Milling two equivalents of K[1,3‐(SiMe3)2C3H3] (=K[A′]) with MgX2(X=Cl, Br) produces the allyl complex [K2MgA′4] (
Milling two equivalents of K[1,3‐(SiMe3)2C3H3] (=K[A′]) with MgX2(X=Cl, Br) produces the allyl complex [K2MgA′4] (
- Award ID(s):
- 1665327
- NSF-PAR ID:
- 10142746
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Angewandte Chemie International Edition
- Volume:
- 59
- Issue:
- 24
- ISSN:
- 1433-7851
- Page Range / eLocation ID:
- p. 9542-9548
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract Without solvents present, the often far‐from‐equilibrium environment in a mechanochemically driven synthesis can generate high‐energy, non‐stoichiometric products not observed from the same ratio of reagents used in solution. Ball milling 2 equiv. K[A’] (A’=[1,3‐(SiMe3)2C3H3]−) with CaI2yields a non‐stoichiometric calciate, K[CaA’3], which initially forms a structure (
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