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  • Synthesis of terpyridine-containing polycarbonates with post polymerization providing water-soluble and micellar polymers and their metal complexes
Title: Synthesis of terpyridine-containing polycarbonates with post polymerization providing water-soluble and micellar polymers and their metal complexes
Carbon dioxide based polymers synthesized from the metal-catalyzed copolymeriation of epoxides and CO 2 containing the terpyridine ligand as an end group are reported. The strategy used was to carry out the polymerization in the presence of a carboxylic acid derivative of terpyridine, 4′-(4-carboxyphenyl)-2,2′:6′,2′′-terpyridine (HL), as a chain transfer agent. The epoxide monomer possessing a vinyl substituent, allyl glycidyl ether (AGE), was copolymerized with CO 2 employing a (salen)Co( iii ) catalyst to afford a polycarbonate which upon the addition of mercaptoacetic acid across the double bond, followed by deprotonation, yielded a water soluble polymer. In a similar manner, the sequential formation of a diblock terpolymer produced from propylene oxide, AGE, and CO 2 provided a amphiphilic polycarbonate which self-assembled upon addition to water to form micelle nanostructures. The molecular weights of these CO 2 -derived polycarbonates were shown to be easily controlled by the quantity of chain transfer agent used. These polymeric ligands were demonstrated to provide a modular design for synthesizing a wide variety of metal complexes as illustrated herein for zinc and platinum derivatives.  more » « less
Award ID(s):
1665258
PAR ID:
10199345
Author(s) / Creator(s):
; ;
Date Published:
Journal Name:
Polymer Chemistry
Volume:
11
Issue:
29
ISSN:
1759-9954
Page Range / eLocation ID:
4699 to 4705
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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