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1. Analyzing the Impact of Evolving Combustion Conditions on the Composition of Wildfire Emissions Using Satellite Data

   https://doi.org/10.1029/2023GL105811  

   Anderson, Lindsey D.; Dix, Barbara; Schnell, Jordan; Yokelson, Robert; Veefkind, J. Pepijn; Ahmadov, Ravan; de Gouw, Joost (December 2023, Geophysical Research Letters)

   Abstract Wildfires have become larger and more frequent because of climate change, increasing their impact on air pollution. Air quality forecasts and climate models do not currently account for changes in the composition of wildfire emissions during the commonly observed progression from more flaming to smoldering combustion. Laboratory measurements have consistently shown decreased nitrogen dioxide (NO₂) relative to carbon monoxide (CO) over time, as they transitioned from more flaming to smoldering combustion, while formaldehyde (HCHO) relative to CO remained constant. Here, we show how daily ratios between column densities of NO₂versus those of CO and HCHO versus CO from the Tropospheric Monitoring Instrument (TROPOMI) changed for large wildfires in the Western United States. TROPOMI‐derived emission ratios were lower than those from the laboratory. We discuss reasons for the discrepancies, including how representative laboratory burns are of wildfires, the effect of aerosols on trace gas retrievals, and atmospheric chemistry in smoke plumes. 

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2. Wintertime Abundance and Sources of Key Trace Gas and Particle Species in Fairbanks, Alaska

   https://doi.org/10.1029/2025JD043677  

   Ketcherside, Damien T; Yokelson, Robert J; Selimovic, Vanessa; Robinson, Ellis S; Cesler‐Maloney, Meeta; Holen, Andrew L; Wu, Judy; Temime‐Roussel, Brice; Ijaz, Amna; Kuhn, Jonas; et al (August 2025, Journal of Geophysical Research: Atmospheres)

   Abstract We investigated how various sources contributed to observations of over 40 trace gas and particulate species in a typical Fairbanks residential neighborhood during the Alaskan Layered Pollution and Chemical Analysis campaign in January–February 2022. Aromatic volatile organic compounds (VOCs) accounted for ∼50% of measured VOCs (molar ratio), while methanol and ethanol accounted for ∼34%. The total wintertime VOC burden and contribution from aromatics were much higher than other US urban areas. Based on diel cycles and positive matrix factorization (PMF) analyses, we find traffic was the largest source of NO, CO, black carbon, and aromatic VOCs. Formic and acetic acid, hydroxyacetone, furanoids, and other VOCs were primarily attributed to residential wood combustion (RWC). Formaldehyde was one of several VOCs featuring significant contributions from multiple sources: RWC (∼35%), aging (∼30%), traffic (∼21%), and heating oil combustion (HO, ∼14%). PMF solutions assigned primary fine particulate matter to RWC (10%–30%), traffic (25%–40%), and HO (30%–60%), the latter likely reflecting high sulfur emissions from older furnaces and fast secondary chemistry. Despite cold and dark conditions, secondary processes impacted many trace gas and particle species' budget by ±10%–20% and more in some cases. Transport of O₃‐rich regional air into Fairbanks contributed to aging, specifically NO₃radical formation. This work highlights a long‐term trend observed in Fairbanks: increasing traffic and decreasing RWC relative contributions as total pollution decreases. Fairbanks exports a relatively fresh pollutant mixture to the regional arctic, the fate of which warrants future study. 

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3. Emissions of Aerospace Fuels F-24 and Jet-A in a Jet Engine and Correlation with Combustion Characteristics from a Constant Volume Combustion Chamber

   https://doi.org/10.4271/2023-01-1666  

   Soloiu, Valentin; Rowell, Aidan; Weaver, Amanda; Mcafee, John; Willis, James; O'Brien, Brandon (October 2023, SAE Transactions)

   SAE, Transactions (Ed.)

