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1. Kinetic surface control for improved magnesium-electrolyte interfaces for magnesium ion batteries

   https://doi.org/10.1016/j.ensm.2019.06.035  

   Li, Bin; Masse, Robert; Liu, Chaofeng; Hu, Yang; Li, Weishan; Zhang, Guoqing; Cao, Guozhong (November 2019, Energy Storage Materials)
2. Magnesium ion assignment and role in ribosome subunit rotation

   Wanes, George; Whitford, Paul C (February 2025, Biophysical Journal)
3. Application of Single-Ion Conducting Gel Polymer Electrolytes in Magnesium Batteries

   https://doi.org/10.1021/acsaem.9b00991  

   Merrill, Laura C.; Ford, Hunter O.; Schaefer, Jennifer L. (August 2019, ACS Applied Energy Materials)
4. Switchable inhibitory behavior of divalent magnesium ion in DNA hybridization-based gene quantification

   https://doi.org/10.1039/D2AN01164F  

   Jin, Hyowon; Lim, Hyun Jeong; Liles, Mark R.; Chua, Beelee; Son, Ahjeong (October 2022, The Analyst)

   Contrary to the understanding that divalent cations only result in under-estimation of gene quantification via DNA hybridization-based assays, we have discovered that Mg 2+ could cause either under or over-estimation at different concentrations. Its switchable inhibitory behavior is likely due to its rigid first solvation (hydrated) shell and hence it is inclined to form non-direct binding with DNA. At low concentrations, it caused under-estimation by occupying the hybridization sites. At high concentrations, it caused probe, signaling and target DNA to aggregate non-specifically via Coulomb forces. By quantifying target DNAs at a range of Mg 2+ concentrations using a gene quantification assay (NanoGene assay), a Mg 2+ inflection concentration of ∼10 −3 M was observed for both target ssDNA and dsDNA. Field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), and Fourier transform infrared spectroscopy (FT-IR) were employed to observe Mg 2+ -induced non-specific binding in the complexes that mimicked the presence of target DNA. Together with two other divalent cations Ca 2+ and Cu 2+ , they were further examined via zeta potential measurements as well as NanoGene assay. This study revealed the importance of Mg 2+ in achieving accurate gene quantification. Through a better mechanistic understanding of this phenomenon, it will be possible to develop strategies to mitigate the impact of Mg 2+ on DNA hybridization-based gene quantification. 

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5. Ion-pairs as a gateway to transmetalation: aryl transfer from boron to nickel and magnesium

   https://doi.org/10.1039/d2dt00746k  

   Fabijanczuk, Kimberly C.; Altalhi, Weam A.; Aldajani, Asma M.; Canty, Allan J.; McLuckey, Scott A.; O'Hair, Richard A. (April 2022, Dalton Transactions)

   Gas-phase ion-ion reactions between tris-1,10-phenantholine metal dications, [(phen)3M]2+ (where M = Ni and Mg), and the tetraphenylborate anion yield the ion-pairs {[(phen)3M]2+[BPh4]-}+. The ion-pairs undergo transmetalation upon loss of a phen ligand to give the organometallic complexes [(phen)2M(Ph)]+. DFT calculations, used to determine the energy barriers for the transmetalation reactions and the hydrolysis reactions, are entirely consistent with the experimental results. 

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