NSF PAR Search | NSF Public Access Repository

Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher. Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?

Some links on this page may take you to non-federal websites. Their policies may differ from this site.

Reactivity of Ce( iv ) imido compounds with heteroallenes

https://doi.org/10.1039/C9CC10052K

Lapsheva, Ekaterina N.; Cheisson, Thibault; Álvarez Lamsfus, Carlos; Carroll, Patrick J.; Gau, Michael R.; Maron, Laurent; Schelter, Eric J. (April 2020, Chemical Communications)
null (Ed.)
The reactivity of alkali metal capped Ce( iv ) imido compounds [M(DME) 2 ][CeNAr F (TriNOx)] ( 1-M with M = K, Rb, Cs and Ar F = 3,5-bis(trifluoromethyl)phenyl) with CO 2 and organic isocyanates has been evaluated. 1-Cs reacted with CO 2 to yield an organocarbamate complex. Reaction of 1-K and 1-Rb with organic isocyanates yielded organoureate Ce( iv ) complexes.
more » « less
Full Text Available
Multiple Bonding in Lanthanides and Actinides: Direct Comparison of Covalency in Thorium(IV)- and Cerium(IV)-Imido Complexes

https://doi.org/10.1021/jacs.9b04061

Cheisson, Thibault; Kersey, Kyle D.; Mahieu, Nolwenn; McSkimming, Alex; Gau, Michael R.; Carroll, Patrick J.; Schelter, Eric J. (May 2019, Journal of the American Chemical Society)

Full Text Available
An investigation of the binding of ( S )-monothioBINOLate to rare earth metal cations

https://doi.org/10.1080/10426507.2019.1602773

Panetti, Grace B.; Varela, Elena J.; Gau, Michael R.; Schelter, Eric J.; Walsh, Patrick J. (April 2019, Phosphorus, Sulfur, and Silicon and the Related Elements)

Full Text Available
¹³ C NMR Shifts as an Indicator of U–C Bond Covalency in Uranium(VI) Acetylide Complexes: An Experimental and Computational Study

https://doi.org/10.1021/acs.inorgchem.8b03175

Mullane, Kimberly C.; Hrobárik, Peter; Cheisson, Thibault; Manor, Brian C.; Carroll, Patrick J.; Schelter, Eric J. (March 2019, Inorganic Chemistry)

Full Text Available
Synthesis of novel copper-rare earth BINOLate frameworks from a hydrogen bonding DBU-H rare earth BINOLate complex

https://doi.org/10.1039/c8dt03335h

Panetti, Grace B.; Robinson, Jerome R.; Carroll, Patrick J.; Gau, Michael R.; Manor, Brain C.; Walsh, Patrick J.; Schelter, Eric J. (October 2018, Dalton Transactions)

The preparation of a novel H-bonding DBU-H + BINOLate Rare Earth Metal complex enabled the synthesis of the first copper-Rare Earth Metal BINOLate complex (CuDBU-REMB). CuDBU-REMB was compared to the analogous Li complex using X-ray crystallography and Exchange NMR spectroscopy (EXSY). The results provide insight into the role of the secondary metal cation in the framework's stabilization.
more » « less
Full Text Available
Silyl Transfer Pathway to a Ce(IV) Imido Complex

https://doi.org/10.1021/acs.organomet.8b00366

Cheisson, Thibault; Solola, Lukman A.; Gau, Michael R.; Carroll, Patrick J.; Schelter, Eric J. (September 2018, Organometallics)
Exploration of the Solid- and Solution-State Structures and Electrochemical Properties of Ce ^IV (atrane) Complexes

https://doi.org/10.1021/acs.inorgchem.8b00712

Solola, Lukman A.; Cheisson, Thibault; Yang, Qiaomu; Carroll, Patrick J.; Schelter, Eric J. (August 2018, Inorganic Chemistry)

Full Text Available
C–H Bond Addition across a Transient Uranium–Nitrido Moiety and Formation of a Parent Uranium Imido Complex

https://doi.org/10.1021/jacs.8b06090

Mullane, Kimberly C.; Ryu, Ho; Cheisson, Thibault; Grant, Lauren N.; Park, Ji Young; Manor, Brian C.; Carroll, Patrick J.; Baik, Mu-Hyun; Mindiola, Daniel J.; Schelter, Eric J. (August 2018, Journal of the American Chemical Society)

Full Text Available
Cationic cerium(IV) complexes with multiple open coordination sites

https://doi.org/10.1016/j.jorganchem.2017.10.017

Solola, Lukman A.; Carroll, Patrick J.; Schelter, Eric J. (February 2018, Journal of Organometallic Chemistry)

Full Text Available

Search for: All records