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1. Hydrogen isotopes in high 3He/4He submarine basalts: Primordial vs. recycled water and the veil of mantle enrichment

   Loewen, Matthew W. (January 2019, Earth and planetary science letters)

   The hydrogen isotope value (δD) of water indigenous to the mantle is masked by the early degassing and recycling of surface water through Earth’s history. High 3He/4He ratios in some ocean island basalts, however, provide a clear geochemical signature of deep, primordial mantle that has been isolated within the Earth’s interior from melting, degassing, and convective mixing with the upper mantle. Hydrogen isotopes were measured in high 3He/4He submarine basalt glasses from the Southeast Indian Ridge (SEIR) at the Amsterdam–St. Paul (ASP) Plateau (δD =−51 to −90, 3He/4He =7.6 to 14.1 RA) and in submarine glasses from Loihi seamount south of the island of Hawaii (δD =−70 to −90, 3He/4He =22.5 to 27.8 RA). These results highlight two contrasting patterns of δD for high 3He/4He lavas: one trend toward high δD of approximately −50, and another converging at δD =−75. These same patterns are evident in a global compilation of previously reported δD and 3He/4He results. We suggest that the high δD values result from water recycled during subduction that is carried into the source region of mantle plumes at the core–mantle boundary where it is mixed with primordial mantle, resulting in high δD and moderately high 3He/4He. Conversely, lower δD values of −75, in basalts from Loihi seamount and also trace element depleted mid-ocean ridge basalts, imply a primordial Earth hydrogen isotopic value of −75or lower. δD values down to −100also occur in the most trace element-depleted mid-ocean ridge basalts, typically in association with 87Sr/86Sr ratios near 0.703. These lower δD values may be a result of multi-stage melting history of the upper mantle where minor D/H fractionation could be associated with hydrogen retention in nominally anhydrous residual minerals. Collectively, the predominance of δD around −75in the majority of mid-ocean ridge basalts and in high 3He/4He Loihi basalts is consistent with an origin of water on Earth that was dominated by accretion of chondritic material. 

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2. 2019. Hydrogen isotopes in high 3He/4He submarine basalts: Primordial vs. recycled water and the veil of mantle enrichment. , 508, .

   Loewen, Matthew W. (February 2019, Earth and planetary science letters)

   The hydrogen isotope value (δD) of water indigenous to the mantle is masked by the early degassing and recycling of surface water through Earth's history. High 3He/4He ratios in some ocean island basalts, however, provide a clear geochemical signature of deep, primordial mantle that has been isolated within the Earth's interior from melting, degassing, and convective mixing with the upper mantle. Hydrogen isotopes were measured in high 3He/4He submarine basalt glasses from the Southeast Indian Ridge (SEIR) at the Amsterdam–St. Paul (ASP) Plateau (δD = −51 to −90‰, 3He/4He = 7.6 to 14.1 RA) and in submarine glasses from Loihi seamount south of the island of Hawaii (δD = −70 to −90‰, 3He/4He = 22.5 to 27.8 RA). These results highlight two contrasting patterns of δD for high 3He/4He lavas: one trend toward high δD of approximately −50‰, and another converging at δD = −75‰. These same patterns are evident in a global compilation of previously reported δD and 3He/4He results. We suggest that the high δD values result from water recycled during subduction that is carried into the source region of mantle plumes at the core–mantle boundary where it is mixed with primordial mantle, resulting in high δD and moderately high 3He/4He. Conversely, lower δD values of −75‰, in basalts from Loihi seamount and also trace element depleted mid-ocean ridge basalts, imply a primordial Earth hydrogen isotopic value of −75‰ or lower. δD values down to −100‰ also occur in the most trace element-depleted mid-ocean ridge basalts, typically in association with 87Sr/86Sr ratios near 0.703. These lower δD values may be a result of multi-stage melting history of the upper mantle where minor D/H fractionation could be associated with hydrogen retention in nominally anhydrous residual minerals. Collectively, the predominance of δD around −75‰ in the majority of mid-ocean ridge basalts and in high 3He/4He Loihi basalts is consistent with an origin of water on Earth that was dominated by accretion of chondritic material. 

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3. Crustal fluid contamination in the Bushveld Complex, South Africa: An analogue for subduction zone fluid migration

   https://doi.org/10.1080/00206814.2020.1795734  

   Benson, Erin; Connolly, James A.; Boudreau, Alan E. (August 2020, International Geology Review)

   null (Ed.)

   Crystallization of the 2.06 Ga Bushveld magma formed a 9 km (maximum) sequence of ultramafic and mafic rocks that generated a large volume of country fluid as it thermally metamorphosed a 3+ km section of previously unaltered underlying sedimentary rocks of the Transvaal sequence – a geometry similar to that seen as subducting lithospheric slabs are heated by overlying mantle rocks. The presence of a diatreme (breccia pipe) and other large, pipe-like features in the Bushveld Complex located proximal to diapiric upwelling of the basement rocks suggest that overpressured fluids generated during dehydration of the footwall sediments are focused by the diapiric structures such that the country fluids rapidly penetrate the Bushveld rock. A re-examination of existing stable and radiogenic isotopic evidence is consistent with contamination of Main Zone magmas by 1–2% country fluid. Numeric modelling of the footwall dehydration similarly shows that most of the country fluids will be confined to pipe-like channels as it percolates into the Bushveld sill. Modelling also suggests that the maximum extent of the metamorphic aureole was reached at about the same time that the Main Zone began to crystallize. It is proposed that rapid inflation of the Bushveld sill induced the sudden and catastrophic expulsion of overpressured country fluids to both generate the diatreme and contaminate the Main Zone magma, resulting in the Main Zone enrichment in crustal stable and radiogenic isotopic signatures (Sr, Nd, O and others). By analogy, it is also suggested that hydration melting in the mantle wedge is episodically driven by similar sudden influxes of slab fluids that are able to retain their geochemical and isotopic character by rapid channelled influx. This can be aided by flow focusing at diapirs structures at the upper slab-mantle contact. 