   An investigation into emissions differences and their correlations with differing combustion characteristics between F24 and Jet-A was conducted. Raw emissions data was taken from a single stage jet engine by a FTIR gas analyzer. Measurements of H₂O, CO₂, CO, NOx, and total hydrocarbon emissions (THC) were taken at 60K, 65K, and 70K RPM. At 70K RPM Jet-A and F-24 the emissions were similar at approx.: 4% H₂O, 3% CO₂, 970 PPM CO, 28 PPM NOx. Jet-A THC emissions were approx.: 1200 PPM THC, F24 THC emissions were lower by over 60%. The significantly lower amount of THC emissions for F24 suggests more complete combustion compared to Jet-A. 

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4. Effect of Methane on Combustion of Glycerol and Methanol Blends Using a Novel Swirl Burst Injector in a Model Dual-Fuel Gas Turbine Combustor

   https://doi.org/10.3390/cleantechnol6040069  

   Islam, S_M Rafiul; Patel, Ishaan; Jiang, Lulin (December 2024, Clean Technologies)

   Glycerol, a byproduct of biodiesel, has moderate energy but high viscosity, making clean combustion challenging. Quickly evaporating fine fuel sprays mix well with air and burn cleanly and efficiently. Unlike conventional air-blast atomizers discharging a jet core/film, a newly developed swirl burst (SB) injector generates fine sprays at the injector’s immediate exit, even for high-viscosity fuels, without preheating, using a unique two-phase atomization mechanism. It thus resulted in ultra-clean combustion for glycerol/methanol (G/M) blends, with complete combustion for G/M of 50/50 ratios by heat release rate (HRR). Lower combustion efficiencies were observed for G/M 60/40 and 70/30, representing crude glycerol. Hence, this study investigates the effect of premixed methane amount from 0–3 kW, and the effect of atomizing gas to liquid mass ratio (ALR) on the dual-fuel combustion efficiency of G/M 60/40-methane in a 7-kW lab-scale swirl-stabilized gas turbine combustor to facilitate crude glycerol use. Results show that more methane and increased ALR cause varying flame lift-off height, length, and gas product temperature. Regardless, mainly lean-premixed combustion, near-zero CO and NOx emissions (≤2 ppm), and ~100% combustion efficiency are enabled for all the cases by SB atomization with the assistance of a small amount of methane. 

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5. Cold Molecular Gas in Merger Remnants. II. The Properties of Dense Molecular Gas

   https://doi.org/10.3847/1538-4365/ac257a  

   Ueda, Junko; Iono, Daisuke; Yun, Min S; Michiyama, Tomonari; Watanabe, Yoshimasa; Snell, Ronald L; Rosa-González, Daniel; Saito, Toshiki; Vega, Olga; Yamashita, Takuji (December 2021, The Astrophysical Journal Supplement Series)

   Abstract We present the 3 mm wavelength spectra of 28 local galaxy merger remnants obtained with the Large Millimeter Telescope. Sixteen molecular lines from 14 different molecular species and isotopologues were identified, and 21 out of 28 sources were detected in one or more molecular lines. On average, the line ratios of the dense gas tracers, such as HCN (1–0) and HCO⁺(1–0), to¹³CO (1–0) are 3–4 times higher in ultra/luminous infrared galaxies (U/LIRGs) than in non-LIRGs in our sample. These high line ratios could be explained by the deficiency of¹³CO and high dense gas fractions suggested by high HCN (1–0)/¹²CO (1–0) ratios. We calculate the IR-to-HCN (1–0) luminosity ratio as a proxy of the dense gas star formation efficiency. There is no correlation between the IR/HCN ratio and the IR luminosity, while the IR/HCN ratio varies from source to source ((1.1–6.5) × 10³L_☉/(K km s⁻¹pc²)). Compared with the control sample, we find that the average IR/HCN ratio of the merger remnants is higher by a factor of 2–3 than those of the early/mid-stage mergers and nonmerging LIRGs, and it is comparable to that of the late-stage mergers. The IR-to-¹²CO (1–0) ratios show a similar trend to the IR/HCN ratios. These results suggest that star formation efficiency is enhanced by the merging process and maintained at high levels even after the final coalescence. The dynamical interactions and mergers could change the star formation mode and continue to impact the star formation properties of the gas in the postmerger phase. 

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