More Like this

1. Metal–Metal-Bonded Fe ₄ Clusters with Slow Magnetic Relaxation

   https://doi.org/10.1021/acs.inorgchem.2c00865  

   Hertler, Phoebe R.; Kautzsch, Linus; Touchton, Alexander J.; Wu, Guang; Hayton, Trevor W. (July 2022, Inorganic Chemistry)
2. Metal-Catalyzed and Metal-Free Nucleophilic Substitution of 7-I-B ₁₈ H ₂₁

   https://doi.org/10.1021/acs.inorgchem.2c02116  

   Anderson, Kierstyn P.; Djurovich, Peter I.; Rubio, Victoria P.; Liang, Aimee; Spokoyny, Alexander M. (September 2022, Inorganic Chemistry)
3. Tl ₂ Ir ₂ O ₇ : A Pauli Paramagnetic Metal, Proximal to a Metal Insulator Transition

   https://doi.org/10.1021/acs.inorgchem.0c03124  

   Feng, Hai L.; Kang, Chang-Jong; Deng, Zheng; Croft, Mark; Liu, Sizhan; Tyson, Trevor A.; Lapidus, Saul H.; Frank, Corey E.; Shi, Youguo; Jin, Changqing; et al (April 2021, Inorganic Chemistry)

   null (Ed.)
4. Unexpectedly large remanent polarization of Hf _0.5 Zr _0.5 O ₂ metal–ferroelectric–metal capacitor fabricated without breaking vacuum

   https://doi.org/10.1063/5.0029532  

   Lee, Younghwan; Alex Hsain, H.; Fields, Shelby S.; Jaszewski, Samantha T.; Horgan, Madison D.; Edgington, Patrick G.; Ihlefeld, Jon F.; Parsons, Gregory N.; Jones, Jacob L. (January 2021, Applied Physics Letters)

   null (Ed.)
5. Exfoliable Transition Metal Chalcogenide Semiconductor NbSe ₂ I ₂

   https://doi.org/10.1021/acs.inorgchem.3c03493  

   Qu, Kejian; Zhang, Yue; Peng, Cheng; Riedel, Zachary W.; Won, Juyeon; Zhang, Rong; Woods, Toby J.; Devereaux, Tom; van der Zande, Arend M.; Shoemaker, Daniel P. (January 2024, Inorganic Chemistry)

   As the field of exfoliated van der Waals electronics grows to include complex heterostructures, the variety of available in-plane symmetries and geometries becomes increasingly valuable. In this work, we present an efficient chemical vapor transport synthesis of NbSe2I2 with the triclinic space group P1̅. This material contains Nb–Nb dimers and an in-plane crystallographic angle γ = 61.3°. We show that NbSe2I2 can be exfoliated down to few-layer and monolayer structures and use Raman spectroscopy to test the preservation of the crystal structure of exfoliated thin films. The crystal structure was verified by single-crystal and powder X-ray diffraction methods. Density functional theory calculations show triclinic NbSe2I2 to be a semiconductor with a band gap of around 1 eV, with similar band structure features for bulk and monolayer crystals. The physical properties of NbSe2I2 have been characterized by transport, thermal, optical, and magnetic measurements, demonstrating triclinic NbSe2I2 to be a diamagnetic semiconductor that does not exhibit any phase transformation below room temperature. 

   more » « less