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1. On the Remarkable Superconductivity of FeSe and Its Close Cousins

   https://doi.org/10.3390/sym12091402  

   Kreisel, Andreas ; Hirschfeld, Peter J. ; Andersen, Brian M. ( September 2020 , Symmetry)

   null (Ed.)

   Emergent electronic phenomena in iron-based superconductors have been at the forefront of condensed matter physics for more than a decade. Much has been learned about the origins and intertwined roles of ordered phases, including nematicity, magnetism, and superconductivity, in this fascinating class of materials. In recent years, focus has been centered on the peculiar and highly unusual properties of FeSe and its close cousins. This family of materials has attracted considerable attention due to the discovery of unexpected superconducting gap structures, a wide range of superconducting critical temperatures, and evidence for nontrivial band topology, including associated spin-helical surface states and vortex-induced Majorana bound states. Here, we review superconductivity in iron chalcogenide superconductors, including bulk FeSe, doped bulk FeSe, FeTe1−xSex, intercalated FeSe materials, and monolayer FeSe and FeTe1−xSex on SrTiO3. We focus on the superconducting properties, including a survey of the relevant experimental studies, and a discussion of the different proposed theoretical pairing scenarios. In the last part of the paper, we review the growing recent evidence for nontrivial topological effects in FeSe-related materials, focusing again on interesting implications for superconductivity. 

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2. Possible transport evidence for three-dimensional topological superconductivity in doped β-PdBi2

   https://doi.org/10.1038/s41598-019-48906-7  

   Kolapo, Ayo ; Li, Tingxin ; Hosur, Pavan ; Miller, Jr., John H. ( August 2019 , Scientific Reports)

   Interest in topological states of matter burgeoned over a decade ago with the theoretical prediction and experimental detection of topological insulators, especially in bulk three-dimensional insulators that can be tuned out of it by doping. Their superconducting counterpart, the fully-gapped three-dimensional time-reversal-invariant topological superconductors, have evaded discovery in bulkintrinsic superconductorsso far. The recently discovered topological metalβ-PdBi₂is a unique candidate for tunable bulk topological superconductivity because of its intrinsic superconductivity and spin-orbit-coupling. In this work, we provide experimental transport signatures consistent with fully-gapped 3D time-reversal-invariant topological superconductivity in K-dopedβ-PdBi₂. In particular, we find signatures of odd-parity bulk superconductivity via upper-critical field and magnetization measurements— odd-parity pairing can be argued, given the band structure ofβ-PdBi₂, to result in 3D topological superconductivity. In addition, Andreev spectroscopy reveals surface states protected by time-reversal symmetry which might be possible evidence of Majorana surface states (Majorana cone). Moreover, we find that the undoped bulk system is a trivial superconductor. Thus, we discoverβ-PdBi₂as a unique bulk material that, on doping, can potentially undergo an unprecedented topological quantum phase transition in the superconducting state.

    

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3. Evidence for higher order topology in Bi and Bi0.92Sb0.08

   https://doi.org/10.1038/s41467-021-24683-8  

   Aggarwal, Leena ; Zhu, Penghao ; Hughes, Taylor L. ; Madhavan, Vidya ( July 2021 , Nature Communications)

   Higher order topological insulators (HOTIs) are a new class of topological materials which host protected states at the corners or hinges of a crystal. HOTIs provide an intriguing alternative platform for helical and chiral edge states and Majorana modes, but there are very few known materials in this class. Recent studies have proposed Bi as a potential HOTI, however, its topological classification is not yet well accepted. In this work, we show that the (110) facets of Bi and BiSb alloys can be used to unequivocally establish the topology of these systems. Bi and Bi_0.92Sb_0.08(110) films were grown on silicon substrates using molecular beam epitaxy and studied by scanning tunneling spectroscopy. The surfaces manifest rectangular islands which show localized hinge states on three out of the four edges, consistent with the theory for the HOTI phase. This establishes Bi and Bi_0.92Sb_0.08as HOTIs, and raises questions about the topological classification of the full family of Bi_xSb_1−xalloys.

