Manganese dioxide (MnO 2 ) with a conversion mechanism is regarded as a promising anode material for lithium-ion batteries (LIBs) owing to its high theoretical capacity (∼1223 mA h g −1 ) and environmental benignity as well as low cost. However, it suffers from insufficient rate capability and poor cyclic stability. To circumvent this obstacle, semiconducting polypyrrole coated-δ-MnO 2 nanosheet arrays on nickel foam (denoted as MnO 2 @PPy/NF) are prepared via hydrothermal growth of MnO 2 followed by the electrodeposition of PPy on the anode in LIBs. The electrode with ∼50 nm thick PPy coating exhibits an outstanding overall electrochemical performance. Specifically, a high rate capability is obtained with ∼430 mA h g −1 of discharge capacity at a high current density of 2.67 A g −1 and more than 95% capacity is retained after over 120 cycles at a current rate of 0.86 A g −1 . These high electrochemical performances are attributed to the special structure which shortens the ion diffusion pathway, accelerates charge transfer, and alleviates volume change in the charging/discharging process, suggesting a promising route for designing a conversion-type anode material for LIBs.
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Sulfur impregnation in polypyrrole-modified MnO 2 nanotubes: efficient polysulfide adsorption for improved lithium–sulfur battery performance
Rechargeable lithium–sulfur batteries have emerged as a viable technology for next generation electrochemical energy storage, and the sulfur cathode plays a critical role in determining the device performance. In this study, we prepared functional composites based on polypyrrole-coated MnO 2 nanotubes as a highly efficient sulfur host (sulfur mass loading 63.5%). The hollow interior of the MnO 2 nanotubes not only allowed for accommodation of volumetric changes of sulfur particles during the cycling process, but also confined the diffusion of lithium polysulfides by physical restriction and chemical adsorption, which minimized the loss of polysulfide species. In addition, the polypyrrole outer layer effectively enhanced the electrical conductivity of the cathode to facilitate ion and electron transport. The as-prepared MnO 2 -PPy-S composite delivered an initial specific capacity of 1469 mA h g −1 and maintained an extremely stable cycling performance, with a small capacity decay of merely 0.07% per cycle at 0.2C within 500 cycles, a high average coulombic efficiency of 95.7% and an excellent rate capability at 470 mA h g −1 at the current density of 3C.
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- Award ID(s):
- 1848841
- NSF-PAR ID:
- 10137706
- Date Published:
- Journal Name:
- Nanoscale
- Volume:
- 11
- Issue:
- 20
- ISSN:
- 2040-3364
- Page Range / eLocation ID:
- 10097 to 10105
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/c8nr10353d
