Abstract Liquid crystal elastomers (LCEs) undergo a large uniaxial contraction upon thermal or optical stimulation. LCE sheets are often fabricated with a spatially patterned direction of contraction, which can sculpt the sheet into a Gauss-curved surface. Here, we instead consider LCE sheets subject to patterned stimulation intensity, leading to a control of contraction strength. We show such patterns may also sculpt a complex surface, but with the advantage that arbitrarily many surfaces may be achieved sequentially in the same sample, thus breaking the link between microstructure and shape. We first consider a monodomain LCE in which some regions are actuated and others are not. We discuss how to join actuated and unactuated regions compatibly, and use this design rule to generate patterns for cones, anti-cones, arrays of cones and a rolling bi-strip. We validate the patterns numerically via elastic shell simulations and demonstrate them experimentally via patterned photo-chemical actuation. Secondly, we consider an LCE disk with an azimuthal director profile actuated by a radially varying stimulus. We show, theoretically and numerically, how to design a stimulation profile to sculpt any surface of revolution. Such re-configurable actuation offers enticing possibilities for haptics, robotics and locomotion.
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Azimuthal Anchoring Strength in Photopatterned Alignment of a Nematic
Spatially-varying director fields have become an important part of research and development in liquid crystals. Characterization of the anchoring strength associated with a spatially-varying director is difficult, since the methods developed for a uniform alignment are seldom applicable. Here we characterize the strength of azimuthal surface anchoring produced by the photoalignment technique based on plasmonic metamsaks. The measurements used photopatterned arrays of topological point defects of strength +1 and −1 in thin layers of a nematic liquid crystal. The integer-strength defects split into pairs of half-integer defects with lower elastic energy. The separation distance between the split pair is limited by the azimuthal surface anchoring, which allows one to determine the strength of the latter. The strength of the azimuthal anchoring is proportional to the UV exposure time during the photoalignment of the azobenzene layer.
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- Award ID(s):
- 1663394
- NSF-PAR ID:
- 10285071
- Date Published:
- Journal Name:
- Crystals
- Volume:
- 11
- Issue:
- 6
- ISSN:
- 2073-4352
- Page Range / eLocation ID:
- 675
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.3390/cryst11060675
