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1. HCN and HCO ⁺ in Planetary Nebulae: The Next Level

   https://doi.org/10.3847/1538-4357/ac4474  

   Schmidt, D. R.; Gold, K. R.; Sinclair, A.; Bergstrom, S.; Ziurys, L. M. (March 2022, The Astrophysical Journal)

   Abstract Observations of HCN and HCO + have been carried out toward 13 planetary nebulae (PNe) using the facilities of the Arizona Radio Observatory (ARO). These nebulae represent a wide range of morphologies and ages (∼2000–28,000 yr). For both molecules, the J = 1 → 0 transitions at 88–89 GHz and the J = 3 → 2 lines at 265–267 GHz were measured, together with CO lines ( J = 1 → 0, 2 → 1, and 3 → 2, depending on the source), using the ARO 12 m and Submillimeter Telescopes. HCN and HCO + were detected with at least one transition in 10 nebulae: He 2-459, Hu 1-1, K3-52, K3-65, M1-8, M1-40, M1-59, M2-53, M4-17, and NGC 6445. HCO + was additionally identified via two transitions in Na 2. Some observed line profiles were complex, with multiple velocity components tracing varied outflows. From radiative transfer modeling, column densities were established for HCN and HCO + : N tot (HCN) = 0.005–1.1 × 10 14 and N tot (HCO + ) = 0.008–9.5 × 10 13 cm −2 . Gas densities of n (H 2 ) ∼ 10 5 –10 7 cm −3 were also determined for all PNe. Fractional abundances with respect to H 2 , calculated using CO as a proxy, are f (HCN) ∼ 0.2–1.5 × 10 −7 and f (HCO + ) ∼ 0.3–5.1 × 10 −8 . The abundances of HCN and HCO + did not significantly vary with nebular age to 28,000 yr. Combined with previous observations, at least 30 PNe contain HCN and/or HCO + , indicating that polyatomic molecules are common constituents of these objects. The data strongly support a scenario where dense ejecta from PNe seed the interstellar medium with molecular material. 

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2. Sub-kiloparsec empirical relations and excitation conditions of HCN and HCO ⁺ J = 3–2 in nearby star-forming galaxies

   https://doi.org/10.1051/0004-6361/202244317  

   García-Rodríguez, A; Usero, A; Leroy, A K; Bigiel, F; Jiménez-Donaire, M J; Liu, D; Querejeta, M; Saito, T; Schinnerer, E; Barnes, A; et al (April 2023, Astronomy & Astrophysics)

   We present new HCN and HCO⁺(J= 3–2) images of the nearby star-forming galaxies (SFGs) NGC 3351, NGC 3627, and NGC 4321. The observations, obtained with the Morita ALMA Compact Array, have a spatial resolution of ∼290–440 pc and resolve the innerR_gal ≲ 0.6–1 kpc of the targets, as well as the southern bar end of NGC 3627. We complement this data set with publicly available images of lower excitation lines of HCN, HCO⁺, and CO and analyse the behaviour of a representative set of line ratios: HCN(3–2)/HCN(1–0), HCN(3–2)/HCO⁺(3–2), HCN(1–0)/CO(2–1), and HCN(3–2)/CO(2–1). Most of these ratios peak at the galaxy centres and decrease outwards. We compare the HCN and HCO⁺observations with a grid of one-phase, non-local thermodynamic equilibrium (non-LTE) radiative transfer models and find them compatible with models that predict subthermally excited and optically thick lines. We study the systematic variations of the line ratios across the targets as a function of the stellar surface density (Σ_star), the intensity-weighted CO(2–1) (⟨I_CO⟩), and the star formation rate surface density (Σ_SFR). We find no apparent correlation with Σ_SFR, but positive correlations with the other two parameters, which are stronger in the case of ⟨I_CO⟩. The HCN/CO–⟨I_CO⟩ relations show ≲0.3 dex galaxy-to-galaxy offsets, with HCN(3–2)/CO(2–1)–⟨I_CO⟩ being ∼2 times steeper than HCN(1–0)/CO(2–1). In contrast, the HCN(3–2)/HCN(1–0)–⟨I_CO⟩ relation exhibits a tighter alignment between galaxies. We conclude that the overall behaviour of the line ratios cannot be ascribed to variations in a single excitation parameter (e.g., density or temperature). 

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3. Physical and Chemical Properties of Galactic Molecular Gas toward QSO J1851+0035

   https://doi.org/10.3847/1538-4357/ad3d5b  

   Narita, Kanako; Sakamoto, Seiichi; Koda, Jin; Yoshimura, Yuki; Kohno, Kotaro (July 2024, The Astrophysical Journal)

