An official website of the United States government
Lacustrine evaporites have potential to document ancient terrestrial climates, including temperatures and their seasonal variations, and atmospheric pCO2. The sodium carbonate mineral nahcolite (NaHCO3) in the early Eocene Parachute Creek Member, Green River Formation, Piceance subbasin, indicates elevated pCO2 concentrations (> 680 ppm) in the water column and in the atmosphere if in contact with brine. These data support a causal connection between elevated atmospheric pCO2 and global warmth during the early Eocene Climatic Optimum. Trona (Na2CO3⋅NaHCO3⋅2H2O), not nahcolite, is the dominant sodium carbonate mineral in the coeval Wilkins Peak Member in the Bridger subbasin, which may be explained by interbasin variations in (1) brine chemistry, (2) temperature, and (3) pCO2. These interpretations are based on equilibrium thermodynamics and simulations that evaporate lake water, but they ignore seasonal changes in water column temperature and pCO2. Winter cooling, rather than evaporative concentration, best explains the fine-scale alternations of nahcolite, halite (NaCl), and nahcolite + halite in the Parachute Creek Member. Simulated evaporation of alkaline source waters from the paleo Aspen River at temperatures between 15⁰ and 27⁰ C and pCO2 at or below 1200 ppm produces the observed mineral sequence in the Wilkins Peak Member: gaylussite (Na2CO3⋅CaCO3⋅5H2O) at temperatures < 27⁰ C and pirssonite (Na2CO3⋅CaCO3⋅2H2O) > 27⁰ C (both now replaced by shortite Na2CO3·2CaCO3), then northupite (Na3Mg(CO3)2Cl), trona, and halite. The challenge of determining paleo-lake temperatures in the Bridger and Piceance subbasins using microthermometry has now been solved using femtosecond lasers that promote nucleation of vapor bubbles in brine inclusions without deforming the halite host crystal. This method shows general agreement with thermodynamic-based calculations and will be used to document mean annual temperatures in the Greater Green River Basin.
more »
« less
When “evaporites” are not formed by evaporation: The role of temperature and pCO2 on saline deposits of the Eocene Green River Formation, Colorado, USA
Abstract Halite precipitates in the Dead Sea during winter but re-dissolves above the thermocline upon summer warming, “focusing” halite deposition below the thermocline (Sirota et al., 2016, 2017, 2018). Here we develop an “evaporite focusing” model for evaporites (nahcolite + halite) preserved in a restricted area of the Eocene Green River Formation in the Piceance Creek Basin of Colorado, USA. Nahcolite solubility is dependent on partial pressure of carbon dioxide (pCO2) as well as temperature (T), so these models covary with both T and pCO2. In the lake that filled the Piceance Creek Basin, halite, nahcolite or mixtures of both could have precipitated during winter cooling, depending on the CO2 content in different parts of the lake. Preservation of these minerals occurs below the thermocline (>∼25 m) in deeper portions of the basin. Our modeling addresses both: (1) the restriction of evaporites in the Piceance Creek Basin to the center of the basin without recourse to later dissolution and (2) the variable mineralogy of the evaporites without recourse to changes in lake water chemistry. T from 20 to 30 °C and pCO2 between 1800 and 2800 ppm are reasonable estimates for the conditions in the Piceance Creek Basin paleolake. Other evaporites occur in the center of basins but do not extend out to the edges of the basin. Evaporite focusing caused by summer-winter T changes in the solubility of the minerals should be considered for such deposits and variable pCO2 within the evaporating brines also needs to be considered if pCO2 sensitive minerals are found.
