skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Universal scaling laws of keyhole stability and porosity in 3D printing of metals
Abstract Metal three-dimensional (3D) printing includes a vast number of operation and material parameters with complex dependencies, which significantly complicates process optimization, materials development, and real-time monitoring and control. We leverage ultrahigh-speed synchrotron X-ray imaging and high-fidelity multiphysics modeling to identify simple yet universal scaling laws for keyhole stability and porosity in metal 3D printing. The laws apply broadly and remain accurate for different materials, processing conditions, and printing machines. We define a dimensionless number, the Keyhole number, to predict aspect ratio of a keyhole and the morphological transition from stable at low Keyhole number to chaotic at high Keyhole number. Furthermore, we discover inherent correlation between keyhole stability and porosity formation in metal 3D printing. By reducing the dimensions of the formulation of these challenging problems, the compact scaling laws will aid process optimization and defect elimination during metal 3D printing, and potentially lead to a quantitative predictive framework.  more » « less
Award ID(s):
1762035 1934367
PAR ID:
10223238
Author(s) / Creator(s):
; ; ; ; ; ; ;
Publisher / Repository:
Nature Publishing Group
Date Published:
Journal Name:
Nature Communications
Volume:
12
Issue:
1
ISSN:
2041-1723
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Laser powder bed fusion is a dominant metal 3D printing technology. However, porosity defects remain a challenge for fatigue-sensitive applications. Some porosity is associated with deep and narrow vapor depressions called keyholes, which occur under high-power, low–scan speed laser melting conditions. High-speed x-ray imaging enables operando observation of the detailed formation process of pores in Ti-6Al-4V caused by a critical instability at the keyhole tip. We found that the boundary of the keyhole porosity regime in power-velocity space is sharp and smooth, varying only slightly between the bare plate and powder bed. The critical keyhole instability generates acoustic waves in the melt pool that provide additional yet vital driving force for the pores near the keyhole tip to move away from the keyhole and become trapped as defects. 
    more » « less
  2. Abstract The macro-porous ceramics has promising durability and thermal insulation performances. A cost-effective and scalable additive manufacturing technique for the fabrication of macro-porous ceramics, with a facile approach to control the printed porosity is reported in the paper. Several ceramic inks were prepared, the foaming agent was used to generate gaseous bubbles in the ink, followed by the direct ink writing and the ambient-pressure and room-temperature drying to create the three-dimensional geometries. The experimental studies were performed to optimize the printing quality. A set of studies revealed the optimal printing process parameters for printing the foamed ceramic ink with a high spatial resolution and fine surface quality. Varying the concentration of the foaming agent enabled the controllability of the structural porosity. The maximum porosity can reach 85%, with a crack-free internal porous structure. The tensile tests showed that the printed macro-porous ceramics have enhanced durability with the addition of fiber. With a high-fidelity 3D printing process and precise control of the porosity, the printed samples exhibited a low thermal conductivity and high mechanical strength. 
    more » « less
  3. Abstract The development of a general‐purpose machine learning algorithm capable of quickly identifying optimal 3D‐printing settings can save manufacturing time and cost, reduce labor intensity, and improve the quality of 3D‐printed objects. Existing methods have limitations which focus on overall performance or one specific aspect of 3D‐printing quality. Here, for addressing the limitations, a multi‐objective Bayesian Optimization (BO) approach which uses a general‐purpose algorithm to optimize the black‐box functions is demonstrated and identifies the optimal input parameters of direct ink writing for 3D‐printing different presurgical organ models with intricate geometry. The BO approach enhances the 3D‐printing efficiency to achieve the best possible printed object quality while simultaneously addressing the inherent trade‐offs from the process of pursuing ideal outcomes relevant to requirements from practitioners. The BO approach also enables us to effectively explore 3D‐printing inputs inclusive of layer height, nozzle travel speed, and dispensing pressure, as well as visualize the trade‐offs between each set of 3D‐printing inputs in terms of the output objectives which consist of time, porosity, and geometry precisions through the Pareto front. 
    more » « less
  4. Abstract Versatile printing of polymers, metals, and composites always calls for simple, economic approaches. Here we present an approach to three-dimensional (3D) printing of polymeric, metallic, and composite materials at room conditions, based on the polymeric vapor-induced phase separation (VIPS) process. During VIPS 3D printing (VIPS-3DP), a dissolved polymer-based ink is deposited in an environment where nebulized non-solvent is present, inducing the low-volatility solvent to be extracted from the filament in a controllable manner due to its higher chemical affinity with the non-solvent used. The polymeric phase is hardened in situ as a result of the induced phase separation process. The low volatility of the solvent enables its reclamation after the printing process, significantly reducing its environmental footprint. We first demonstrate the use of VIPS-3DP for polymer printing, showcasing its potential in printing intricate structures. We further extend VIPS-3DP to the deposition of polymer-based metallic inks or composite powder-laden polymeric inks, which become metallic parts or composites after a thermal cycle is applied. Furthermore, spatially tunable porous structures and functionally graded parts are printed by using the printing path to set the inter-filament porosity as well as an inorganic space-holder as an intra-filament porogen. 
    more » « less
  5. Heavy metal contamination is one of the leading causes of water pollution, with known adverse effects on human health and the environment. This work demonstrates a novel custom-made 3D printable eco-friendly hydrogel and fabrication process that produces stable biocompatible adsorbents with the ability to capture and remove heavy metals from aqueous environments quickly and economically. The 3D printable ink contains alginate, gelatin, and polyethyleneimine (PEI), which binds heavy metals through primary and secondary amine side chains favoring heavy metal adsorption. The ink's rheological properties are optimized to create mechanically stable constructs, in the form of 3D-printed tablets, fabricated entirely by printing. The optimized tablets have high porosity and accessible surface area with multiple binding sites for heavy metal ion adsorption while the printing process enables rapid and affordable production with the potential for scale-up. The results demonstrate the contribution of hydrogel composition and rheology in determining the printability, stability, and heavy metal binding characteristics of the hydrogel, and indicate the critical role of the PEI in increasing stability of the printed construct, in addition to its metal binding properties. The highest removal capacity was obtained for copper, followed by cadmium, cobalt, and nickel ions. In the optimized formulation, each hydrogel tablet removed 60% from 100 ppm copper in 5 h and up to 98% in 18 h. For more concentrated solutions (1000 ppm), ∼25% of copper was removed in 18 h. The printed tablets are stable, robust, and can be produced in a single simple step from inexpensive biomaterials. The ink's tunability, excellent printability, and stability offer a universally applicable procedure for creating hydrogel-based structures for environmental remediation. These unique capabilities open new avenues for manufacturing tailor-made constructs with integrated functionality for water treatment and environmental applications. 
    more » « less