More Like this

1. Three-Fold Intramolecular Ring Closing Alkene Metatheses of Square Planar Complexes with cis Phosphorus Donor Ligands P(X(CH 2 ) m CH═CH 2 ) 3 (X = −, m = 5–10; X = O, m = 3–5): Syntheses, Structures, and Thermal Properties of Macrocyclic Dibridgehead Diphosphorus Complexes

   https://doi.org/10.1021/jacs.8b02846  

   Joshi, Hemant ; Kharel, Sugam ; Ehnbom, Andreas ; Skopek, Katrin ; Hess, Gisela D. ; Fiedler, Tobias ; Hampel, Frank ; Bhuvanesh, Nattamai ; Gladysz, John A. ( June 2018 , Journal of the American Chemical Society)
2. M x La 1–x SiO 2–y N z ( M = Ca/Sr/Ba): Elucidating and Tuning the Structure and Eu 2+ Local Environments to Develop Full-Visible Spectrum Phosphors

   https://doi.org/10.1021/acs.chemmater.2c00252  

   Amachraa, Mahdi ; Li, Shuxing ; Huang, Po-Yuan ; Liu, Ru-Shi ; Wang, Zhenbin ; Xie, Rong-Jun ; Ong, Shyue Ping ( May 2022 , Chemistry of Materials)
3. Crystal structures of two copper(I)–6,6′-dimethyl-2,2′-bipyridyl (dmbpy) compounds, [Cu(dmbpy) 2 ] 2 [ M F 6 ]· x H 2 O ( M = Zr, Hf; x = 1.134, 0.671)

   https://doi.org/10.1107/S2056989021007295  

   Wang, Yiran ; Nisbet, Matthew L. ; Poeppelmeier, Kenneth R. ( August 2021 , Acta Crystallographica Section E Crystallographic Communications)

   The syntheses and crystal structures of two bimetallic molecular compounds, namely, bis[bis(6,6′-dimethyl-2,2′-bipyridine)copper(I)] hexafluoridozirconate(IV) 1.134-hydrate, [Cu(dmbpy) 2 ] 2 [ZrF 6 ]·1.134H 2 O (dmbpy = 6,6′-dimethyl-2,2′-bipyridyl, C 12 H 12 N 2 ), (I), and bis[bis(6,6′-dimethyl-2,2′-bipyridine)copper(I)] hexafluoridohafnate(IV) 0.671-hydrate, [Cu(dmbpy) 2 ] 2 [HfF 6 ]·0.671H 2 O, (II), are reported. Apart from a slight site occupany difference for the water molecule of crystallization, compounds (I) and (II) are isostructural, featuring isolated tetrahedral cations of copper(I) ions coordinated by two dmbpy ligands and centrosymmetric, octahedral anions of fluorinated early transition metals. The tetrahedral environments of the copper complexes are distorted owing to the steric effects of the dmbpy ligands. The extended structures are built up through Coulombic interactions between cations and anions and π–π stacking interactions between heterochiral Δ- and Λ-[Cu(dmbpy) 2 ] + complexes. A comparison between the title compounds and other [Cu(dmbpy) 2 ] + compounds with monovalent and bivalent anions reveals a significant influence of the cation-to-anion ratio on the resulting crystal packing architectures, providing insights for future crystal design of distorted tetrahedral copper compounds. 

   more » « less
4. Not Just Par for the Course: 73 Quaternary Germanides RE 4 M 2 X Ge 4 ( RE = La–Nd, Sm, Gd–Tm, Lu; M = Mn–Ni; X = Ag, Cd) and the Search for Intermetallics with Low Thermal Conductivity

   https://doi.org/10.1021/acs.inorgchem.8b02279  

   Zhang, Dong ; Oliynyk, Anton O. ; Duarte, Gabriel M. ; Iyer, Abishek K. ; Ghadbeigi, Leila ; Kauwe, Steven K. ; Sparks, Taylor D. ; Mar, Arthur ( November 2018 , Inorganic Chemistry)
5. P 2 S 5 Reactive Flux Method for the Rapid Synthesis of Mono- and Bimetallic 2D Thiophosphates M 2–x M′ x P 2 S 6

   https://doi.org/10.1021/acs.inorgchem.0c03577  

   Chica, Daniel G. ; Iyer, Abishek K. ; Cheng, Matthew ; Ryan, Kevin M. ; Krantz, Patrick ; Laing, Craig ; dos Reis, Roberto ; Chandrasekhar, Venkat ; Dravid, Vinayak P. ; Kanatzidis, Mercouri G. ( March 2021 , Inorganic Chemistry)

   null (Ed.)