Abstract Diamond color centers have been widely studied in the field of quantum optics. The negatively charged silicon vacancy (SiV − ) center exhibits a narrow emission linewidth at the wavelength of 738 nm, a high Debye–Waller factor, and unique spin properties, making it a promising emitter for quantum information technologies, biological imaging, and sensing. In particular, nanodiamond (ND)-based SiV − centers can be heterogeneously integrated with plasmonic and photonic nanostructures and serve as in vivo biomarkers and intracellular thermometers. Out of all methods to produce NDs with SiV − centers, ion implantation offers the unique potential to create controllable numbers of color centers in preselected individual NDs. However, the formation of single color centers in NDs with this technique has not been realized. We report the creation of single SiV − centers featuring stable high-purity single-photon emission through Si implantation into NDs with an average size of ∼20 nm. We observe room temperature emission, with zero-phonon line wavelengths in the range of 730–800 nm and linewidths below 10 nm. Our results offer new opportunities for the controlled production of group-IV diamond color centers with applications in quantum photonics, sensing, and biomedicine.
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Narrow-Linewidth Tin-Vacancy Centers in a Diamond Waveguide
Integrating solid-state quantum emitters with photonic circuits
is essential for realizing large-scale quantum photonic processors. Negatively
charged tin-vacancy (SnV−) centers in diamond have emerged as promising
candidates for quantum emitters because of their excellent optical and spin
properties, including narrow-linewidth emission and long spin coherence times.
SnV− centers need to be incorporated in optical waveguides for efficient onchip
routing of the photons they generate. However, such integration has yet to
be realized. In this Letter, we demonstrate the coupling of SnV− centers to a
nanophotonic waveguide. We realize this device by leveraging our recently
developed shallow ion implantation and growth method for the generation of
high-quality SnV− centers and the advanced quasi-isotropic diamond
fabrication technique. We confirm the compatibility and robustness of these
techniques through successful coupling of narrow-linewidth SnV− centers (as
narrow as 36 ± 2 MHz) to the diamond waveguide. Furthermore, we investigate the stability of waveguide-coupled SnV− centers
under resonant excitation. Our results are an important step toward SnV−-based on-chip spin-photon interfaces, single-photon
nonlinearity, and photon-mediated spin interactions.
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- Award ID(s):
- 1838976
- NSF-PAR ID:
- 10191909
- Date Published:
- Journal Name:
- ACS Photonics
- ISSN:
- 2330-4022
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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A central challenge in quantum networking is transferring quantum states between different physical modalities, such as between flying photonic qubits and stationary quantum memories. One implementation entails using spin–photon interfaces that combine solid-state spin qubits, such as color centers in diamond, with photonic nanostructures. However, while high-fidelity spin–photon interactions have been demonstrated on isolated devices, building practical quantum repeaters requires scaling to large numbers of interfaces yet to be realized. Here, we demonstrate integration of nanophotonic cavities containing tin-vacancy (SnV) centers in a photonic integrated circuit (PIC). Out of a six-channel quantum microchiplet (QMC), we find four coupled SnV-cavity devices with an average Purcell factor of ∼7. Based on system analyses and numerical simulations, we find with near-term improvements this multiplexed architecture can enable high-fidelity quantum state transfer, paving the way toward building large-scale quantum repeaters.
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Abstract Single-photon defect emitters (SPEs), especially those with magnetically and optically addressable spin states, in technologically mature wide bandgap semiconductors are attractive for realizing integrated platforms for quantum applications. Broadening of the zero phonon line (ZPL) caused by dephasing in solid state SPEs limits the indistinguishability of the emitted photons. Dephasing also limits the use of defect states in quantum information processing, sensing, and metrology. In most defect emitters, such as those in SiC and diamond, interaction with low-energy acoustic phonons determines the temperature dependence of the dephasing rate and the resulting broadening of the ZPL with the temperature obeys a power law. GaN hosts bright and stable single-photon emitters in the 600–700 nm wavelength range with strong ZPLs even at room temperature. In this work, we study the temperature dependence of the ZPL spectra of GaN SPEs integrated with solid immersion lenses with the goal of understanding the relevant dephasing mechanisms. At temperatures below ~ 50 K, the ZPL lineshape is found to be Gaussian and the ZPL linewidth is temperature independent and dominated by spectral diffusion. Above ~ 50 K, the linewidth increases monotonically with the temperature and the lineshape evolves into a Lorentzian. Quite remarkably, the temperature dependence of the linewidth does not follow a power law. We propose a model in which dephasing caused by absorption/emission of optical phonons in an elastic Raman process determines the temperature dependence of the lineshape and the linewidth. Our model explains the temperature dependence of the ZPL linewidth and lineshape in the entire 10–270 K temperature range explored in this work. The ~ 19 meV optical phonon energy extracted by fitting the model to the data matches remarkably well the ~ 18 meV zone center energy of the lowest optical phonon band (
$$E_{2}(low)$$ $$E_{2}(low)$$ -
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Abstract Ultra-small mode volume nanophotonic crystal cavities have been proposed as powerful tools for increasing coupling rates in cavity quantum electrodynamics systems. However, their adoption in quantum information applications remains elusive. In this work, we investigate possible reasons why, and analyze the impact of different low mode volume resonator design choices on their utility in quantum optics experiments. We analyze band structure features and loss rates of low mode volume bowtie cavities in diamond and demonstrate independent design control over cavity-emitter coupling strength and loss rates. Further, using silicon vacancy centers in diamond as exemplary emitters, we investigate the influence of placement imprecision. We find that the benefit on photon collection efficiency and indistinguishability is limited, while the fabrication complexity of ultra-small cavity designs increases substantially compared to conventional photonic crystals. We conclude that ultra-small mode volume designs are primarily of interest for dispersive spin-photon interactions, which are of great interest for future quantum networks.
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Robust spin-photon interfaces in solids are essential components in quantum networking and sensing technologies. Ideally, these interfaces combine a long-lived spin memory, coherent optical transitions, fast and high-fidelity spin manipulation, and straightforward device integration and scaling. The tin-vacancy center (SnV) in diamond is a promising spin-photon interface with desirable optical and spin properties at 1.7 K. However, the SnV spin lacks efficient microwave control, and its spin coherence degrades with higher temperature. In this work, we introduce a new platform that overcomes these challenges—SnV centers in uniformly strained thin diamond membranes. The controlled generation of crystal strain introduces orbital mixing that allows microwave control of the spin state with 99.36(9)% gate fidelity and spin coherence protection beyond a millisecond. Moreover, the presence of crystal strain suppresses temperature-dependent dephasing processes, leading to a considerable improvement of the coherence time up to 223(10) μs at 4 K, a widely accessible temperature in common cryogenic systems. Critically, the coherence of optical transitions is unaffected by the elevated temperature, exhibiting nearly lifetime-limited optical linewidths. Combined with the compatibility of diamond membranes with device integration, the demonstrated platform is an ideal spin-photon interface for future quantum technologies.more » « less
- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1021/acsphotonics.0c00833
