skip to main content


Title: Magnesium‐Ion Batteries: High‐Rate and Long Cycle‐Life Alloy‐Type Magnesium‐Ion Battery Anode Enabled Through (De)magnesiation‐Induced Near‐Room‐Temperature Solid–Liquid Phase Transformation (Adv. Energy Mater. 45/2019)
Award ID(s):
1840672
NSF-PAR ID:
10200729
Author(s) / Creator(s):
; ; ; ; ; ;
Date Published:
Journal Name:
Advanced Energy Materials
Volume:
9
Issue:
45
ISSN:
1614-6832
Page Range / eLocation ID:
1970180
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Gas-phase ion-ion reactions between tris-1,10-phenantholine metal dications, [(phen)3M]2+ (where M = Ni and Mg), and the tetraphenylborate anion yield the ion-pairs {[(phen)3M]2+[BPh4]-}+. The ion-pairs undergo transmetalation upon loss of a phen ligand to give the organometallic complexes [(phen)2M(Ph)]+. DFT calculations, used to determine the energy barriers for the transmetalation reactions and the hydrolysis reactions, are entirely consistent with the experimental results. 
    more » « less
  2. null (Ed.)