An official website of the United States government
Abstract New‐particle formation is important to aerosol–cloud interactions and thus climate, but for newly formed particles to become cloud condensation nuclei, they must grow and avoid scavenging by larger background particles. Whereas ion‐induced new‐particle formation and growth have received attention recently, here we study an opposing effect, blunting the enhancement due to ions, that has received less attention: Small charged particles are scavenged more efficiently due to their charge, and thus their survival probability is lower than that of their neutral counterparts. Through simulations, we show that particle survival is reduced, in some cases dramatically, matching updated theoretical predictions. We also show that the survival of charged particles is enhanced if particles lose their charge via neutralization; therefore, for ion‐induced nucleation to be important, the resulting charged particles must become neutral as soon as possible. Overall, the coagulation scavenging enhancement due to charge ought to lessen the influence of ions in new‐particle formation and growth.
more »
« less
Technical note: The enhancement limit of coagulation scavenging of small charged particles
Abstract. We show that the limit of the enhancement of coagulation scavenging of charged particles is 2, that is, doubled compared to the neutral case.Because the particle survival probability decreases exponentially as the coagulation sink increases, everything else being equal, the doubling of the coagulation sink can amount to a dramatic drop in survival probability – squaring the survival probability, p2, where p≤1 is the survival probability in the neutral case.Thus, it is imperative to consider this counterbalancing effect when studying ion-induced new-particle formation and ion-enhanced new-particle growth in the atmosphere.
more »
« less
- PAR ID:
- 10282696
- Date Published:
- Journal Name:
- Atmospheric Chemistry and Physics
- Volume:
- 21
- Issue:
- 5
- ISSN:
- 1680-7324
- Page Range / eLocation ID:
- 3827 to 3832
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
Intense new particle formation events are regularly observed under highly polluted conditions, despite the high loss rates of nucleated clusters. Higher than expected cluster survival probability implies either ineffective scavenging by pre-existing particles or missing growth mechanisms. Here we present experiments performed in the CLOUD chamber at CERN showing particle formation from a mixture of anthropogenic vapours, under condensation sinks typical of haze conditions, up to 0.1 s −1 . We find that new particle formation rates substantially decrease at higher concentrations of pre-existing particles, demonstrating experimentally for the first time that molecular clusters are efficiently scavenged by larger sized particles. Additionally, we demonstrate that in the presence of supersaturated gas-phase nitric acid (HNO 3 ) and ammonia (NH 3 ), freshly nucleated particles can grow extremely rapidly, maintaining a high particle number concentration, even in the presence of a high condensation sink. Such high growth rates may explain the high survival probability of freshly formed particles under haze conditions. We identify under what typical urban conditions HNO 3 and NH 3 can be expected to contribute to particle survival during haze.more » « less
-
Abstract Joule heating is a major energy sink in the solar wind‐magnetosphere‐ionosphere system and modeling it is key to understanding the impact of space weather on the neutral atmosphere. Ion drifts and neutral wind velocities are key parameters when modeling Joule heating, however there is limited validation of the modeled ion and neutral velocities at mid‐latitudes. We use the Blackstone Super Dual Auroral Radar Network radar and the Michigan North American Thermosphere Ionosphere Observing Network Fabry‐Perot interferometer to obtain the local nightside ion and neutral velocities at ∼40° geographic latitude during the nighttime of 16 July 2014. Despite being a geomagnetically quiet period, we observe significant sub‐auroral ion flows in excess of 200 ms−1. We calculate an enhancement to the local Joule heating rate due to these ion flows and find that the neutrals impart a significant increase or decrease to the total Joule heating rate of >75% depending on their direction. We compare our observations to outputs from the Thermosphere Ionosphere Electrodynamic General Circulation Model (TIEGCM). At such a low geomagnetic activity however, TIEGCM was not able to model significant sub‐auroral ion flows and any resulting Joule heating enhancements equivalent to our observations. We found that the neutral winds were the primary contributor to the Joule heating rates modeled by TIEGCM rather than the ions as suggested by our observations.more » « less
-
Three-velocity ballistic annihilation is an interacting system in which stationary, left-, and right-moving particles are placed at random throughout the real line and mutually annihilate upon colliding. We introduce a coalescing variant in which collisions may generate new particles. For a symmetric three-parameter family of such systems, we compute the survival probability of stationary particles at a given initial density. This allows us to describe a phase-transition for stationary particle survival.more » « less
-
null (Ed.)Particle charging in the afterglows of non-thermal plasmas typically take place in a non-neutral space charge environment. We model the same by incorporating particle-ion collision rate constant models, developed in prior work by analyzing particle-ion trajectories calculated using Langevin Dynamics simulations, into species transport equations for ions, electrons and charged particles in the afterglow. A scaling analysis of particle charging and additional Langevin Dynamics calculations of the particle-ion collision rate constant are presented to extend the range of applicability to ion electrostatic to thermal energy ratios of 300 and diffusive Knudsen number (that scales inversely with gas pressure) up to 2000. The developed collision rate constant models are first validated by comparing predictions of particle charge against measured values in a stationary, non-thermal DC plasma from past PK-4 campaigns published in Phys. Rev. Lett. 93(8): 085001 and Phys. Rev. E 72(1): 016406). The comparisons reveal excellent agreement within ±35% for particles of radius 0.6,1.0,1.3 μm in the gas pressure range of ~20-150 Pa. The experiments to probe particle charge distributions by Sharma et al. (J. Physics D: Appl. Phys. 53(24): 245204) are modeled using the validated particle-ion collision rate constant models and the calculated charge fractions are compared with measurements. The comparisons reveal that the ion/electron concentration and gas temperature in the afterglow critically influence the particle charge and the predictions are generally in qualitative agreement with the measurements. Along with critical assessment of the modeling assumptions, several recommendations are presented for future experimental design to probe charging in afterglows.more » « less
- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.5194/acp-21-3827-2021
