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1. Creep of CarbFix basalt: influence of rock–fluid interaction

   https://doi.org/10.5194/se-13-137-2022  

   Xing, Tiange ; Ghaffari, Hamed O. ; Mok, Ulrich ; Pec, Matej ( January 2022 , Solid Earth)

   Abstract. Geological carbon sequestration provides permanentCO2 storage to mitigate the current high concentration of CO2 inthe atmosphere. CO2 mineralization in basalts has been proven to be oneof the most secure storage options. For successful implementation and futureimprovements of this technology, the time-dependent deformation behavior ofreservoir rocks in the presence of reactive fluids needs to be studied indetail. We conducted load-stepping creep experiments on basalts from theCarbFix site (Iceland) under several pore fluid conditions (dry,H2O saturated and H2O + CO2 saturated) at temperature,T≈80 ∘C and effective pressure, Peff=50 MPa,during which we collected mechanical, acoustic and pore fluid chemistrydata. We observed transient creep at stresses as low as 11 % of thefailure strength. Acoustic emissions (AEs) correlated strongly with strainaccumulation, indicating that the creep deformation was a brittle process inagreement with microstructural observations. The rate and magnitude of AEswere higher in fluid-saturated experiments than in dry conditions. We inferthat the predominant mechanism governing creep deformation is time- andstress-dependent subcritical dilatant cracking. Our results suggest thatthe presence of aqueous fluids exerts first-order control on creepdeformation of basaltic rocks, while the composition of the fluids playsonly a secondary role under the studied conditions. 

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2. The Brittle–Ductile Transition and the Formation of Compaction Bands in the Savonnières Limestone: Impact of the Stress and Pore Fluid

   https://doi.org/10.1007/s00603-022-02963-z  

   Sari, Mustafa ; Sarout, Joel ; Poulet, Thomas ; Dautriat, Jeremie ; Veveakis, Manolis ( January 2022 , Rock Mechanics and Rock Engineering)

   Abstract Carbonate sediments play a prominent role on the global geological stage as they store more than $$60\%$$ 60 % of world’s oil and $$40\%$$ 40 % of world’s gas reserves. Prediction of the deformation and failure of porous carbonates is, therefore, essential to minimise reservoir compaction, fault reactivation, or wellbore instability. This relies on our understanding of the mechanisms underlying the observed inelastic response to fluid injection or deviatoric stress perturbations. Understanding the impact of deformation/failure on the hydraulic properties of the rock is also essential as injection/production rates will be affected. In this work, we present new experimental results from triaxial deformation experiments carried out to elucidate the behaviour of a porous limestone reservoir analogue (Savonnières limestone). Drained triaxial and isotropic compression tests were conducted at five different confining pressures in dry and water-saturated conditions. Stress–strain data and X-ray tomography images of the rock indicate two distinct types of deformation and failure regimes: at low confinement (10 MPa) brittle failure in the form of dilatant shear banding was dominant; whereas at higher confinement compaction bands orthogonal to the maximum principal stress formed. In addition to the pore pressure effect, the presence of water in the pore space significantly weakened the rock, thereby shrinking the yield envelope compared to the dry conditions, and shifted the brittle–ductile transition to lower effective confining pressures (from 35 MPa to 29 MPa). Finally, permeability measurements during deformation show a reduction of an order of magnitude in the ductile regime due to the formation of the compaction bands. These results highlight the importance of considering the role of the saturating fluid in the brittle–ductile response of porous rocks and elucidate some of the microstructural processes taking place during this transition. 

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3. Magnitude Clustering During Stick‐Slip Dynamics on Laboratory Faults

   https://doi.org/10.1029/2024GL109865  

   Khajehdehi, Omid ; Goebel, Thomas_H W ; Dresen, Georg ; Davidsen, Jörn ( October 2024 , Geophysical Research Letters)

   We present an analysis of magnitude clustering of microfractures inferred from acoustic emissions (AEs) during stick‐slip (SS) dynamics of faulted Westerly granite samples in frictional sliding experiments, with and without fluids, under triaxial loading with constant displacement rate. We investigate magnitude clustering in time across periods during, preceding and after macroscopic slip events on laboratory faults. Our findings reveal that magnitude clustering exists such that subsequent AEs tend to have more similar magnitudes than expected. Yet, this clustering only exists during macroscopic slip events and is strongest during major slip events in fluid‐saturated and dry samples. We demonstrate that robust magnitude clustering arises from variations in frequency‐magnitude distributions of AE events during macroscopic slip events. These temporal variations indicate a prevalence of larger AE events right after (0.3–3 s) the SS onset. Hence, magnitude clustering is a consequence of non‐stationarities.

