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Title: Phase Stability and Thermal Equation of State of Iron Carbide Fe 3 C to 245 GPa
Abstract

We conducted shock wave experiments on iron carbide Fe3C up to a Hugoniot pressure of 245 GPa. The correlation between the particle velocity (up) and shock wave velocity (us) can be fitted into a linear relationship,us= 4.627(±0.073) + 1.614(±0.028)up. The density‐pressure relationship is consistent with a single‐phase compression without decomposition. The inference is further supported by the comparison of the observed Hugoniot density with the calculated Hugoniot curves of possible decomposition products. The new Hugoniot data combined with the reported 300‐K isothermal compression data yielded a Grüneisen parameter ofγ= 2.23(7.982/ρ)0.29. The thermal equation of state of Fe3C is further used to calculate the density profile of Fe3C along the Earth's adiabatic geotherm. The density of Fe3C was found to be too low (by ~5%) to match the observed density in the Earth's inner core, and Fe3C is unlikely a dominant component of the inner core.

 
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Award ID(s):
1619868
NSF-PAR ID:
10446330
Author(s) / Creator(s):
 ;  ;  ;  ;  ;  ;  ;  
Publisher / Repository:
DOI PREFIX: 10.1029
Date Published:
Journal Name:
Geophysical Research Letters
Volume:
46
Issue:
20
ISSN:
0094-8276
Page Range / eLocation ID:
p. 11018-11024
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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