skip to main content


Title: Direct determination of mode-projected electron-phonon coupling in the time domain

Ultrafast spectroscopies have become an important tool for elucidating the microscopic description and dynamical properties of quantum materials. In particular, by tracking the dynamics of nonthermal electrons, a material’s dominant scattering processes can be revealed. Here, we present a method for extracting the electron-phonon coupling strength in the time domain, using time- and angle-resolved photoemission spectroscopy (TR-ARPES). This method is demonstrated in graphite, where we investigate the dynamics of photoinjected electrons at theK¯point, detecting quantized energy-loss processes that correspond to the emission of strongly coupled optical phonons. We show that the observed characteristic time scale for spectral weight transfer mediated by phonon-scattering processes allows for the direct quantitative extraction of electron-phonon matrix elements for specific modes.

 
more » « less
Award ID(s):
1752713
NSF-PAR ID:
10126474
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ; ; ; ; ;
Publisher / Repository:
American Association for the Advancement of Science (AAAS)
Date Published:
Journal Name:
Science
Volume:
366
Issue:
6470
ISSN:
0036-8075
Page Range / eLocation ID:
p. 1231-1236
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract

    We perform particle-in-cell simulations to elucidate the microphysics of relativistic weakly magnetized shocks loaded with electron-positron pairs. Various external magnetizationsσ≲ 10−4and pair-loading factorsZ±≲ 10 are studied, whereZ±is the number of loaded electrons and positrons per ion. We find the following: (1) The shock becomes mediated by the ion Larmor gyration in the mean field whenσexceeds a critical valueσLthat decreases withZ±. AtσσLthe shock is mediated by particle scattering in the self-generated microturbulent fields, the strength and scale of which decrease withZ±, leading to lowerσL. (2) The energy fraction carried by the post-shock pairs is robustly in the range between 20% and 50% of the upstream ion energy. The mean energy per post-shock electron scales asE¯eZ±+11. (3) Pair loading suppresses nonthermal ion acceleration at magnetizations as low asσ≈ 5 × 10−6. The ions then become essentially thermal with mean energyE¯i, while electrons form a nonthermal tail, extending fromEZ±+11E¯itoE¯i. Whenσ= 0, particle acceleration is enhanced by the formation of intense magnetic cavities that populate the precursor during the late stages of shock evolution. Here, the maximum energy of the nonthermal ions and electrons keeps growing over the duration of the simulation. Alongside the simulations, we develop theoretical estimates consistent with the numerical results. Our findings have important implications for models of early gamma-ray burst afterglows.

     
    more » « less
  2. Abstract

    While it is well known that cosmic rays (CRs) can gain energy from turbulence via second-order Fermi acceleration, how this energy transfer affects the turbulent cascade remains largely unexplored. Here, we show that damping and steepening of the compressive turbulent power spectrum are expected once the damping timetdampρv2/ĖCRECR1becomes comparable to the turbulent cascade time. Magnetohydrodynamic simulations of stirred compressive turbulence in a gas-CR fluid with diffusive CR transport show clear imprints of CR-induced damping, saturating atĖCRϵ˜, whereϵ˜is the turbulent energy input rate. In that case, almost all of the energy in large-scale motions is absorbed by CRs and does not cascade down to grid scale. Through a Hodge–Helmholtz decomposition, we confirm that purely compressive forcing can generate significant solenoidal motions, and we find preferential CR damping of the compressive component in simulations with diffusion and streaming, rendering small-scale turbulence largely solenoidal, with implications for thermal instability and proposed resonant scattering ofE≳ 300 GeV CRs by fast modes. When CR transport is streaming dominated, CRs also damp large-scale motions, with kinetic energy reduced by up to 1 order of magnitude in realisticECREgscenarios, but turbulence (with a reduced amplitude) still cascades down to small scales with the same power spectrum. Such large-scale damping implies that turbulent velocities obtained from the observed velocity dispersion may significantly underestimate turbulent forcing rates, i.e.,ϵ˜ρv3/L.

     
    more » « less
  3. Abstract

    Kagomé metals are widely recognized, versatile platforms for exploring topological properties, unconventional electronic correlations, magnetic frustration, and superconductivity. In theRV6Sn6family of materials (R= Sc, Y, Lu), ScV6Sn6hosts an unusual charge density wave ground state as well as structural similarities with theAV3Sb5system (A= K, Cs, Rb). In this work, we combine Raman scattering spectroscopy with first-principles lattice dynamics calculations to reveal phonon mixing processes in the charge density wave state of ScV6Sn6. In the low temperature phase, we find at least four new peaks in the vicinity of the V-containing totally symmetric mode near 240 cm−1suggesting that the density wave acts to mix modes ofP6/mmmand$$R\bar{3}m$$R3¯msymmetry - a result that we quantify by projecting phonons of the high symmetry state onto those of the lower symmetry structure. We also test the stability of the short-range ordered density wave state under compression and propose that both physical and chemical pressure quench the effect. We discuss these findings in terms of symmetry and the structure-property trends that can be unraveled in this system.

     
    more » « less
  4. Abstract

    We present UV and/or optical observations and models of SN 2023ixf, a type II supernova (SN) located in Messier 101 at 6.9 Mpc. Early time (flash) spectroscopy of SN 2023ixf, obtained primarily at Lick Observatory, reveals emission lines of Hi, Hei/ii, Civ, and Niii/iv/vwith a narrow core and broad, symmetric wings arising from the photoionization of dense, close-in circumstellar material (CSM) located around the progenitor star prior to shock breakout. These electron-scattering broadened line profiles persist for ∼8 days with respect to first light, at which time Doppler broadened the features from the fastest SN ejecta form, suggesting a reduction in CSM density atr≳ 1015cm. The early time light curve of SN 2023ixf shows peak absolute magnitudes (e.g.,Mu= −18.6 mag,Mg= −18.4 mag) that are ≳2 mag brighter than typical type II SNe, this photometric boost also being consistent with the shock power supplied from CSM interaction. Comparison of SN 2023ixf to a grid of light-curve and multiepoch spectral models from the non-LTE radiative transfer codeCMFGENand the radiation-hydrodynamics codeHERACLESsuggests dense, solar-metallicity CSM confined tor= (0.5–1) × 1015cm, and a progenitor mass-loss rate ofṀ=102Myr−1. For the assumed progenitor wind velocity ofvw= 50 km s−1, this corresponds to enhanced mass loss (i.e.,superwindphase) during the last ∼3–6 yr before explosion.

     
    more » « less
  5. Abstract

    Recently, room temperature superconductivity was measured in a carbonaceous sulfur hydride material whose identity remains unknown. Herein, first-principles calculations are performed to provide a chemical basis for structural candidates derived by doping H3S with low levels of carbon. Pressure stabilizes unusual bonding configurations about the carbon atoms, which can be six-fold coordinated as CH6entities within the cubic H3S framework, or four-fold coordinated as methane intercalated into the H-S lattice, with or without an additional hydrogen in the framework. The doping breaks degenerate bands, lowering the density of states at the Fermi level (NF), and localizing electrons in C-H bonds. Low levels of CH4doping do not increaseNFto values as high as those calculated for$$Im\bar{3}m$$Im3¯m-H3S, but they can yield a larger logarithmic average phonon frequency, and an electron–phonon coupling parameter comparable to that ofR3m-H3S. The implications of carbon doping on the superconducting properties are discussed.

     
    more » « less