, which allows for the production rate calibration of 10Be in pyroxene by assuming production–decay equilibrium. The other set of samples, which has a more recent exposure history, is used to determine if a rapid fusion method can be successfully applied to samples with Holocene to Last Glacial Maximum exposure ages. From measured 10Be concentrations in the near-saturation sample set we find the production rate of 10Be in pyroxene to be 3.74 ± 0.10 atoms g−1 yr−1, which is consistent with 10Be/3He paired nuclide ratios from samples assumed to have simple exposure. Given the high 10Be concentration measured in this sample set, a sample mass of ∼ 0.5 g of pyroxene is sufficient for the extraction of cosmogenic 10Be from pyroxene using a rapid fusion method. However, for the set of samples that have low 10Be concentrations, measured concentrations were higher than expected. We attribute spuriously high 10Be concentrations to failure in removing all meteoric 10Be and/or a highly variable and poorly quantified procedural blank background correction.
more »
« less
- PAR ID:
- 10575039
- Publisher / Repository:
- Copernicus Publications
- Date Published:
- Journal Name:
- Geochronology
- Volume:
- 6
- Issue:
- 3
- ISSN:
- 2628-3719
- Page Range / eLocation ID:
- 491 to 502
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
Cosmogenic nuclide surface exposure dating and erosion rate measurements in basaltic landscapes rely primarily on measurement of 3He in olivine or pyroxene. However, geochemical investigations using 3He have been impossible in the substantial fraction of basalts that lack separable olivine or pyroxene crystals, or where such crystals were present, but have been chemically weathered. Fine-textured basalts often contain small grains of ilmenite, a weathering-resistant mineral that is a target for cosmogenic 3He production with good He retention and straightforward mineral separation, but with a poorly constrained production rate. Here we empirically calibrate the cosmogenic 3He production rate in ilmenite by measuring 3He concentrations in basalts with fine-grained (~20 lm cross-section) ilmenite and co-existing pyroxene or olivine from the Columbia River and Snake River Plain basalt provinces in the western United States. The concentration ratio of ilmenite to pyroxene and olivine is 0.78 ± 0.02, yielding an apparent cosmogenic 3He production rate of 93.6 ± 7.7 atom g-1 yr-1 that is 20–30% greater than expected from prior theoretical and empirical estimates for compositionally similar minerals. The production rate discrepancy arises from the high energy with which cosmic ray spallation reactions emit tritium and 3He and the associated long stopping distances that cause them to redistribute within a rock. Fine-grained phases with low cosmogenic 3He production rates, like ilmenite, will have anomalously high production rates owing to net implantation of 3He from the surrounding, higher 3He production rate, matrix. Semi-quantitative modeling indicates implantation of spallation 3He increases with decreasing ilmenite grain size, leading to production rates that exceed those in a large grain by ~10% when grain radii are <150 lm. The modeling predicts that for the ilmenite grain size in our samples, implantation causes production rates to be ~20% greater than expected for a large grain, and within uncertainty resolves the discrepancy between our calibrated production rate, theory, and rates from previous work. The redistribution effect is maximized when the host rock and crystals differ substantially in mean atomic number, as they do between whole-rock basalt and ilmenite.more » « less
-
Abstract. Since the 1990s, analysis of cosmogenic nuclides, primarily 10Be, in quartz-bearing river sand, has allowed for quantitative determination of erosion rates at a basin scale. Paired measurements of in situ cosmogenic 26Al and 10Be in sediment are less common but offers insight into the history of riverine sediment moving down slopes and through drainage basins. Prolonged sediment burial (>105 years), a violation of assumptions underlying erosion rate calculations, is indicated by higher 26Al-based than 10Be-based erosion rates due to preferential loss of shorter-lived 26Al by decay when quartz is shielded from cosmic rays. Here, we use a global compilation of 26Al and 10Be data generated from quartz-bearing fluvial sediment samples (n = 624, including 121 new measurements) and calculate the discordance between erosion rates derived from each nuclide. We test for correlations between such discordance and topographic metrics for drainage basins, allowing us to infer the likelihood of sediment burial during transport in different geomorphic settings. We find that nearly half of samples (n = 276) exhibit discordance (> 1σ uncertainty) between erosion rates derived from 10Be and 26Al, indicating sediment histories that must include extended burial