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1. Interpreting detrital modes and geochemistry of sandstones from the late Paleozoic Tepuel-Genoa Basin: Paleogeographic implications (Patagonia, Argentina)

   https://doi.org/https://doi.org/10.1016/j.jsames.2020.102858  

   Ciccioli, P. L.; Limarino, C. O.; Isbell, J.L.; Taboada, A. C.; Pagani, M. A.; Gulbranson, E.L. (September 2020, Journal of South American earth sciences)

   null (Ed.)

   The provenance of sandstones deposited in the late Paleozoic Tepuel-Genoa Basin is analyzed in this paper. Five sections were sampled in Esquel, Sierra de Tepuel, Sierra de Tecka, El Molle, and Río Genoa areas for petrographic and geochemical studies. The sandstones in the Tepuel-Genoa Basin are dominated by feldspathic litharenites and litharenites, showing lithic fragments of volcanic and sedimentary rocks in the Valle Chico Formation and medium-to high-grade metamorphic rock clasts in the rest of the units. Detrital modes of seventy-five sandstones samples from the Valle Chico, Pampa de Tepuel, Moj´on de Hierro, and Río Genoa formations were counted and analyzed. Seven modal components have discriminant value for identifying provenance areas (Qm, Qi, Lv, Lmm-h, Lm-Lp, Lm, Qpm). These modal components allow identification of three petrofacies: 1. Quartzose-lithic (Qm69Lv2Lm29), 2. Quartzose (Qm89Lv4Lm7) and 3. Volcanic-sedimentary (Qm60Lv38Lm1). The quartzose-lithic petrofacies is mainly composed of monocrystalline quartz, medium- and high-grade metamorphic clasts and polycrystalline quartz with cataclastic texture, this assemblage is interpreted as being derived from the crystalline rocks that form the Deseado Massif. The quartzose petrofacies is composed of monocrystalline quartz with scarce contributions of metamorphic clasts and traces of volcanic fragments; the provenance area is ascribed to sedimentary terrains, which most likely covered part of the Deseado Massif. The volcanic-sedimentary petrofacies is comprised of volcanic (acidic and intermediate rocks) and sedimentary (sandstone and mudstone) clasts, with discrete amounts of quartz grains with idiomorph shapes and embayments. This assemblage may correspond to material supply from the Devonian-Early Carboniferous accretionary complex developed in Chile or the unroofing of the western volcanic arc located in the central part of Patagonia. The validity of the three defined petrofacies was evaluated using Principal Component Analysis and triangular compositional diagrams; both methods show good separation and lack of overlap between the three petrofacies. Major (Si, Al, Fe, Na, K) and trace-REE elements (Zr, Th, Sc, Hf) were used to improve the petrographic information. The relation SiO2 against K2O/Na2O indicates that the Pampa de Tepuel and the Moj´on de Hierro formations correspond to a passive margin, while the Valle Chico and Río Genoa formations represent different types of active continental margins. The Th/Sc and Zr/Sc ratios and the Th-Hf-Co distributions indicate that the sandstones of the Tepuel Group were formed from rocks compatibles with the average composition of the upper continental crust. 

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2. A waning Saxothuringian Ocean evidenced in the Famennian tephra-bearing siliceous succession of the Bardo Unit (Central Sudetes, SW Poland)

   https://doi.org/10.1130/B35971.1  

   Racki, Grzegorz; Mazur, Stanisław; Narkiewicz, Katarzyna; Pisarzowska, Agnieszka; Bardziński, Waldemar; Kołtonik, Katarzyna; Szymanowski, Dawid; Filipiak, Paweł; Kremer, Barbara (February 2022, GSA Bulletin)

   Abstract A tephra-rich cherty-clayey Famennian succession within the major Brzeźnica olistostrome in the Bardo Mountains, Central Sudetes, SW Poland, preserves a record of the lost ocean later incorporated into the Variscan orogenic belt. Fluctuating but mostly oligotrophic regimes and low primary production levels were influenced by weak up-welling below the perennial oxygen minimum zone, which controlled the interplay between biosiliceous and siliciclastic deposition in the oceanic basin, with episodic oxygen deficiency. The Hangenberg Black Shale has been identified in this oceanic setting based on its characteristics described worldwide (including mercury enrichments). A tectonic uplift of the sediment source area near the Devonian-Carboniferous boundary, recorded in the distinguishing provenance signal of old continental crust, was paired with a global transgression, anoxia, and volcanic episode in an interglacial interval. Assuming paleogeographic affinity with the Bavarian facies of the Saxothuringian terrane, we interpret the allochthonous sediments as part of an accretionary prism that was gravitationally redeposited into the late orogenic basin in front of advancing Variscan nappes. The oceanic basin parental to the Bardo pelagic succession is therefore thought to represent a tract of the waning Saxothuringian Ocean in the Peri-Gondwanan paleogeographic domain that was eventually subducted beneath the Brunovistulian margin of Laurussia. The sediments of the Bardo Ocean basin also include a distal record of Famennian explosive volcanic activity that was likely related to a continental magmatic arc whose remnants are preserved as the Vrbno Group of the East Sudetes. 

