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1. CAMELS-Chem: augmenting CAMELS (Catchment Attributes and Meteorology for Large-sample Studies) with atmospheric and stream water chemistry data

   https://doi.org/10.5194/hess-28-611-2024  

   Sterle, Gary; Perdrial, Julia; Kincaid, Dustin W; Underwood, Kristen L; Rizzo, Donna M; Haq, Ijaz Ul; Li, Li; Lee, Byung Suk; Adler, Thomas; Wen, Hang; et al (January 2024, Hydrology and Earth System Sciences)

   Abstract. Large sample datasets are transforming the catchment sciences, but there are few off-the-shelf stream water chemistry datasets with complementary atmospheric deposition, streamflow, meteorology, and catchment physiographic attributes. The existing CAMELS (Catchment Attributes and Meteorology for Large-sample Studies) dataset includes data on topography, climate, streamflow, land cover, soil, and geology across the continental US. With CAMELS-Chem, we pair these existing attribute data for 516 catchments with atmospheric deposition data from the National Atmospheric Deposition Program and water chemistry and instantaneous discharge data from the US Geological Survey over the period from 1980 through 2018 in a relational database and corresponding dataset. The data include 18 common stream water chemistry constituents: Al, Ca, Cl, dissolved organic carbon, total organic carbon, HCO3, K, Mg, Na, total dissolved N, total organic N, NO3, dissolved oxygen, pH (field and lab), Si, SO4, and water temperature. Annual deposition loads and concentrations include hydrogen, NH4, NO3, total inorganic N, Cl, SO4, Ca, K, Mg, and Na. We demonstrate that CAMELS-Chem water chemistry data are sampled effectively across climates, seasons, and discharges for trend analysis and highlight the coincident sampling of stream constituents for process-based understanding. To motivate their use by the larger scientific community across a variety of disciplines, we show examples of how these publicly available datasets can be applied to trend detection and attribution, biogeochemical process understanding, and new hypothesis generation via data-driven techniques. 

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2. Exploring the Complex Effects of Wildfire on Stream Water Chemistry: Insights From Concentration‐Discharge Relationships

   https://doi.org/10.1029/2023WR034940  

   Richardson, C; Montalvo, M; Wagner, S; Barton, R; Paytan, A; Redmond, M; Zimmer, M (February 2024, Water Resources Research)

   Wildfires are a worldwide disturbance with unclear implications for stream water quality. We examined stream water chemistry responses immediately (<1 month) following a wildfire by measuring over 40 constituents in four gauged coastal watersheds that burned at low to moderate severity. Three of the four watersheds also had pre‐fire concentration‐discharge data for 14 constituents: suspended sediment (SS_fine), dissolved organic and inorganic carbon (DOC, DIC), specific UV absorbance (SUVA), major ions (Ca²⁺, K⁺, Mg²⁺, Na⁺, Cl⁻, SO₄²⁻, NO₃⁻, F⁻), and select trace elements (total dissolved Mn, Fe). In all watersheds, post‐fire stream water concentrations of SS_fine, DOC, Ca²⁺, Cl⁻, and changed when compared to pre‐fire data. Post‐fire changes in , K⁺, Na⁺, Mg²⁺, DIC, SUVA, and total dissolved Fe were also found for at least two of the three streams. For constituents with detectable responses to wildfire, post‐fire changes in the slopes of concentration‐discharge relationships commonly resulted in stronger enrichment trends or weaker dilution trends, suggesting that new contributing sources were surficial or near the surface. However, a few geogenic solutes, Ca²⁺, Mg²⁺, and DIC, displayed stronger dilution trends at nearly all sites post‐fire. Moreover, fire‐induced constituent concentration changes were highly discharge and site‐dependent. These similarities and differences in across‐site stream water chemistry responses to wildfire emphasize the need for a deeper understanding of landscape‐scale changes to solute sources and pathways. Our findings also highlight the importance of being explicit about reference points for both stream discharge and pre‐fire stream water chemistry in post‐fire assessment of concentration changes. 

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3. A salinity module for SWAT to simulate salt ion fate and transport at the watershed scale

   https://doi.org/10.5194/hess-23-3155-2019  

   Bailey, Ryan T.; Tavakoli-Kivi, Saman; Wei, Xiaolu (January 2019, Hydrology and Earth System Sciences)

   Abstract. Salinity is one of the most common water quality threats in riverbasins and irrigated regions worldwide. However, no available numericalmodels simulate all major processes affecting salt ion fate and transport at the watershed scale. This study presents a new salinity module for the SWAT model that simulates the fate and transport of eight major salt ions(SO42-, Ca2+, Mg2+, Na+, K+, Cl−,CO32-, HCO3-) in a watershed system. The module accountsfor salt transport in surface runoff, soil percolation, lateral flow,groundwater, and streams, and equilibrium chemistry reactions in soil layersand the aquifer. The module consists of several new subroutines that areimbedded within the SWAT modelling code and one input file containing soilsalinity and aquifer salinity data for the watershed. The model is appliedto a 732 km2 salinity-impaired irrigated region within the ArkansasRiver Valley in southeastern Colorado and tested against root zone soilsalinity, groundwater salt ion concentration, groundwater salt loadings tothe river network, and in-stream salt ion concentration. The model can be auseful tool in simulating baseline salinity transport and investigatingsalinity best management practices in watersheds of varying spatial scales. 

