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1. Quantum-vibrational-state-selected Integral Cross Sections and Product Branching Ratios for the Ion-molecule Reactions of N ₂ ⁺ ( X ² Σ _g ⁺ ; v ⁺ = 0–2) + H ₂ O and H ₂ O ⁺ ( X ² B ₁ : v ₁ ⁺ v ₂ ⁺ v ₃ ⁺ = 000 and 100) + N ₂ in the Collision Energy Range of 0.04–10.00 eV

   https://doi.org/10.3847/1538-4357/aac9bf  

   Xu, Yuntao; Xiong, Bo; Chang, Yih Chung; Ng, Cheuk-Yiu (July 2018, The Astrophysical Journal)
2. Spinodal Decomposition During Anion Exchange in Colloidal Mn ²⁺ -Doped CsPbX ₃ (X = Cl, Br) Perovskite Nanocrystals

   https://doi.org/10.1021/acs.chemmater.9b02646  

   De Siena, Michael C.; Sommer, David E.; Creutz, Sidney E.; Dunham, Scott T.; Gamelin, Daniel R. (August 2019, Chemistry of Materials)
3. Clarification of Mn ²⁺ Doping of CH ₃ NH ₃ PbBr ₃ Perovskite Magic‐Sized Clusters

   https://doi.org/10.1002/cnma.202500288  

   Zeitz, David C; Creech, Sarah A; Khvichia, Mariam; Zhang, Jin Z (July 2025, ChemNanoMat)

   Mn²⁺doping of CsPbBr₃perovskite magic‐sized clusters (PMSCs) has been reported previously, where PMSCs with first excitonic absorption and photoluminescence (PL) around 425 nm were reported originally, followed by Mn²⁺‐doped PMSCs with host absorption and PL around 400 nm. There, the observed 25 nm blueshift was attributed to smaller PMSCs or the Cl⁻ions introduced by MnCl₂as dopant precursor. However, subsequent studies suggest that the 400 nm band may instead be due to ligand‐assisted metal halide molecular clusters (MHMCs), which lack the A component of perovskite. This raises the question whether the originally claimed Mn²⁺‐doped PMSCs are actually MHMCs. To unambiguously address this issue, Mn²⁺‐doped CH₃NH₃PbBr₃PMSCs were synthesized with PL at both 440 nm, attributed to the PMSC, and at 600 nm, attributed to Mn²⁺. Blueshifting of the host absorption and PL bands due to Cl⁻codoping is avoided by selecting MnBr₂as dopant precursor rather than MnCl₂. Dopant incorporation into PMSCs is further supported by PL excitation, time‐resolved PL, and electron paramagnetic resonance studies. This work provides direct and strong evidence of successful Mn²⁺doping in PMSCs. 

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4. A chemical dynamics study of the reaction of the methylidyne radical (CH, X ² Π) with dimethylacetylene (CH ₃ CCCH ₃ , X ¹ A _1g )

   https://doi.org/10.1039/D1CP04443E  

   He, Chao; Fujioka, Kazuumi; Nikolayev, Anatoliy A.; Zhao, Long; Doddipatla, Srinivas; Azyazov, Valeriy N.; Mebel, Alexander M.; Sun, Rui; Kaiser, Ralf I. (December 2021, Physical Chemistry Chemical Physics)

   The gas-phase reaction of the methylidyne (CH; X 2 Π) radical with dimethylacetylene (CH 3 CCCH 3 ; X 1 A 1g ) was studied at a collision energy of 20.6 kJ mol −1 under single collision conditions with experimental results merged with ab initio calculations of the potential energy surface (PES) and ab initio molecule dynamics (AIMD) simulations. The crossed molecular beam experiment reveals that the reaction proceeds barrierless via indirect scattering dynamics through long-lived C 5 H 7 reaction intermediate(s) ultimately dissociating to C 5 H 6 isomers along with atomic hydrogen with atomic hydrogen predominantly released from the methyl groups as verified by replacing the methylidyne with the D1-methylidyne reactant. AIMD simulations reveal that the reaction dynamics are statistical leading predominantly to p28 (1-methyl-3-methylenecyclopropene, 13%) and p8 (1-penten-3-yne, 81%) plus atomic hydrogen with a significant amount of available energy being channeled into the internal excitation of the polyatomic reaction products. The dynamics are controlled by addition to the carbon–carbon triple bond with the reaction intermediates eventually eliminating a hydrogen atom from the methyl groups of the dimethylacetylene reactant forming 1-methyl-3-methylenecyclopropene (p28). The dominating pathways reveal an unexpected insertion of methylidyne into one of the six carbon–hydrogen single bonds of the methyl groups of dimethylacetylene leading to the acyclic intermediate, which then decomposes to 1-penten-3-yne (p8). Therefore, the methyl groups of dimethylacetylene effectively ‘screen’ the carbon–carbon triple bond from being attacked by addition thus directing the dynamics to an insertion process as seen exclusively in the reaction of methylidyne with ethane (C 2 H 6 ) forming propylene (CH 3 C 2 H 3 ). Therefore, driven by the screening of the triple bond, one propynyl moiety (CH 3 CC) acts in four out of five trajectories as a spectator thus driving an unexpected, but dominating chemistry in analogy to the methylidyne – ethane system. 

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5. CH ₃ –X Reductive Elimination Reactivity of Pt ^IV Me Complexes Supported by a Sulfonated CNN Pincer Ligand (X = OH, CF ₃ CO ₂ , PhNMe ₂ ⁺ )

   https://doi.org/10.1021/acs.organomet.9b00702  

   Ruan, Jiaheng; Wang, Daoyong; Vedernikov, Andrei N. (December 2019, Organometallics)