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Title: Probing Redox Non‐Innocence in Iron–Carbene Complexes {Fe=C(H)Ar} 10–11 by 1,2 H and 13 C Pulse Electron Paramagnetic Resonance
Abstract

We report the synthesis and spectroscopic characterization of a series of iron‐carbene complexes in redox states {Fe=C(H)Ar}10–11. Pulse EPR studies of the1,2H and13C isotopologues of {Fe=C(H)Ar}11reveal the high covalency of the Fe–carbene bonding, leading to a more even spin distribution than commonly observed for reduced Fischer carbenes.

 
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Award ID(s):
1905320
NSF-PAR ID:
10302559
Author(s) / Creator(s):
 ;  ;  
Publisher / Repository:
Wiley Blackwell (John Wiley & Sons)
Date Published:
Journal Name:
Angewandte Chemie International Edition
Volume:
60
Issue:
52
ISSN:
1433-7851
Format(s):
Medium: X Size: p. 27220-27224
Size(s):
["p. 27220-27224"]
Sponsoring Org:
National Science Foundation
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