More Like this

1. Mixed norm H ₂ / H _∞ and entropy covariance control: a convex optimisation approach

   https://doi.org/10.1080/00207179.2020.1833251  

   Haddad, Wassim M.; Lanchares, Manuel; Chen, Yongxin (January 2020, International Journal of Control)

   null (Ed.)
2. H ₂ evolution from H ₂ O via O–H oxidative addition across a 9,10-diboraanthracene

   https://doi.org/10.1039/D0CC05261B  

   Taylor, Jordan W.; Harman, W. Hill (November 2020, Chemical Communications)

   null (Ed.)

   The water reactivity of the boroauride complex ([Au(B 2 P 2 )][K(18-c-6)]; (B 2 P 2 , 9,10-bis(2-(diisopropylphosphino)-phenyl)-9,10-dihydroboranthrene) and its corresponding two-electron oxidized complex, Au(B 2 P 2 )Cl, are presented. Au(B 2 P 2 )Cl is tolerant to H 2 O and forms the hydroxide complex Au(B 2 P 2 )OH in the presence of H 2 O and triethylamine. [Au(B 2 P 2 )]Cl and [Au(B 2 P 2 )]OH are poor Lewis acids as judged by the Gutmann–Becket method, with [Au(B 2 P 2 )]OH displaying facile hydroxide exchange between B atoms of the DBA ring as evidenced by variable temperature NMR spectroscopy. The reduced boroauride complex [Au(B 2 P 2 )] − reacts with 1 equivalent of H 2 O to produce a hydride/hydroxide product, [Au(B 2 P 2 )(H)(OH)] − , that rapidly evolves H 2 upon further H 2 O reaction to yield the dihydroxide compound, [Au(B 2 P 2 )(OH) 2 ] − . [Au(B 2 P 2 )]Cl can be regenerated from [Au(B 2 P 2 )(OH) 2 ] − via HCl·Et 2 O, providing a synthetic cycle for H 2 evolution from H 2 O enabled by O–H oxidative addition at a diboraanthracene unit. 

   more » « less
3. Phase Behavior and Superprotonic Conductivity in the System (1– x )CsH ₂ PO ₄ – x H ₃ PO ₄ : Discovery of Off-Stoichiometric α-[Cs _1–x H _x ]H ₂ PO ₄

   https://doi.org/10.1021/acs.chemmater.1c04061  

   Wang, Louis S.; Patel, Sawankumar V.; Truong, Erica; Hu, Yan-Yan; Haile, Sossina M. (February 2022, Chemistry of Materials)
4. Topological Evidence of Previously Overlooked N _i+1 –H···N _i H-Bonds and Their Contribution to Protein Structure and Stability

   https://doi.org/10.1021/acs.jpca.7b11013  

   Holcomb, Matthew; Adhikary, Ramkrishna; Zimmermann, Jörg; Romesberg, Floyd E. (December 2017, The Journal of Physical Chemistry A)
5. Millimeter/Submillimeter-wave Spectroscopy and the Semi-experimental Equilibrium ( r _e ^SE ) Structure of 1 H -1,2,4-Triazole ( c -C ₂ H ₃ N ₃ )

   https://doi.org/10.1021/acs.jpca.2c06038  

   Bunn, Hayley A.; Esselman, Brian J.; Franke, Peter R.; Kougias, Samuel M.; McMahon, Robert J.; Stanton, John F.; Widicus Weaver, Susanna L.; Woods, R. Claude (November 2022, The Journal of Physical Chemistry A)