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   https://doi.org/10.1016/j.dyepig.2022.110858  

   Jimenez, Jayvic C.; Tran, Quynh; Pugh, Madison H.; Brancel, Christina D.; Rheingold, Arnold L.; Sauvé, Geneviève (January 2023, Dyes and Pigments)

   Zinc(II) complexes of azadipyrromethenes are non-planar chromophores with strong absorption in the visible to NIR and are promising n-type materials for organic solar cells. To increase solubility and tune their properties, we incorporated hexyl or hexyloxy solubilizing groups either on the distal or proximal phenyls of bis[2,6-diphenylethynyl-1,3,7,9-tetraphenyl azadipyrromethene] zinc(II) (Zn(WS3)2). Crystal structures confirm the typical distorted tetrahedral geometry for these types of complexes and show that the solubilizing groups on the distal phenyls extend away from the conjugated core whereas groups on proximal phenyls interact with the other ligand. Differential scanning calorimetry measurement indicated that crystals of distal-substituted complexes have two endothermic peaks: solubilizing groups ‘melting’ and complex melting, whereas the proximal substituted complexes show one exothermic crystallization peak and one endothermic melting peak. Electrochemical and optical properties varied as expected for ADP-based complexes: the presence of electron rich groups at the proximal substitutions resulted in lower oxidation potentials, higher HOMO levels, red-shifted absorption and lower optical gap than distal substitutions, and the effect was greater for hexyloxy than hexyl. Upon thermal annealing, films of the hexyloxy-substituted complexes strongly aggregated and showed crystal features under a polarized microscope, indicating that hexyloxy groups drive ordered self-assembly, especially when placed on distal phenyls. The ability to guide solid-state self-assembly of these non-planar chromophores using solubilizing groups have the potential to improve their charge carrier mobility and performance in opto-electronic applications such as organic solar cells, and photodetectors. 

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2. Synthesis, characterization, and photophysical properties of bismetalated platinum complexes with benzothiophene ligands

   https://doi.org/10.1016/j.jorganchem.2018.12.010  

   Anderson, Craig M.; Mastrocinque, Claudio; Greenberg, Matthew W.; McClellan, Ian C.; Duman, Leila; Oh, Nathaniel; Mastrocinque, Francesco; Pizzuto, Michael; Tran, Kaylynn; Tanski, Joseph M. (March 2019, Journal of Organometallic Chemistry)
3. Tuning the Properties of Azadipyrromethene-Based Near-Infrared Dyes Using Intramolecular BO Chelation and Peripheral Substitutions

   https://doi.org/10.1021/acs.inorgchem.1c01597  

   Jimenez, Jayvic C.; Zhou, Zehao; Rheingold, Arnold L.; Parker, Shane M.; Sauvé, Geneviève (September 2021, Inorganic Chemistry)
4. Synthesis and Catalytic Properties of Dirhodium Paddlewheel Complexes with Tethered, Axially Coordinating Thioether Ligands

   https://doi.org/10.1021/acs.inorgchem.8b02627  

   Anderson, Bradley G.; Cressy, Derek; Patel, Jay J.; Harris, Caleb F.; Yap, Glenn P.; Berry, John F.; Darko, Ampofo (January 2019, Inorganic Chemistry)
5. Synthesis, Structures, and Catalytic Properties of Dinuclear Iridium(I) Complexes with a Hexadentate Macrocyclic Diamine-Tetracarbene Ligand: Synthesis, Structures, and Catalytic Properties of Dinuclear Iridium(I) Complexes with a Hexadentate Macrocyclic Diamine-Tetracarbene Ligand

   https://doi.org/10.1002/ejic.201800088  

   Fei, Fan; Lu, Taotao; Yang, Chu-Fan; Chen, Xue-Tai; Xue, Zi-Ling (April 2018, European Journal of Inorganic Chemistry)