skip to main content
Explore Scholarly Publications and Datasets in the NSF-PAR

Title: Ionic Liquid Welding of the UIO-66-NH2 MOF to Cotton Textiles
Ionic liquid based fiber welding has been used to attach the metal−organic framework (MOF) UiO-66-NH2to cotton fibers. The results show that by controlling the extent of the welding process, it is possible to produce fibers that contain a high surface area (approximately 50−100 m2/ g), an X-ray diffraction pattern consistent with UiO-66-NH2, and fibers that are chemically reactive to dimethyl 4-nitrophenyl phosphate (DMNP), a common chemical weapon simulant. The ionic liquid/MOF welding solution can be applied by directly placing the fabric in the welding solution or by utilizing an airbrushing technique. Both welding techniques are shown to be scalable with results collected on approximately 1×1, 5 ×5, and 15.5×15.5 in. swatches. The results are also applicable to weaving methods where the MOF is welded to individual threads and subsequently woven into a textile. The results provide an industrially scalable method of attaching a wide variety of MOFs to cotton textiles, which does not require synthesizing the MOF in the presence of the textile.
Authors:
; ; ; ; ;
Award ID(s):
1726263
Publication Date:
NSF-PAR ID:
10207558
Journal Name:
Industrial engineering chemistry research
Volume:
59
Issue:
43
Page Range or eLocation-ID:
19285-19298
ISSN:
1520-5045
Sponsoring Org:
National Science Foundation
More Like this
  1. ; ; ; ; ( , Separation and purification technology)
    Defense against small molecule toxic gases is an important aspect of protection against chemical and biological threat as well as chemical releases from industrial accidents. Current protective respirators/garments cannot effectively block small molecule toxic gases and vapors and retain moisture transmission capability without a heavy burden. Here, we developed a nanopacked bed of nanoparticles of UiO-66-NH₂ metal organic framework (MOF) by synthesizing them in the pores of microporous expanded polytetrafluoroethylene (ePTFE) membranes. The submicron scale size of membrane pores ensures a large surface area of MOF nanoparticles which can capture/adsorb and react with toxic gas molecules efficiently. It was demonstratedmore »that the microporous ePTFE membrane with UiO-66-NH₂ MOF grown inside and around the membrane can defend against ammonia for a significant length of time while allowing passage of moisture and nitrogen. It was also demonstrated that the MOF-loaded ePTFE membrane could provide significant protection from Cl₂ intrusion as well as intrusion from 2-chloroethyl ethyl sulfide (CEES) (a simulant for sulfur mustard). Such MOF-filled membranes exhausted by NH₃ breakthrough experiments were regenerated conveniently by heating at 60 °C for one week under vacuum for further/repeated use; a single regenerated membrane could block NH₃ for 200–300 min. The moisture permeability of such a membrane/nanopacked bed was considerably above the breathability threshold value of 2000 g/m² -day. The results suggest that microporous membranes filled with reactive MOF nanoparticles could be designed as protective barriers against toxic gases/vapors, e.g., NH₃ and Cl₂ and yet be substantially permeable to H₂O and air.« less
  2. ( , ACS omega)
    Ionic liquids (ILs) are becoming important solvents in commerce, but monitoring their purity and performance in industrial applications presents new challenges. Fiber welding technology utilizes ILs to mold and shape natural fibers (cotton, hemp, flax, silk, and wool) into morphologies that are typically attained only using synthetic, petroleum-based non-biodegradable plastics. The result is an atom-efficient process that up-converts fibrous substrates to value-added products and materials. A key aspect of bringing this and other IL-enabled technologies to market relies on efficient monitoring and recycling of IL-based solvents. Implementing online IL quality monitoring enhances the unit economics of these processes. Here, wemore »characterize and report conductivity measurements, refractometry, and ATR–FTIR spectroscopy techniques for online IL monitoring during an industrial fiber welding process. The online analysis enables more efficient recycling of the IL solvent, increasing the process efficiency and product quality.« less
  3. ; ( , Journal of Materials Chemistry A)
    Isothermal membrane-based air dehumidification (IMAD) is much more energy-efficient and economical than traditional air-dehumidification technologies. There are, however, no practical IMAD process technologies currently available mainly due to limitations of current membranes. Ionic liquids (ILs) are a promising air-dehumidification membrane material. Current supported IL membranes suffer from poor stability, limiting their performances. Herein, we propose new stable IL membranes, encapsulated IL membranes (EILMs) by encapsulating 1-butyl-3-methylimidazolium bromide ([C 4 MIM][Br]) into ultrathin polycrystalline UiO-66-NH 2 metal–organic framework membranes via a ship-in-a-bottle method. The stability of IL membranes is significantly enhanced due to the IL entrapped in the pore cages ofmore »UiO-66-NH 2 . The EILMs show unprecedentedly high H 2 O permeance (∼2.36 × 10 −4 mol m −2 s −1 Pa −1 ), an order of magnitude greater than that of the most permeable air-dehumidification membranes reported so far. Furthermore, the encapsulated [C 4 MIM][Br] drastically increases the H 2 O/N 2 separation factor to ∼1560, satisfying the minimally required H 2 O/N 2 separation performance for commercially viable air-dehumidification.« less
  4. ; ; ; ; ; ; ; ( , Environmental Science: Nano)
    With the increased bacteria-induced hospital-acquired infections (HAIs) caused by bio-contaminated surfaces, the requirement for a safer and more efficient antibacterial strategy in designing personal protective equipment (PPE) such as N95 respirators is rising with urgency. Herein, a self-decontaminating nanofibrous filter with a high particulate matter (PM) filtration efficiency was designed and fabricated via a facile electrospinning method. The fillers implemented in the electrospun nanofibers were constructed by grafting a layer of antibacterial polymeric quaternary ammonium compound (QAC), that is, poly[2-(dimethyl decyl ammonium) ethyl methacrylate] (PQDMAEMA), onto the surface of metal–organic framework (MOF, UiO-66-NH 2 as a model) to form themore »active composite UiO-PQDMAEMA. The UiO-PQDMAEMA filter demonstrates an excellent PM filtration efficiency (>95%) at the most penetrating particle size (MPPS) of 80 nm, which is comparable to that of the commercial N95 respirators. Besides, the UiO-PQDMAEMA filter is capable of efficiently killing both Gram-positive ( S. epidermidis ) and Gram-negative ( E. coli ) airborne bacteria. The strong electrostatic interactions between the anionic cell wall of the bacteria and positively charged nitrogen of UiO-PQDMAEMA are the main reasons for severe cell membrane disruption, which leads to the death of bacteria. The present work provides a new avenue for combating air contamination by using the QAC-modified MOF-based active filters.« less
  5. ; ; ; ; ; ; ( , Chemical Communications)
    Herein, a series of halogenated UiO-66 derivatives was synthesized and analyzed for the breakdown of the chemical warfare agent simulant dimethyl-4-nitrophenyl phosphate (DMNP) to analyze ligand effects. UiO-66-I degrades DMNP at a rate four times faster than the most active previously reported MOFs. MOF defects were quantified and ruled out as a cause for increased activity. Theoretical calculations suggest the enhanced activity of UiO-66-I originates from halogen bonding of the iodine atom to the phosphoester linkage allowing for more rapid hydrolysis of the P–O bond.
  • Citation Formats
  • MLA
  • APA
  • Chicago
  • BibTeX
  • Save / Share this Record
  • Send to Email