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1. Measurements of ¹⁸ O ¹⁸ O and ¹⁷ O ¹⁸ O in the atmosphere and the role of isotope-exchange reactions: ¹⁸ O ¹⁸ O AND ¹⁷ O ¹⁸ O IN THE ATMOSPHERE

   https://doi.org/10.1029/2012JD017992  

   Yeung, Laurence Y.; Young, Edward D.; Schauble, Edwin A. (September 2012, Journal of Geophysical Research: Atmospheres)
2. The Role of Ozone Vibrational Resonances in the Isotope Exchange Reaction ¹⁶ O ¹⁶ O + ¹⁸ O → ¹⁸ O ¹⁶ O + ¹⁶ O: The Time-Dependent Picture

   https://doi.org/10.1021/acs.jpca.9b06139  

   Yuen, Chi Hong; Lapierre, David; Gatti, Fabien; Kokoouline, Viatcheslav; Tyuterev, Vladimir G. (August 2019, The Journal of Physical Chemistry A)
3. Layered and Cubic Semiconductors A Ga M ′ Q ₄ ( A ⁺ = K ⁺ , Rb ⁺ , Cs ⁺ , Tl ⁺ ; M ′ ⁴⁺ = Ge ⁴⁺ , Sn ⁴⁺ ; Q ^2– = S ^2– , Se ^2– ) and High Third-Harmonic Generation

   https://doi.org/10.1021/jacs.0c08638  

   Friedrich, Daniel; Byun, Hye Ryung; Hao, Shiqiang; Patel, Shane; Wolverton, Chris; Jang, Joon Ik; Kanatzidis, Mercouri G. (October 2020, Journal of the American Chemical Society)

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4. High ³ He/ ⁴ He in central Panama reveals a distal connection to the Galápagos plume

   https://doi.org/10.1073/pnas.2110997118  

   Bekaert, David V.; Gazel, Esteban; Turner, Stephen; Behn, Mark D.; de Moor, J. Marten; Zahirovic, Sabin; Manea, Vlad C.; Hoernle, Kaj; Fischer, Tobias P.; Hammerstrom, Alexander; et al (November 2021, Proceedings of the National Academy of Sciences)

   It is well established that mantle plumes are the main conduits for upwelling geochemically enriched material from Earth's deep interior. The fashion and extent to which lateral flow processes at shallow depths may disperse enriched mantle material far (>1,000 km) from vertical plume conduits, however, remain poorly constrained. Here, we report He and C isotope data from 65 hydrothermal fluids from the southern Central America Margin (CAM) which reveal strikingly high 3 He/ 4 He (up to 8.9R A ) in low-temperature (≤50 °C) geothermal springs of central Panama that are not associated with active volcanism. Following radiogenic correction, these data imply a mantle source 3 He/ 4 He >10.3R A (and potentially up to 26R A , similar to Galápagos hotspot lavas) markedly greater than the upper mantle range (8 ± 1R A ). Lava geochemistry (Pb isotopes, Nb/U, and Ce/Pb) and geophysical constraints show that high 3 He/ 4 He values in central Panama are likely derived from the infiltration of a Galápagos plume–like mantle through a slab window that opened ∼8 Mya. Two potential transport mechanisms can explain the connection between the Galápagos plume and the slab window: 1) sublithospheric transport of Galápagos plume material channeled by lithosphere thinning along the Panama Fracture Zone or 2) active upwelling of Galápagos plume material blown by a “mantle wind” toward the CAM. We present a model of global mantle flow that supports the second mechanism, whereby most of the eastward transport of Galápagos plume material occurs in the shallow asthenosphere. These findings underscore the potential for lateral mantle flow to transport mantle geochemical heterogeneities thousands of kilometers away from plume conduits. 

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5. A comprehensive approach for elucidating the interplay between 4f ⁿ⁺¹ and 4f ⁿ 5d ¹ configurations in Ln ²⁺ complexes

   https://doi.org/10.1039/d4sc05438e  

   Beltran-Leiva, Maria J; Moore, William_N G; Jenkins, Tener F; Evans, William J; Albrecht, Thomas E; Celis-Barros, Cristian (January 2025, Chemical Science)

   To advance our ability to control the electronic properties of divalent lanthanides, the interplay between deformation densities, 4f interelectronic repulsion, and ligand field effects is discussed to predict the nature of their ground states. 

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