    

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4. Hunting for Majoranas

   https://doi.org/10.1126/science.ade0850  

   Yazdani, Ali ; von Oppen, Felix ; Halperin, Bertrand I. ; Yacoby, Amir ( June 2023 , Science)

   BACKGROUND The past decade has witnessed considerable progress toward the creation of new quantum technologies. Substantial advances in present leading qubit technologies, which are based on superconductors, semiconductors, trapped ions, or neutral atoms, will undoubtedly be made in the years ahead. Beyond these present technologies, there exist blueprints for topological qubits, which leverage fundamentally different physics for improved qubit performance. These qubits exploit the fact that quasiparticles of topological quantum states allow quantum information to be encoded and processed in a nonlocal manner, providing inherent protection against decoherence and potentially overcoming a major challenge of the present generation of qubits. Although still far from being experimentally realized, the potential benefits of this approach are evident. The inherent protection against decoherence implies better scalability, promising a considerable reduction in the number of qubits needed for error correction. Transcending possible technological applications, the underlying physics is rife with exciting concepts and challenges, including topological superconductors, non-abelian anyons such as Majorana zero modes (MZMs), and non-abelian quantum statistics.­­ ADVANCES In a wide-ranging and ongoing effort, numerous potential material platforms are being explored that may realize the required topological quantum states. Non-abelian anyons were first predicted as quasiparticles of topological states known as fractional quantum Hall states, which are formed when electrons move in a plane subject to a strong perpendicular magnetic field. The prediction that hybrid materials that combine topological insulators and conventional superconductors can support localized MZMs, the simplest type of non-abelian anyon, brought entirely new material platforms into view. These include, among others, semiconductor-superconductor hybrids, magnetic adatoms on superconducting substrates, and Fe-based superconductors. One-dimensional systems are playing a particularly prominent role, with blueprints for quantum information applications being most developed for hybrid semiconductor-superconductor systems. There have been numerous attempts to observe non-abelian anyons in the laboratory. Several experimental efforts observed signatures that are consistent with some of the theoretical predictions for MZMs. A few extensively studied platforms were subjected to intense scrutiny and in-depth analyses of alternative interpretations, revealing a more complex reality than anticipated, with multiple possible interpretations of the data. Because advances in our understanding of a physical system often rely on discrepancies between experiment and theory, this has already led to an improved understanding of Majorana signatures; however, our ability to detect and manipulate non-abelian anyons such as MZMs remains in its infancy. Future work can build on improved materials in some of the existing platforms but may also exploit new materials such as van der Waals heterostructures, including twisted layers, which promise many new options for engineering topological phases of matter. OUTLOOK Experimentally establishing the existence of non-abelian anyons constitutes an outstandingly worthwhile goal, not only from the point of view of fundamental physics but also because of their potential applications. Future progress will be accelerated if claims of Majorana discoveries are based on experimental tests that go substantially beyond indicators such as zero-bias peaks that, at best, suggest consistency with a Majorana interpretation. It will be equally important that these discoveries build on an excellent understanding of the underlying material systems. Most likely, further material improvements of existing platforms and the exploration of new material platforms will both be important avenues for progress toward obtaining solid evidence for MZMs. Once that has been achieved, we can hope to explore—and harness—the fascinating physics of non-abelian anyons such as the topologically protected ground state manifold and non-abelian statistics. Proposed topological platforms. (Left) Proposed state of electrons in a high magnetic field (even-denominator fractional quantum Hall states) are predicted to host Majorana quasiparticles. (Right) Hybrid structures of superconductors and other materials have also been proposed to host such quasiparticles and can be tailored to create topological quantum bits based on Majoranas. 

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5. Phase-induced topological superconductivity in a planar heterostructure

   https://doi.org/10.1073/pnas.2107377118  

   Lesser, Omri ; Saydjari, Andrew ; Wesson, Marie ; Yacoby, Amir ; Oreg, Yuval ( June 2021 , Proceedings of the National Academy of Sciences)

   Topological superconductivity in quasi-one-dimensional systems is a novel phase of matter with possible implications for quantum computation. Despite years of effort, a definitive signature of this phase in experiments is still debated. A major cause of this ambiguity is the side effects of applying a magnetic field: induced in-gap states, vortices, and alignment issues. Here we propose a planar semiconductor–superconductor heterostructure as a platform for realizing topological superconductivity without applying a magnetic field to the two-dimensional electron gas hosting the topological state. Time-reversal symmetry is broken only by phase biasing the proximitizing superconductors, which can be achieved using extremely small fluxes or bias currents far from the quasi-one-dimensional channel. Our platform is based on interference between this phase biasing and the phase arising from strong spin–orbit coupling in closed electron trajectories. The principle is demonstrated analytically using a simple model, and then shown numerically for realistic devices. We show a robust topological phase diagram, as well as explicit wavefunctions of Majorana zero modes. We discuss experimental issues regarding the practical implementation of our proposal, establishing it as an accessible scheme with contemporary experimental techniques.

    

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