Infrared and Raman spectroscopy techniques were applied to investigate the drying
and aggregation behavior of Nafion ionomer particles dispersed in aqueous solution. Gravimetric measurements aided the identification of gel-phase development within a series of time-resolved spectra that tracked transformations of a dispersion sample during solvent evaporation. A spectral band characteristic of ionomer sidechain end group vibration provided a quantitative probe of the dispersion-to-gel change. For sets of attenuated total reflection Fourier transform infrared (ATR-FTIR) spectra, adherence to Beer’s law was attributed to the relatively constant refractive index in the frequency region of hydrated -SO3
- group vibrations as fluorocarbon-rich ionomer regions aggregate in forming the structural framework of membranes and thin films. Although vibrational bands associated with ionomer backbone CF2 stretching vibrations were affected by distortion characteristic of wavelength-dependent refractive index change within a sample, the onset of band distortion signaled gel formation and coincided with ionomer mass % values just below the critical gelation point for Nafion aqueous dispersions. Similar temporal behavior was observed in confocal Raman microscopy experiments that monitored the formation of a thin ionomer film from an individual dispersion droplet. For the ATR FTIR spectroscopy and confocal Raman microscopy techniques, intensity in the water H-O-H bending vibrational band dropped sharply at the ionomer critical gelation point and displayed a time dependence consistent with changes in water content derived from gravimetric measurements. The reported studies lay groundwork for examining the impact of dispersing solvents and above-ambient temperatures on fluorinated ionomer transformations that influence structural properties of dispersion-cast membranes and thin films.
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Mechanism and control of “coffee-ring erosion” phenomena in structurally colored ionomer films
Ionomer polyesters have polymer backbones functionalized with charged groups that make them water-dispersible. Despite the widespread use of ionomer polymers in environmentally friendly coatings without volatile organic solvents, the fundamental understanding of their film formation properties is still limited. In the study, we deposited polyester nanofilms of brilliant structural colors and correlated the macroscale optical properties to the microscale thickness of the thin films. We found that sessile water droplets deposited on these films drive the formation of a rich variety of structures by an evaporation-induced effect of “coffee-ring erosion”. The ionomers spontaneously get partially re-dispersed in the form of nanoparticles in the sessile droplets and driven by convective evaporation flows, become redistributed in multiple colorful ring patterns. By using the structural colors as means to follow the polymer redistribution, we characterized further the coffee-ring patterns and found that the generated patterns are dictated by polymer composition but are mostly independent on molecular weight. As expected by colloidal theory, this phenomenon was suppressed in presence of electrolytes. Furthermore, we show that the integrity of these thin polyester films can be significantly improved by thermal densification without any further chemical curing.
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- Award ID(s):
- 1825476
- NSF-PAR ID:
- 10175735
- Date Published:
- Journal Name:
- Soft Matter
- Volume:
- 16
- Issue:
- 11
- ISSN:
- 1744-683X
- Page Range / eLocation ID:
- 2683 to 2694
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/C9SM02457C
