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Award ID contains: 1905320

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  1. ; ; ( , Angewandte Chemie International Edition)
    Abstract

    We report the synthesis and spectroscopic characterization of a series of iron‐carbene complexes in redox states {Fe=C(H)Ar}10–11. Pulse EPR studies of the1,2H and13C isotopologues of {Fe=C(H)Ar}11reveal the high covalency of the Fe–carbene bonding, leading to a more even spin distribution than commonly observed for reduced Fischer carbenes.

     
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  2. ; ; ; ; ; ; ; ( , Chemical Science)
    57Fe nuclear resonance vibrational spectroscopy (NRVS) is used to study the tetranuclear iron clusters bearing a terminal Fe(iii)–O/OH moiety. The redox states of the three remote basal iron sites modulate the Fe(iii)–O/OH vibrational frequencies.

     
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    Free, publicly-accessible full text available October 9, 2025
  3. ; ; ; ; ( , JACS Au)
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  4. ; ; ; ; ; ( , Journal of the American Chemical Society)
    null (Ed.)
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  5. ; ( , Journal of the American Chemical Society)
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  6. ; ; ( , Inorganic Chemistry)
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