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1. Implications of Multiple Disequilibrium Textures in Quartz-Hosted Embayments

   https://doi.org/10.3389/feart.2021.742895  

   Ruefer, Anna C.; Befus, Kenneth S.; Thompson, James O.; Andrews, Benjamin J. (December 2021, Frontiers in Earth Science)

   The faces of volcanic phenocrysts may be marked by imperfections occurring as holes that penetrate the crystal interior. When filled with glass these features, called embayments or reentrants, have been used to petrologically constrain magmatic ascent rate. Embayment ascent speedometry relies on the record of disequilibrium preserved as diffusion-limited volatile concentration gradients in the embayment glass. Clear, glassy embayments are carefully selected for speedometry studies. The use and subsequent descriptions of pristine embayments overrepresent their actual abundance. Here, we provide a textural analysis of the number, morphology, and filling characteristics of quartz-hosted embayments. We target a collection of large (i.e., >20 km³erupted volume) silicic eruptions, including the Bishop Tuff, Tuff of Bluff Point, Bandelier Tuff, Mesa Falls Tuff, and Huckleberry Ridge Tuff in the United States, Oruanui Tuff in New Zealand, Younger Toba Tuff in Indonesia, the Kos Plateau Tuff in Greece, and the Giant Pumice from La Primavera caldera in Mexico. For each unit, hundreds of quartz crystals were picked and the total number of embayment-hosting crystals were counted and categorized into classifications based on the vesicularity and morphology. We observed significant variability in embayment abundance, form, and vesicularity across different eruptions. Simple, cylindrical forms are the most common, as are dense glassy embayments. Increasingly complex shapes and a range of bubble textures are also common. Embayments may crosscut or deflect prominent internal cathodoluminescence banding in the host quartz, indicating that embayments form by both dissolution and growth. We propose potential additional timescales recorded by embayment disequilibrium textures, namely, faceting, bubbles, and the lack thereof. Embayment formation likely occurs tens to hundreds of years before eruption because embayment surfaces are rounded instead of faceted. Bubble textures in embayments are far from those predicted by equilibrium solubility. Homogenous nucleation conditions likely allow preservation of pressures much greater than magmastatic inside embayments. Our textural observations lend insight into embayment occurrence and formation and guide further embayment studies. 

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2. Rehydrated glass embayments record the cooling of a Yellowstone ignimbrite

   https://doi.org/10.1130/G51905.1  

   Befus, Kenneth S; Thompson, James O; Allison, Chelsea M; Ruefer, Anna C; Manga, Michael (March 2024, Geology)

   Abstract Hydration fronts penetrate 50–135 μm into glassy rhyolite embayments hosted in quartz crystals from the Mesa Falls Tuff in the Yellowstone Plateau volcanic field. The hydration fronts occur as steep enrichments that reach 2.4 ± 0.6 wt% H2O at the embayment opening, representing much higher values than interior concentrations of 0.9 ± 0.2 wt% H2O. Molecular water accounts for most of the water enrichment. Water speciation indicates the hydration fronts comprise absorbed meteoric water that modified the original magmatic composition of the rhyolitic glass. We used finite difference diffusion models to demonstrate that glass rehydration was likely produced over a few decades as the ignimbrite cooled. Such temperatures and time scales are consistent with rare firsthand observations of decadal hydrothermal systems associated with cooling ignimbrites at Mount Pinatubo (Philippines) and the Valley of Ten Thousand Smokes (Alaska). 

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3. Ignimbrites of the Sour Creek dome, Yellowstone volcano, USA: Implications for the Lava Creek Tuff eruption and Yellowstone Caldera

   https://doi.org/10.1130/GES02939.1  

   Myers, Madison L; Salazar, Raymond D; Wilson, Colin JN; Finch, Hailey; Henderson, Stacy L; Stelten, Mark E; Ketel, Jessica; Brown, Thomas; Ruth, Dawn (June 2026, Geosphere)

   Field observations plus sanidine compositional and 40Ar/39Ar age data collected on rocks from the Sour Creek dome (SCD) area of Yellowstone volcano (United States) serve to identify five new ignimbrite packages with ages (average 631.5 ± 0.9 ka) that are analytically indistinguishable from those of the Lava Creek Tuff (LCT), challenging the current framework of two LCT eruptive members. Newly recognized package 1 occurs as LCT-aged recycled clasts within a proximal lag breccia, reflecting a major time break in the LCT eruption sequence. Conformably above, the scoria-bearing ignimbrite of package 2 is extensively found in the dome, having been previously mis-mapped as Huckleberry Ridge Tuff and LCT member A. To the south, package 3 is a crystal-rich, densely welded ignimbrite (inferred to be younger than package 2) that is conformably overlain by package 4, a fine-grained ignimbrite that contains abundant clasts of recycled tuff. Lastly, the topographically highest parts of the dome are made up of package 5, a multicomponent ignimbrite containing scoria, recycled clasts, and pumices, potentially correlative with package 2 and/or package 4. Cathodoluminescence imaging and zoning assessment was integrated with sanidine geochemistry from all five packages, including their recycled clasts. Four of the five packages were sourced from separate magmatic bodies within a larger plumbing system, each defined by their sanidine Ba distributions and componentry. Although the SCD was originally mapped as a resurgent dome and is actively deforming today, faults cutting the region show comparable offsets for NW-SE “resurgent faulting” as for orthogonal NE-SW faulting, the latter of which also cuts the 162 ka Elephant Back lava flow. We infer that faulting in the SCD well postdates eruption and that the SCD instead represents a domical accumulation of ignimbrite, not a resurgent structure. The abundance of recycled materials (and absence of Absaroka country rocks) in the SCD ignimbrites implies that vent locations were well inboard of the mapped caldera boundary, with some potentially along the line of the Yellowstone River, requiring a revision of the currently accepted LCT caldera outline. The LCT eruptive events were thus far more complex than currently recognized, with multiple deposits fed from multiple magma bodies over a time scale that cannot be resolved by radiometric dating. 