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4. Physical and biogeochemical drivers of solute mobilization and flux through the critical zone after wildfire

   https://doi.org/10.3389/frwa.2023.1148298  

   Sánchez, Rodrigo Andrés; Meixner, Thomas; Roy, Tirthankar; Ferré, Paul Ty; Whitaker, Martha; Chorover, Jon (May 2023, Frontiers in Water)

   A nine-year time series of nutrient cation and anion concentration and efflux from three forested catchments in the Jemez River Basin Critical Zone Observatory (JRB-CZO) in northern New Mexico was used to quantify the pulse of chemical denudation resulting from varying levels stand-replacing wildfire intensity in May-June of 2013. The 3 years of pre-fire and 6 years of postfire data were also probed to shed light on the mechanisms underlying the pulsed release and the subsequent recovery. The initial large solute pulse released to the streams—K⁺, Ca²⁺, Mg²⁺, SO ${}_4^{2-}$, Cl⁻, dissolved inorganic carbon (DIC), dissolved organic carbon (DOC), and total dissolved nitrogen (TDN)—was caused by leaching of hillslope ash deposits during the first monsoon storms post-fire. Debris flow following the wildfire likely redistributed much of the ash-containing sediments along streams and valley bottoms. Sustained elevated solute concentrations observed in the surface waters throughout the post-fire period relative to pre-fire baselines is consistent with these soluble materials being periodically flushed from the soils during wet seasons, i.e., snowmelt and summer monsoons. As microbial mediated reactions and biotic uptake—due to plant regrowth—recover after fire, nutrient ion export (e.g., NO ${}_3^{-}$, Cl⁻and SO ${}_4^{2-}$) steadily decreased toward the end of the post fire period, but remained above pre-fire levels, particularly for NO ${}_3^{-}$and SO ${}_4^{2-}$. Surface water concentrations of polyvalent cations (e.g., Al and Fe) decreased significantly after the fire. Our observations suggest that changes in organic matter composition after fire (e.g., increased humification index—HIX) and the presence of pyrogenic carbon may not favor organo-metal complexation and transport. Finally, differences in burn severity among the three watersheds presented in this study, provide insights of the relative impact of solute exports and resilience. The catchments that experienced high burn severity exhibited greater solute fluxes than the less severely burn. Moreover, despite these differences, toward the end of the post-fire period these surface waters presented low and similar solute effluxes, indicating system recovery. Nonetheless, magnitudes and rebounds were solute and process specific. The results of this study highlight the importance of surface and near surface physical and biogeochemical processes on the long-lasting geochemical denudation of forested catchments following wildfires of varying intensities. 

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5. Examining spatial variation in soil solutes and flowpaths in a semi-arid, montane catchment

   https://doi.org/10.3389/frwa.2022.1003968  

   Gregory, Reece B.; Bush, Sidney A.; Sullivan, Pamela L.; Barnard, Holly R. (November 2022, Frontiers in Water)

   Biogeochemical properties of soils play a crucial role in soil and stream chemistry throughout a watershed. How water interacts with soils during subsurface flow can have impacts on water quality, thus, it is fundamental to understand where and how certain soil water chemical processes occur within a catchment. In this study, ~200 soil samples were evaluated throughout a small catchment in the Front Range of Colorado, USA to examine spatial and vertical patterns in major soil solutes among different landscape units: riparian areas, alluvial/colluvial fans, and steep hillslopes. Solutes were extracted from the soil samples in the laboratory and analyzed for major cation (Li, K, Mg, Br, and Ca) and anion (F, Cl, NO 2 , NO 3 , PO 4 , and SO 4 ) concentrations using ion chromatography. Concentrations of most solutes were greater in near surface soils (10 cm) than in deeper soils (100 cm) across all landscape units, except for F which increased with depth, suggestive of surface accumulation processes such as dust deposition or enrichment due to biotic cycling. Potassium had the highest variation between depths, ranging from 1.04 mg/l (100 cm) to 3.13 mg/l (10 cm) sampled from riparian landscape units. Nearly every solute was found to be enriched in riparian areas where vegetation was visibly denser, with higher mean concentrations than the hillslopes and fans, except for NO 3 which had higher concentrations in the fans. Br, NO 2 , and PO 4 concentrations were often below the detectable limit, and Li and Na were not variable between depths or landscape units. Ratioed stream water concentrations (K:Na, Ca:Mg, and NO 3 :Cl) vs. discharge relationships compared to the soil solute ratios indicated a hydraulic disconnection between the shallow soils (<100 cm) and the stream. Based on the comparisons among depths and landscape units, our findings suggest that K, Ca, F, and NO 3 solutes may serve as valuable tracers to identify subsurface flowpaths as they are distinct among landscape units and depth within this catchment. However, interflow and/or shallow groundwater flow likely have little direct connection to streamflow generation. 

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