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Abstract Using the popular metal‐ligand axial coordination self‐assembly approach, donor‐acceptor conjugates have been constructed using zinc tetrapyrroles (porphyrin (ZnP), phthalocyanine (ZnPc), and naphthalocyanine (ZnNc)) as electron donors and imidazole functionalized tetracyanobutadiene (Im‐TCBD) and cyclohexa‐2,5‐diene‐1,4‐diylidene‐expanded‐tetracyanobutadiene (Im‐DCNQ) as electron acceptors. The newly formed donor‐acceptor conjugates were fully characterized by a suite of physicochemical methods, including absorption and emission, electrochemistry, and computational methods. The measured binding constants for the 1 : 1 complexes were in the order of 104–105 M−1in o‐dichlorobenzene. Free‐energy calculations and the energy level diagrams revealed the high exergonicity for the excited state electron transfer reactions. However, in the case of the ZnNc:Im‐DCNQ complex, owing to the facile oxidation of ZnNc and facile reduction of Im‐DCNQ, slow electron transfer was witnessed in the dark without the aid of light. Systematic transient pump‐probe studies were performed to secure evidence of excited state charge separation and gather their kinetic parameters. The rate of charge separation was as high as 1011 s−1suggesting efficient processes. These findings show that the present self‐assembly approach could be utilized to build donor‐acceptor constructs with powerful electron acceptors, TCBD and DCNQ, to witness ground and excited state charge transfer, fundamental events required in energy harvesting, and building optoelectronic devices.
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Photoinduced Electron Transfer in Axially Coordinated Supramolecular Zinc Tetrapyrrole Bis(styryl)BODIPY Donor‐Acceptor Conjugates
Abstract Photoinduced electron transfer (PET) in newly assembled dyads formedviametal‐ligand axial coordination of phenylimidazole‐functionalized bis(styryl)BODIPY (BODIPY(Im)2) and zinc tetrapyrroles, that is, zinc tetratolylporphyrin (ZnP), zinc tetra‐t‐butyl phthalocyanine (ZnPc) and zinc tetra‐t‐butyl naphthalocyanine (ZnNc), in non‐coordinatingo‐dichlorobenzene (DCB) is investigated using both steady‐state and time‐resolved transient absorption techniques. The structure of the BODIPY(Im)2was identified by using single crystal X‐ray structural analysis. The newly formed supramolecular dyads were fully characterized by spectroscopic, computational and electrochemical methods. The binding constants measured from optical absorption spectral studies were in the range of ∼104 M−1for the first zinc tetrapyrrole binding and suggested that the two imidazole entities of bis(styryl)BODIPY behave independently in the binding process. The energy level diagram established using spectral and electrochemical studies suggested PET to be thermodynamically unfavorable in the ZnP‐bearing complex while for ZnPc‐ and ZnNc‐bearing complexes such a process is possible when zinc tetrapyrrole is selectively excited. Consequently, occurrence of efficient PET in the latter two dyads was possible to establish from femtosecond transient absorption studies wherein the electron transfer products, that is, the radical cation of zinc tetrapyrrole and the radical anion of BODIPY(Im)2, was possible to spectrally identify. From target analysis of the transient data, time constants of circa 3 ns for ZnPc⋅+:BODIPY⋅−and circa 0.5 ns for ZnNc⋅+:BODIPY⋅−were obtained indicating persistence of the radical ion‐pair to some extent. The electron acceptor property of bis(styryl)BODIPY in donor‐acceptor conjugates is borne out from the present study.
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- Award ID(s):
- 1726652
- PAR ID:
- 10258369
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- ChemPhotoChem
- Volume:
- 5
- Issue:
- 3
- ISSN:
- 2367-0932
- Format(s):
- Medium: X Size: p. 260-269
- Size(s):
- p. 260-269
- Sponsoring Org:
- National Science Foundation
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