    

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4. Computational Modeling of Creep Behavior in Shales Induced by Fluid-Rock Interaction

   https://doi.org/10.56952/ARMA-2022-0831  

   Prakash, R. ; Abedi, S. ( January 2022 , 56th U.S. Rock Mechanics/Geomechanics Symposium, Santa Fe, New Mexico, USA, June 2022)

   The chemo-mechanical loading of rocks causes the dissolution and precipitation of multiple phases in the rock. This dissolution and precipitation of load-bearing mineral phases lead to the stress redistribution in neighboring phases, which in turn results in deformational changes of the sample composite. The aim of this study is to investigate the link between microstructural evolution and creep behavior of shale rocks subjected to chemo-mechanical loading through modeling time-dependent deformation induced by the dissolution-precipitation process. The model couples the microstructural evolution of the shale rocks with the stress/strain fields inside the material as a function of time. The modeling effort is supplemented with an experimental study where shale rocks were exposed to CO2-rich brine under high temperature and pressure conditions. 3D snapshots of the sample microstructure were generated using segmented micro-CT images of the shale sample. The time-evolving microstructures were then integrated with the Finite element-based mechanical model to simulate the creep induced by dissolution and precipitation processes independent of the intrinsic viscoelasticity/viscoplasticity of the mineral phases. After computation of the time-dependent viscoelastic properties of the shale composite, the combined microstructure model and finite element model were utilized to predict the time-dependent stress and strain fields in different zones of reacted shale.

   Determination of viscous behavior of shale rocks is key in wide range of applications such as stability of reservoirs, stability of geo-structures subjected to environmental forcing, underground storage of hazardous materials and hydraulic fracturing. Short-term creep strains in hydraulic fracturing can change stress fields and in turn can impact the hydraulic fracturing procedures(H. Sone & Zoback, 2010; Hiroki Sone & Zoback, 2013). While long-term creep strains can hamper the reservoir performance due to the reduction in permeability of the reservoir by closing of fractures and fissures(Du, Hu, Meegoda, & Zhang, 2018; Rybacki, Meier, & Dresen, 2016; Sharma, Prakash, & Abedi, 2019; Hiroki Sone & Zoback, 2014). Owing to these significance of creep strain, it is important to understand the viscoelastic/viscoplastic behavior of shales.

    

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5. Effects of H2O–CO2 Fluids, Temperature, and Peridotite Fertility on Partial Melting in Mantle Wedges and Generation of Primary Arc Basalts

   https://doi.org/10.1093/petrology/egad047  

   Lara, Michael ; Dasgupta, Rajdeep ( July 2023 , Journal of Petrology)

   Many lines of evidence from high P–T experiments, thermodynamic models, and natural observations suggest that slab-derived aqueous fluids, which flux mantle wedges contain variable amounts of dissolved carbon. However, constraints on the effects of H2O–CO2 fluids on mantle melting, particularly at mantle wedge P–T conditions, are limited. Here, we present new piston cylinder experiments on fertile and depleted peridotite compositions with 3.5 wt.% H2O and XCO2 [= molar CO2 / (CO2 + H2O)] of 0.04–0.17. Experiments were performed at 2–3 GPa and 1350°C to assess how temperature, peridotite fertility, and XCO2 of slab-derived fluid affects partial melting in mantle wedges. All experiments produce olivine + orthopyroxene +7 to 41 wt.% partial melt. Our new data, along with previous lower temperature data, show that as mantle wedge temperature increases, primary melts become richer in SiO2, FeO*, and MgO and poorer CaO, Al2O3, and alkalis when influenced by H2O–CO2 fluids. At constant P–T and bulk H2O content, the extent of melting in the mantle wedge is largely controlled by peridotite fertility and XCO2 of slab-fluid. High XCO2 depleted compositions generate ~7 wt.% melt, whereas, at identical P–T, low XCO2 fertile compositions generate ~30 to 40 wt.% melt. Additionally, peridotite fertility and XCO2 have significant effects on peridotite partial melt compositions. At a constant P–T–XCO2, fertile peridotites generate melts richer in CaO and Al2O3 and poorer in SiO2, MgO + FeO, and alkalis. Similar to previous experimental studies, at a constant P–T fertility condition, as XCO2 increases, SiO2 and CaO of melts systematically decrease and increase, respectively. Such distinctive effects of oxidized form of dissolved carbon on peridotite partial melt compositions are not observed if the carbon-bearing fluid is reduced, such as CH4-bearing. Considering the large effect of XCO2 on melt SiO2 and CaO concentrations and the relatively oxidized nature of arc magmas, we compare the SiO2/CaO of our experimental melts and melts from previous peridotite + H2O ± CO2 studies to the SiO2/CaO systematics of primitive arc basalts and ultra-calcic, silica-undersaturated arc melt inclusions. From this comparison, we demonstrate that across most P–T–fertility conditions predicted for mantle wedges, partial melts from bulk compositions with XCO2 ≥ 0.11 have lower SiO2/CaO than all primitive arc melts found globally, even when correcting for olivine fractionation, whereas partial melts from bulk compositions with XCO2 = 0.04 overlap the lower end of the SiO2/CaO field defined by natural data. These results suggest that the upper XCO2 limit of slab-fluids influencing primary arc magma formation is 0.04 < XCO2 < 0.11, and this upper limit is likely to apply globally. Lastly, we show that the anomalous SiO2/CaO and CaO/Al2O3 signatures observed in ultra-calcic arc melt inclusions can be reproduced by partial melting of either CO2-bearing hydrous fertile and depleted peridotites with 0 < XCO2 < 0.11 at 2–3 GPa, or from nominally CO2-free hydrous fertile peridotites at P > 3 GPa.

    

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