   Abstract Atacama Large Millimeter/submillimeter Array (ALMA) data toward QSO J1851+0035 (l= 33.°498,b= +0.°194) were used to study absorption lines by Galactic molecular gas. We detected 17 species (CO,¹³CO, C¹⁸O, HCO⁺, H¹³CO⁺, HCO, H₂CO, C₂H,c-C₃H,c-C₃H₂, CN, HCN, HNC, CS, SO, SiO, and C) and set upper limits to 18 species as reference values for chemical models. About 20 independent velocity components at 4.7–10.9 kpc from the Galactic center were identified. Their column density and excitation temperature estimated from the absorption study, as well as the CO intensity distributions obtained from the FUGIN survey, indicate that the components withτ≲1 correspond to diffuse clouds or cloud outer edges. Simultaneous multiple-Gaussian fitting of COJ= 1–0 andJ= 2–1 absorption lines shows that these are composed of narrow- and broad-line components. The kinetic temperature empirically expected from the high HCN/HNC isomer ratio (≳4) reaches ≳40 K and the corresponding thermal width accounts for the line widths of the narrow-line components. CN-bearing molecules and hydrocarbons have tight and linear correlations within the groups. The CO/HCO⁺abundance ratio showed a dispersion as large as 3 orders of magnitude with a smaller ratio in a smallerN(HCO⁺) (or lowerA_V) range. Some of the velocity components are detected in single-dish CO emission and ALMA HCO⁺absorption but without corresponding ALMA CO absorption. This may be explained by the mixture of clumpy CO emitters not resolved with the ∼1 pc single-dish beam surrounded by extended components with a very low CO/HCO⁺abundance ratio (i.e., CO-poor gas). 

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4. ALMA Imaging of a Galactic Molecular Outflow in NGC 4945

   https://doi.org/10.3847/1538-4357/ac2c08  

   Bolatto, Alberto D.; Leroy, Adam K.; Levy, Rebecca C.; Meier, David S.; Mills, Elisabeth A.; Thompson, Todd A.; Emig, Kimberly L.; Veilleux, Sylvain; Ott, Jürgen; Gorski, Mark; et al (December 2021, The Astrophysical Journal)

   Abstract We present the ALMA detection of molecular outflowing gas in the central regions of NGC 4945, one of the nearest starbursts and also one of the nearest hosts of an active galactic nucleus (AGN). We detect four outflow plumes in CO J = 3 − 2 at ∼0.″3 resolution that appear to correspond to molecular gas located near the edges of the known ionized outflow cone and its (unobserved) counterpart behind the disk. The fastest and brightest of these plumes has emission reaching observed line-of-sight projected velocities of over 450 km s −1 beyond systemic, equivalent to an estimated physical outflow velocity v ≳ 600 km s −1 for the fastest emission. Most of these plumes have corresponding emission in HCN or HCO + J = 4 − 3. We discuss a kinematic model for the outflow emission where the molecular gas has the geometry of the ionized gas cone and shares the rotation velocity of the galaxy when ejected. We use this model to explain the velocities we observe, constrain the physical speed of the ejected material, and account for the fraction of outflowing gas that is not detected due to confusion with the galaxy disk. We estimate a total molecular mass outflow rate M ̇ mol ∼ 20 M ⊙ yr −1 flowing through a surface within 100 pc of the disk midplane, likely driven by a combination of the central starburst and AGN. 

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5. A 2–3 mm high-resolution molecular line survey towards the centre of the nearby spiral galaxy NGC 6946

   https://doi.org/10.1051/0004-6361/202142624  

   Eibensteiner, C.; Barnes, A. T.; Bigiel, F.; Schinnerer, E.; Liu, D.; Meier, D. S.; Usero, A.; Leroy, A. K.; Rosolowsky, E.; Puschnig, J.; et al (March 2022, Astronomy & Astrophysics)

   The complex physical, kinematic, and chemical properties of galaxy centres make them interesting environments to examine with molecular line emission. We present new 2 − 4″ (∼75 − 150 pc at 7.7 Mpc) observations at 2 and 3 mm covering the central 50″ (∼1.9 kpc) of the nearby double-barred spiral galaxy NGC 6946 obtained with the IRAM Plateau de Bure Interferometer. We detect spectral lines from ten molecules: CO, HCN, HCO + , HNC, CS, HC 3 N, N 2 H + , C 2 H, CH 3 OH, and H 2 CO. We complemented these with published 1 mm CO observations and 33 GHz continuum observations to explore the star formation rate surface density Σ SFR on 150 pc scales. In this paper, we analyse regions associated with the inner bar of NGC 6946 – the nuclear region (NUC), the northern (NBE), and southern inner bar end (SBE) and we focus on short-spacing corrected bulk (CO) and dense gas tracers (HCN, HCO + , and HNC). We find that HCO + correlates best with Σ SFR , but the dense gas fraction ( f dense ) and star formation efficiency of the dense gas (SFE dense ) fits show different behaviours than expected from large-scale disc observations. The SBE has a higher Σ SFR , f dense , and shocked gas fraction than the NBE. We examine line ratio diagnostics and find a higher CO(2−1)/CO(1−0) ratio towards NBE than for the NUC. Moreover, comparison with existing extragalactic datasets suggests that using the HCN/HNC ratio to probe kinetic temperatures is not suitable on kiloparsec and sub-kiloparsec scales in extragalactic regions. Lastly, our study shows that the HCO + /HCN ratio might not be a unique indicator to diagnose AGN activity in galaxies. 

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