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Title: High Performance Air Breathing Flexible Lithium–Air Battery
Lithium–oxygen (Li–O2) batteries possess the highest theoretical energy density (3500 Wh kg−1), which makes them attractive candidates for modern electronics and transportation applications. In this work, an inexpensive, flexible, and wearable Li–O2 battery based on the bifunctional redox mediator of InBr3, MoS2 cathode catalyst, and Fomblin-based oxygen permeable membrane that enable long-cycle-life operation of the battery in pure oxygen, dry air, and ambient air is designed, fabricated, and tested. The battery operates in ambient air with an open system air-breathing architecture and exhibits excellent cycling up to 240 at the high current density of 1 A g−1 with a relative humidity of 75%. The electrochemical performance of the battery including deep-discharge capacity, and rate capability remains almost identical after 1000 cycle in a bending fatigue test. This finding opens a new direction for utilizing high performance Li–O2 batteries for applications in the field of flexible and wearable electronics.  more » « less
Award ID(s):
1729420
NSF-PAR ID:
10301713
Author(s) / Creator(s):
Date Published:
Journal Name:
Small
Volume:
14
Issue:
42
ISSN:
1613-6829
Page Range / eLocation ID:
2102072
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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    Acknowledgment

    This work was partially supported by the U.S. National Science Foundation (NSF) Award No. ECCS-1931088. S.L. and H.W.S. acknowledge the support from the Improvement of Measurement Standards and Technology for Mechanical Metrology (Grant No. 22011044) by KRISS.

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