Catalytic Deuteration of C(sp 2 )–H Bonds of Substituted (Hetero)arenes in a Pt(II) CNN-Pincer Complex/2,2,2-Trifluoroethanol- d 1 System: Effect of Substituents on the Reaction Rate and Selectivity
- Award ID(s):
- 1800089
- PAR ID:
- 10225091
- Date Published:
- Journal Name:
- Organometallics
- Volume:
- 39
- Issue:
- 22
- ISSN:
- 0276-7333
- Page Range / eLocation ID:
- 4102 to 4114
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract In this paper we consider the following problem: let X k , be a Banach space with a normalised basis ( e (k, j) ) j , whose biorthogonals are denoted by $${(e_{(k,j)}^*)_j}$$ , for $$k\in\N$$ , let $$Z=\ell^\infty(X_k:k\kin\N)$$ be their l ∞ -sum, and let $$T:Z\to Z$$ be a bounded linear operator with a large diagonal, i.e. , $$\begin{align*}\inf_{k,j} \big|e^*_{(k,j)}(T(e_{(k,j)})\big|>0.\end{align*}$$ Under which condition does the identity on Z factor through T ? The purpose of this paper is to formulate general conditions for which the answer is positive.more » « less
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