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4. Evaluating the Potential of Rhyolitic Glass as a Lithium Source for Brine Deposits

   https://doi.org/10.5382/econgeo.4866  

   Ellis, B. S.; Szymanowski, D.; Harris, C.; Tollan, P.M.E.; Neukampf, J.; Guillong, M.; Cortes-Calderon, E. A.; Bachmann, O. (January 2022, Economic Geology)

   Abstract Lithium is an economically important element that is increasingly extracted from brines accumulated in continental basins. While a number of studies have identified silicic magmatic rocks as the ultimate source of dissolved brine lithium, the processes by which Li is mobilized remain poorly constrained. Here we focus on the potential of low-temperature, post-eruptive processes to remove Li from volcanic glass and generate Li-rich fluids. The rhyolitic glasses in this study (from the Yellowstone-Snake River Plain volcanic province in western North America) have interacted with meteoric water emplacement as revealed by textures and a variety of geochemical and isotopic signatures. Indices of glass hydration correlate with Li concentrations, suggesting Li is lost to the water during the water-rock interaction. We estimate the original Li content upon deposition and the magnitude of Li depletion both by direct in situ glass measurements and by applying a partition-coefficient approach to plagioclase Li contents. Across our whole sample set (19 eruptive units spanning ca. 10 m.y.), Li losses average 8.9 ppm, with a maximum loss of 37.5 ppm. This allows estimation of the dense rock equivalent of silicic volcanic lithologies required to potentially source a brine deposit. Our data indicate that surficial processes occurring post-eruption may provide sufficient Li to form economic deposits. We found no relationship between deposit age and Li loss, i.e., hydration does not appear to be an ongoing process. Rather, it occurs primarily while the deposit is cooling shortly after eruption, with δ18O and δD in our case study suggesting a temperature window of 40° to 70°C. 

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5. Evaluating the Role of Titanomagnetite in Bubble Nucleation: Rock Magnetic Detection and Characterization of Nanolites and Ultra‐Nanolites in Rhyolite Pumice and Obsidian From Glass Mountain, California

   https://doi.org/10.1029/2023GC011336  

   Brachfeld, Stefanie; McCartney, Kelly N.; Hammer, Julia E.; Shea, Thomas; Giachetti, Thomas (April 2024, Geochemistry, Geophysics, Geosystems)

   We document the presence, composition, and number density (TND) of titanomagnetite nanolites and ultra‐nanolites in aphyric rhyolitic pumice, obsidian, and vesicular obsidian from the 1060 CE Glass Mountain volcanic eruption of Medicine Lake Volcano, California, using magnetic methods. Curie temperatures indicate compositions of Fe2.40Ti0.60O4 to Fe3O4. Rock‐magnetic parameters sensitive to domain state, which is dependent on grain volume, indicate a range of particle sizes spanning superparamagnetic (<50–80 nm) to multidomain (>10 μm) particles. Cylindrical cores drilled from the centers of individual pumice clasts display anisotropy of magnetic susceptibility with prolate fabrics, with the highest degree of anisotropy coinciding with the highest vesicularity. Fabrics within a pumice clast require particle alignment within a fluid, and are interpreted to result from the upward transport of magma driven by vesiculation, ensuing bubble growth, and shearing in the conduit. Titanomagnetite number density (TND) is calculated from titanomagnetite volume fraction, which is determined from ferromagnetic susceptibility. TND estimates for monospecific assemblages of 1,000 nm–10 nm cubes predict 10^12 to 10^20 m^−3 of solid material, respectively. TND estimates derived using a power law distribution of grain sizes predict 10^18 to 10^19  m^−3. These ranges agree well with TND determinations of 10^18 to 10^20  m^−3 made by McCartney et al. (2024), and are several orders of magnitude larger than the number density of bubbles in these materials. These observations are consistent with the hypothesis that titanomagnetite crystals already existed in extremely high number‐abundance at the time of magma ascent and bubble nucleation. 

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