Abstract Charge density wave (CDW) ordering has been an important topic of study for a long time owing to its connection with other exotic phases such as superconductivity and magnetism. The$$R{\textrm{Te}}_{3}$$ (R= rare-earth elements) family of materials provides a fertile ground to study the dynamics of CDW in van der Waals layered materials, and the presence of magnetism in these materials allows to explore the interplay among CDW and long range magnetic ordering. Here, we have carried out a high-resolution angle-resolved photoemission spectroscopy (ARPES) study of a CDW material$${\textrm{Gd}}{\textrm{Te}}_{3}$$ , which is antiferromagnetic below$$\sim \mathrm {12~K}$$ , along with thermodynamic, electrical transport, magnetic, and Raman measurements. Our ARPES data show a two-fold symmetric Fermi surface with both gapped and ungapped regions indicative of the partial nesting. The gap is momentum dependent, maximum along$${\overline{\Gamma }}-\mathrm{\overline{Z}}$$ and gradually decreases going towards$${\overline{\Gamma }}-\mathrm{\overline{X}}$$ . Our study provides a platform to study the dynamics of CDW and its interaction with other physical orders in two- and three-dimensions.
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Phonon mixing in the charge density wave state of ScV6Sn6
Abstract Kagomé metals are widely recognized, versatile platforms for exploring topological properties, unconventional electronic correlations, magnetic frustration, and superconductivity. In theRV6Sn6family of materials (R= Sc, Y, Lu), ScV6Sn6hosts an unusual charge density wave ground state as well as structural similarities with theAV3Sb5system (A= K, Cs, Rb). In this work, we combine Raman scattering spectroscopy with first-principles lattice dynamics calculations to reveal phonon mixing processes in the charge density wave state of ScV6Sn6. In the low temperature phase, we find at least four new peaks in the vicinity of the V-containing totally symmetric mode near 240 cm−1suggesting that the density wave acts to mix modes ofP6/mmmand$$R\bar{3}m$$ symmetry - a result that we quantify by projecting phonons of the high symmetry state onto those of the lower symmetry structure. We also test the stability of the short-range ordered density wave state under compression and propose that both physical and chemical pressure quench the effect. We discuss these findings in terms of symmetry and the structure-property trends that can be unraveled in this system.
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- Award ID(s):
- 2046020
- PAR ID:
- 10498852
- Publisher / Repository:
- Springer Nature
- Date Published:
- Journal Name:
- npj Quantum Materials
- Volume:
- 8
- Issue:
- 1
- ISSN:
- 2397-4648
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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