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3. Episodic evolution of a protracted convergent margin revealed by detrital zircon geochronology in the Greater Caucasus

   https://doi.org/10.1111/bre.12825  

   Vasey, Dylan_A; Garcia, Leslie; Cowgill, Eric; Trexler, Charles_C; Godoladze, Tea (September 2023, Basin Research)

   Abstract Convergent margins play a fundamental role in the construction and modification of Earth's lithosphere and are characterized by poorly understood episodic processes that occur during the progression from subduction to terminal collision. On the northern margin of the active Arabia‐Eurasia collision zone, the Greater Caucasus Mountains provide an opportunity to study a protracted convergent margin that spanned most of the Phanerozoic and culminated in Cenozoic continental collision. However, the main episodes of lithosphere formation and deformation along this margin remain enigmatic. Here, we use detrital zircon U–Pb geochronology from Paleozoic and Mesozoic (meta)sedimentary rocks in the Greater Caucasus, along with select zircon U–Pb and Hf isotopic data from coeval igneous rocks, to link key magmatic and depositional episodes along the Caucasus convergent margin. Devonian to Early Carboniferous rocks were deposited prior to Late Carboniferous accretion of the Greater Caucasus crystalline core onto the Laurussian margin. Permian to Triassic rocks document a period of northward subduction and forearc deposition south of a continental margin volcanic arc in the Northern Caucasus and Scythian Platform. Jurassic rocks record the opening of the Caucasus Basin as a back‐arc rift during southward migration of the arc front into the Lesser Caucasus. Cretaceous rocks have few Jurassic‐Cretaceous zircons, indicating a period of relative magmatic quiescence and minimal exhumation within this basin. Late Cenozoic closure of the Caucasus Basin juxtaposed the Lesser Caucasus arc to the south against the crystalline core of the Greater Caucasus to the north and led to the formation of a hypothesized terminal suture. We expect this suture to be within ~20 km of the southern range front of the Greater Caucasus because all analysed rocks to the north exhibit a provenance affinity with the crystalline core of the Greater Caucasus. 

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4. Origin of paleovalleys on the Rio Grande do Sul Shield (Brazil): Implications for the extent of late Paleozoic glaciation in west-central Gondwana

   Fedorchuk, N.D.; Isbell, J.L.; Griffis, N.P.; Montañez, I.P.; Vesely, F.F.; Iannuzzi, R.; Mundil, R.; Yin, Q.-Z.; Pauls, K.N.; Rosa, E.L.M (April 2018, Palaeogeography, palaeoclimatology, palaeoecology)

   The location, longevity, and geographic extent of late Paleozoic ice centers in west-central Gondwana remain ambiguous. Paleovalleys on the Rio Grande do Sul Shield of southernmost Brazil have previously been interpreted as fjords carved by outlet glaciers that originated in Africa and emptied into the Paraná Basin (Brazil). In this study, the sedimentology, stratigraphy, and provenance of sediments infilling two such paleovalleys (the Mariana Pimentel and Leão paleovalleys) were examined in order to test the hypothesis that an ice center over present day Namibia drained across southernmost Brazil during the Carboniferous and Permian. Contrary to previous findings, the facies assemblage from within the paleovalleys is inconsistent with a fjord setting and no clear evidence for glaciation was observed. The facies show a transition from a non-glacial lacustrine/estuarine environment, to a fluvial-dominated setting, and finally to a restricted marine/estuarine environment. Detrital zircon results present a single population of Neoproterozoic ages (c. 800–550 Ma) from the paleovalley fill that matches the ages of underlying igneous and metamorphic basement (Dom Feliciano Belt) and is incongruent with African sources that contain abundant older (Mesoproterozoic, Paleoproterozoic, and Archean) zircons. Furthermore, results suggest that the formation of the paleovalleys and the deposition of their fill were controlled by the reactivation of Neoproterozoic basement structures during the Carboniferous and Permian. The lack of evidence for glaciation in these paleovalleys highlights the need for detailed studies of supposed late Paleozoic glacial deposits. These results are supportive of the hypothesis that well-established glacial sediments on the Rio Grande do Sul Shield (southern margin of the Paraná Basin) may be the product of a separate lobe extending north across Uruguay, rather than a single, massive ice sheet draining west from Africa. 

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5. A Carboniferous apex for the late Paleozoic icehouse

   https://doi.org/10.1144/sp535-2022-256  

   Griffis, N.; Mundil, R.; Montañez, I.; Le Heron, D.; Dietrich, P.; Iannuzzi, R. (October 2022, Geological Society, London, Special Publications)

   Abstract Icehouse climate systems occur across an abbreviated portion of Earth history, constitutingc.25% of the Phanerozoic record. The Late Paleozoic Ice Age (LPIA) was the most extreme and longest lasting glaciation of the Phanerozoic and is characterized by periods of acute continental-scale glaciation, separated by periods of ice minima or ice-free conditions on the order of <10⁶years. The late Paleozoic glaciogenic record of the Paraná and Kalahari basins of southern Gondwana form one of the largest, best-preserved and well-calibrated records of this glaciation. In the Carboniferous, the eastern and southern margins of the Paraná Basin and the Kalahari Basin were characterized by subglacial conditions, with evidence for continental and upland glaciers. In the latest Carboniferous, these basins transitioned from subglacial reservoirs to ice-free or ‘ice distal‘ conditions evidenced by the widespread deposition of marine deposits juxtaposed on subglacial bedforms. High-precision U–Pb zircon chemical abrasion thermal ionization mass spectrometry geochronological constraints from volcanic ash deposits in the deglacial marine black shales of the Kalahari Basin and from fluvial and coal successions, which overlie marine deposits in the Paraná Basin, indicate subglacial evidence in these regions is constrained to the Carboniferous. The loss of ice in these regions is congruent with a late Carboniferous peak inpCO₂and widespread marine anoxia in the late Carboniferous. The permeant retreat of glaciers in basinal settings, despite an early PermianpCO₂nadir, highlights the influence of short-term perturbations on the longer-term CO₂record and suggests an ice threshold had been crossed in the latest Carboniferous. A definitive driver for greenhouse gases in the LPIA, such as abundant and sustained volcanic activity or an increased biological pump driven by ocean fertilization, is unresolved for this period. Lastly, the proposed Carboniferous apex for the high-latitude LPIA record is incongruent with observations from the low-latitude tropics where an early Permian peak is proposed. 

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