Abstract Nematicity, spontaneous breaking of rotational symmetry, is a ubiquitous phenomenon in correlated quantum matter. Here we show a phase transition in high-quality ScV6Sn6bilayer kagome metal at a temperature$${T}^{*}$$ , occurring seven Kelvins below the charge density wave transition at$${T}_{{CDW}}$$ , as indicated by thermodynamic, transport, and optical measurements. This emerging intermediate phase does not exhibit spontaneous time-reversal-symmetry breaking, as evidenced by zero-field Sagnac interferometry. However, it displays a strong, spontaneous in-plane anisotropy between$${T}^{*}$$ and$${T}_{{CDW}}$$ , revealed by transport and optical polarization rotation measurements. A pronounced depolarization effect detected by the Sagnac interferometer further confirms its nematic nature. Unlike AV3Sb5, this phase, alongside the recently discovered intra-unit cell nematic order at lower temperatures, presents a diverse landscape of nematicities at multiple length and temperature scales. Our findings highlight ScV6Sn6as a prime candidate for realizing symmetry-breaking phases driven by charge density competition, kagome physics, and Van Hove singularities.
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Phonon mixing in the charge density wave state of ScV6Sn6
Abstract Kagomé metals are widely recognized, versatile platforms for exploring topological properties, unconventional electronic correlations, magnetic frustration, and superconductivity. In theRV6Sn6family of materials (R= Sc, Y, Lu), ScV6Sn6hosts an unusual charge density wave ground state as well as structural similarities with theAV3Sb5system (A= K, Cs, Rb). In this work, we combine Raman scattering spectroscopy with first-principles lattice dynamics calculations to reveal phonon mixing processes in the charge density wave state of ScV6Sn6. In the low temperature phase, we find at least four new peaks in the vicinity of the V-containing totally symmetric mode near 240 cm−1suggesting that the density wave acts to mix modes ofP6/mmmand$$R\bar{3}m$$ symmetry - a result that we quantify by projecting phonons of the high symmetry state onto those of the lower symmetry structure. We also test the stability of the short-range ordered density wave state under compression and propose that both physical and chemical pressure quench the effect. We discuss these findings in terms of symmetry and the structure-property trends that can be unraveled in this system.
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- Award ID(s):
- 2046020
- PAR ID:
- 10498852
- Publisher / Repository:
- Springer Nature
- Date Published:
- Journal Name:
- npj Quantum Materials
- Volume:
- 8
- Issue:
- 1
- ISSN:
- 2397-4648
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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