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Title: Manipulating nonadiabatic conical intersection dynamics by optical cavities
Optical cavities hold great promise to manipulate and control the photochemistry of molecules. We demonstrate how molecular photochemical processes can be manipulated by strong light–matter coupling. For a molecule with an inherent conical intersection, optical cavities can induce significant changes in the nonadiabatic dynamics by either splitting the pristine conical intersections into two novel polaritonic conical intersections or by creating light-induced avoided crossings in the polaritonic surfaces. This is demonstrated by exact real-time quantum dynamics simulations of a three-state two-mode model of pyrazine strongly coupled to a single cavity photon mode. We further explore the effects of external environments through dissipative polaritonic dynamics computed using the hierarchical equation of motion method. We find that cavity-controlled photochemistry can be immune to external environments. We also demonstrate that the polariton-induced changes in the dynamics can be monitored by transient absorption spectroscopy.
Authors:
;
Award ID(s):
1663822
Publication Date:
NSF-PAR ID:
10174895
Journal Name:
Chemical Science
Volume:
11
Issue:
5
Page Range or eLocation-ID:
1290 to 1298
ISSN:
2041-6520
Sponsoring Org:
National Science Foundation
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