more »
« less
- Award ID(s):
- 1812741
- PAR ID:
- 10281320
- Date Published:
- Journal Name:
- GSA Bulletin
- Volume:
- 132
- Issue:
- 7-8
- ISSN:
- 0016-7606
- Page Range / eLocation ID:
- 1365 to 1380
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
Lacustrine chemical sediments of the Wilkins Peak Member, Eocene Green River Formation potentially preserve paleoclimate information relating to the conditions of their formation and preservation within the lake basin during the Early Eocene Climatic Optimum. The Green River Formation comprises the world’s largest sodium-carbonate evaporite deposit in the form of trona (Na2CO3⋅NaHCO3⋅2H2O) in the Bridger sub-basin and nahcolite (NaHCO3) in the neighboring Piceance Creek basin. Modern analogues suggest that these minerals necessitate the existence of an alkaline source water. Detrital provenance geochronometers suggest that the most likely source for volcanic waters to the Greater Green River Basin is the Colorado Mineral Belt, connected to the basin via the Aspen paleo-river. We tested the hypothesis that magmatic waters from the Colorado Mineral Belt could have supplied the Greater Green River Basin with the alkalinity needed to precipitate sodium-carbonate evaporites that are preserved in the Wilkins Peak Member by numerically simulating the evaporation of modern soda spring waters from northwestern Colorado at various temperature and atmospheric pCO2 conditions. We compare the resulting simulated evaporite sequences of the modern soda spring waters to the mineralogy preserved within the Wilkins Peak Member. Simulated evaporation of Steamboat Springs water produces the closest match to core observations and mineralogy. These simulations provide constraints on the salinities at which various minerals precipitated in the Wilkins Peak Member as well as insights into the regional temperature (>15ºC for gaylussite and trona; >27º for pirssonite and trona) and pCO2 conditions (<1200ppm for gaylussite and trona) during the EECO.more » « less
-
null (Ed.)Searles Lake, California, was a saline-alkaline lake that deposited >25 non-clastic minerals that record the history of lake chemistry and regional climate. Here, the mineralogy and petrography from the late Pleistocene/Holocene (32−6 ka) portion of a new Searles Lake sediment core, SLAPP-SRLS17, is combined with thermodynamic models to determine the geochemical and paleoclimate conditions required to produce the observed mineral phases, sequences, and abundances. The models reveal that the primary precipitates formed by open system (i.e., fractional crystallization), whereas the early diagenetic salts formed by salinity-driven closed system back-reactions (i.e., equilibrium crystallization). For core SLAPP-SRLS17, the defining evaporite sequence trona → burkeite → halite indicates brine temperatures within a 20−29 °C range, implying thermally insulating lake depths >10 m during salt deposition. Evaporite phases reflect lake water pCO2 consistent with contemporaneous atmospheric values of ∼190−270 ppmv. However, anomalous layers of nahcolite and thenardite indicate pulses of pCO2 > 700−800 ppm, likely due to variable CO2 injection along faults. Core sedimentology indicates that Searles Lake was continuously perennial between 32 ka and 6 ka such that evaporite units reflect periods of net evaporation but never complete desiccation. Model simulations indicate that cycles of partial evaporation and dilution strongly influence long-term brine evolution by amassing certain species, particularly Cl−, that only occur in late-stage soluble salts. A model incorporating long-term brine dynamics corrects previous mass-balance anomalies and shows that the late Pleistocene/Holocene (32−6 ka) salts are partially inherited from the solutes introduced into earlier lakes going back at least 150 ka.more » « less
-
Chemical sediments from the Early Eocene Green River Formation can be used for assessing hydroclimate and basin evolution during their deposition. The Wilkins Peak Member (WPM) of the Green River Formation contains a relatively continuous record of perennial closed-basin saline lake deposition in the Bridger Basin, southwest Wyoming, from approximately 51.6 to 49.8 Ma. The volumes and paragenesis of authigenic chemical sediments in the WPM are intrinsically related to the chemical evolution of basin brines. The geographic distribution of those chemical sediments across the Bridger Basin relates to the syn- and post-depositional tectonic history of the basin. In this study, we integrated thermodynamic modeling of chemical evolution of lake brines with chemostratigraphic and lithostratigraphic interpretations of the basin-center Solvay S-34-1 core to evaluate physical and chemical changes to and within ancient Lake Gosiute during the Early Eocene. Fine-scale X-ray fluorescence (XRF) scanning along the length of the core provides a high-resolution chemical stratigraphy of the WPM. Thermodynamic modeling of the evaporation of hypothetical inflow waters and lake brines yield predicted sequences of evaporite minerals, allowing estimation of the salinities and evaporated volumes of water required to reach saturation with respect to observed mineral deposits from the basin. The spatial distributions of bedded evaporites allow us to investigate tectonic changes to the basin during and after the deposition of the WPM. Here, we integrate these data to interpret changes in lake-level, salinity, and hydroclimate of ancient Lake Gosiute during the Early Eocene.more » « less
-
Femtosecond lasers, fired in short pulses, can induce bubble cavitation in single-phase liquid fluid inclusions at temperatures near the inclusion homogenization temperature. By coupling femtosecond laser-induced cavitation with microthermometry, paleotemperatures can be extracted from fluid inclusions in primary halite crystals. This technique minimizes plastic deformation of halite by not subjecting samples to extreme temperatures during vapor bubble nucleation. The resultant homogenization temperatures are precise and reproducible. We applied this technique to Eocene Green River Formation primary bottom-growth halites from the Piceance Creek Basin in Colorado. Samples from the basin-center Savage 24-1 core yield average bottom water temperatures of 27.0 ± 1.3 ºC and 20.1 ± 1.2 ºC for the Upper and Lower Salt intervals, respectively. Average bottom water temperatures from modern perennial hypersaline lakes have been shown to reflect the local mean annual air temperature. Therefore, homogenization temperatures from primary bottom-growth halite fluid inclusions are a proxy for mean annual air temperature. These results agree with regional Early Eocene mean annual air temperature estimate ranges from other mineralogical and biochemical proxies, bolstering the reliability of temperature estimates obtained using this technique. Additionally, the highly selective nature of laser induced cavitation microthermometry allows for a higher degree of quality control compared to standard microthermometry, yielding more reproducible and precise results.more » « less
- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1130/B35303.1