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4. The Evolution of Cordilleran Topography in the Americas: Records of Surface Uplift and the Onset of Orogenic Collapse, American Geophysical Union Fall Meeting, December 2019.

   Cassel, E.J. (December 2019, American Geophysical Union Fall Meeting 2019)

   High elevation regions cover a relatively small portion of Earth’s surface, but have an out-sized influence on regional hydrology, continental sediment transport, and global climate. What factors control the lifespan of mountains, and what are the mechanics of the transition to orogenic collapse? The Cenozoic morphology and evolution of the Cordilleran orogen is widely studied and debated in both North and South America, particularly the timing and rates of uplift, the links to possible mantle delamination, and the controls on extensional collapse. At least part of this discrepancy is due to the inherent complexity of atmospheric circulation and moisture sourcing in continental interiors, such as in the modern Rocky Mountains and Altiplano, where the distribution of hydrogen and oxygen isotope ratios (δD/δ18O) of precipitation does not correlate with temperature. Here we reconstruct past elevations across the northern and southern Basin and Range of the western U.S. and the Central Andes of southern Peru, using hydrogen isotope ratios (δD) of paleo-precipitation preserved in volcanic glass from widespread air-fall ashes and ignimbrites. Data span from the paleo-Pacific shoreline across the Cordilleran orogen and are paired with new sanidine 40Ar/39Ar geochronology and detailed chemo- and litho-stratigraphy, providing a novel approach to interpreting changes in δD values over space and time. Paleogene data in the western U.S. show that Pacific-sourced moisture crossed a high elevation Cordilleran hinterland prior to reaching what are now the Rocky Mountains and Great Plains. Mixing with Gulf-sourced moisture likely took place over the central and southern Rocky Mountains, making applications of the modern lapse rate or a Rayleigh modeled lapse rate inaccurate as both use a single moisture source. Data from west of the Sevier foreland, dominated by Pacific-sourced moisture, however, reveal the locations of peak Paleogene elevations. Across the southern Peruvian Altiplano, we observe a similar pattern of paleo-air-mass mixing from relatively higher and lower elevation moisture sources. 

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5. The Systematics of Olivine CaO + Cr-Spinel in High-Mg# Arc Volcanic Rocks: Evidence for in-Situ Mantle Wedge Depletion at the Arc Volcanic Front

   https://doi.org/10.1093/petrology/egad085  

   Straub, Susanne M.; Batanova, Valentina; Sobolev, Alexander; Gómez-Tuena, Arturo; Espinasa-Perena, Ramon; Fleming, W. Lindsey; Bindeman, Ilya N.; Stuart, Finlay M.; Widom, Elisabeth; Iizuka, Yoshiyuki (December 2023, Journal of Petrology)

   Abstract We investigated the state of the arc background mantle (i.e. mantle wedge without slab component) by means of olivine CaO and its Cr-spinel inclusions in a series of high-Mg# volcanic rocks from the Quaternary Trans-Mexican Volcanic Belt. Olivine CaO was paired with the Cr# [molar Cr/(Cr + Al) *100] of Cr-spinel inclusions, and 337 olivine+Cr-spinel pairs were obtained from 33 calc-alkaline, high-K and OIB-type arc front volcanic rocks, and three monogenetic rear-arc basalts that lack subduction signatures. Olivine+Cr-spinels display coherent elemental and He–O isotopic systematics that contrast with the compositional diversity of the bulk rocks. All arc front olivines have low CaO (0.135 ± 0.029 wt %) relative to rear-arc olivines which have the higher CaO (0.248 ± 0.028 wt %) of olivines from mid-ocean ridge basalts. Olivine 3He/4He–δ18O isotope systematics confirm that the olivine+Cr-spinels are not, or negligibly, affected by crustal basement contamination, and thus preserve compositional characteristics of primary arc magmas. Variations in melt H2O contents in the arc front series and the decoupling of olivine CaO and Ni are inconsistent with controls on the olivine CaO by melt water and/or secondary mantle pyroxenites. Instead, we propose that low olivine CaO reflects the typical low melt CaO of high-Mg# arc magmas erupting through thick crust. We interpret the inverse correlation of olivine CaO and Cr-spinel Cr# over a broad range of Cr# (~10–70) as co-variations of CaO, Al and Cr of their (near) primary host melts, which derived from a mantle that has been variably depleted by slab-flux driven serial melt extraction. Our results obviate the need for advecting depleted residual mantle from rear- and back-arc region, but do not upset the larger underlying global variations of melt CaO high-Mg# arc magmas worldwide, despite leading to considerable regional variations of melt CaO at the arc front of the Trans-Mexican Volcanic Belt. 

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