during residence on hillslopes and/or in the fluvial system after or during initial near-surface exposure. Physical basin parameters such as basin area, slope, and tectonic activity exhibit significant correlation with erosion rate discordance whereas climatic parameters have little correlation. Our analysis suggests that 26Al/10Be erosion rate discordance occurs more regularly in basins larger than 1,000 km2, particularly when such basins have low average slopes and are in tectonically quiescent terrains. Sediment sourced from smaller, steeper basins in tectonically active regions is more likely to have similar 10Be and 26Al erosion rates indicative of limited storage and limited burial during residence in the hillslope and fluvial sediment system. The data and analysis we present demonstrate that paired 26Al and 10Be analyses in detrital fluvial samples can provide a window into watershed processes, elucidating landscape behavior at different spatial scales and allowing a deeper understanding of both sediment routing systems and whether erosion rate assumptions are violated. Large lowland basins are more likely to transport detrital sediment that has experienced prolonged sediment storage and burial either on hillslopes and/or in fluvial networks; thus, erosion rates from such basins are lower limits due to nuclide decay during storage. Conversely, samples from smaller upland basins are more likely to provide reliable erosion rates.more » « less
-
Abstract. Outlet glaciers that flow through the Transantarctic Mountains (TAM) experienced changes in ice thickness greater than other coastal regions of Antarctica during glacial maxima. As a result, ice-free areas that are currently exposed may have been covered by ice at various points during the Cenozoic, complicating our understanding of ecological succession in TAM soils. Our knowledge of glacial extent on small spatial scales is limited for the TAM, and studies of soil exposure duration and disturbance, in particular, are rare. We collected surface soil samples and, in some places, depth profiles every 5 cm to refusal (up to 30 cm) from 11ice-free areas along Shackleton Glacier, a major outlet glacier of the EastAntarctic Ice Sheet. We explored the relationship between meteoric 10Be and NO3- in these soils as a tool for understanding landscape disturbance and wetting history and as exposure proxies. Concentrations of meteoric 10Be spanned more than an order of magnitude across the region (2.9×108 to 73×108 atoms g−1) and are among the highest measured in polar regions. The concentrations of NO3- were similarly variable and ranged from ∼1 µg g−1 to 15 mg g−1. In examining differences and similarities in the concentrations of 10Be and NO3- with depth, we suggest that much of the southern portion of the Shackleton Glacier region has likely developed under a hyper-arid climate regime with minimal disturbance. Finally, we inferred exposure time using 10Be concentrations. This analysis indicates that the soils we analyzed likelyrange from recent exposure (following the Last Glacial Maximum) to possibly>6 Myr. We suggest that further testing and interrogation of meteoric 10Be and NO3- concentrations and relationships in soils can provide important information regarding landscape development, soil evolution processes, and inferred exposure durations of surfaces in the TAM.more » « less
-
We assess if variations in the in situ cosmogenic 26Al/10Be production ratio expected from nuclear physics are consistent with empirical data, knowledge critical for two-isotope studies. We do this using 313 samples from glacially transported boulders or scoured bedrock with presumed simple exposure histories in the Informal Cosmogenic-nuclide Exposure-age Database (ICE-D) from latitudes between 53°S to 70°N and altitudes up to 5000 m above sea level. Although there were small systematic differences in Al/Be ratios measured in different laboratories, these were not significant and are in part explained by differences in elevation distribution of samples analyzed by each laboratory. We observe a negative correlation between the 26Al/10Be production ratio and elevation (p = 0.0005), consistent with predictions based on the measured energy dependence of nuclear reaction cross-sections and the spatial variability in cosmic-ray energy spectra. We detect an increase in the production ratio with increasing latitude, but this correlation is significant only in a single variate model, and we attribute at least some of the correlation to sample elevation bias because lower latitude samples are typically from higher elevations (and vice versa). Using 6.75 as the 26Al/10Be production ratio globally will bias two-isotope results at higher elevations and perhaps higher latitudes. Data reported here support using production rate scaling that incorporates such ratio changes, such as the LSDn scheme, to minimize such biases.more » « less