Understanding the electronic structures of high‐valent metal complexes aids the advancement of metal‐catalyzed cross coupling methodologies. A prototypical complex with formally high valency is [Cu(CF3)4]−(
In this research article, we describe the synthesis and characterization of mononuclear and dinuclear Cu complexes bound by a family of tridentate redox‐active ligands with tunable H‐bonding donors. The mononuclear Cu‐anion complexes were oxidized to the corresponding “high‐valent” intermediates by oxidation of the redox‐active ligand. These species were capable of oxidizing phenols with weak O−H bonds via H‐atom abstraction. Thermodynamic analysis of the H‐atom abstractions, which included reduction potential measurements, p
- Award ID(s):
- 1941220
- PAR ID:
- 10227932
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Chemistry – An Asian Journal
- Volume:
- 16
- Issue:
- 12
- ISSN:
- 1861-4728
- Page Range / eLocation ID:
- p. 1608-1618
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract Understanding the electronic structures of high‐valent metal complexes aids the advancement of metal‐catalyzed cross coupling methodologies. A prototypical complex with formally high valency is [Cu(CF3)4]−(
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