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Title: Synthesis of novel copper-rare earth BINOLate frameworks from a hydrogen bonding DBU-H rare earth BINOLate complex
The preparation of a novel H-bonding DBU-H + BINOLate Rare Earth Metal complex enabled the synthesis of the first copper-Rare Earth Metal BINOLate complex (CuDBU-REMB). CuDBU-REMB was compared to the analogous Li complex using X-ray crystallography and Exchange NMR spectroscopy (EXSY). The results provide insight into the role of the secondary metal cation in the framework's stabilization.  more » « less
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Date Published:
Journal Name:
Dalton Transactions
Page Range / eLocation ID:
14408 to 14410
Medium: X
Sponsoring Org:
National Science Foundation
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