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1. Pyroxenite melting at subduction zones

   https://doi.org/10.1130/G50929.1  

   Bowman, Emilie E.; Ducea, Mihai N. (February 2023, Geology)

   Abstract Arc magmatism is thought to be driven by peridotite melting in the mantle wedge. Yet pyroxenites are ubiquitous in the melting region beneath magmatic arcs. Because they typically have lower solidi temperatures and higher melt productivities compared to peridotite, pyroxenites likely play a significant role in magma generation. Here, we use the Zn/Fe ratios of a global database of Pliocene–Holocene primitive arc magmas to show that, as the crustal thickness of the overlying plate increases, so does the proportion of pyroxenite-derived melts relative to peridotite-derived melts. In fact, at arcs with crustal thicknesses >40 km, the majority of magmas are sourced from pyroxenite. Major and trace element geochemistry of pyroxenite melts is consistent with derivation from mafic magmas frozen in the mantle en route to the surface. We hypothesize that, as the thickness of the continental crust increases, the mantle wedge is displaced toward higher pressures and cooler temperatures, thereby lowering the extent of peridotite melting and allowing magmas sourced from the pyroxeniteveined mantle to dominate the arc budget. 

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2. Effects of H2O–CO2 Fluids, Temperature, and Peridotite Fertility on Partial Melting in Mantle Wedges and Generation of Primary Arc Basalts

   https://doi.org/10.1093/petrology/egad047  

   Lara, Michael; Dasgupta, Rajdeep (July 2023, Journal of Petrology)

   Abstract Many lines of evidence from high P–T experiments, thermodynamic models, and natural observations suggest that slab-derived aqueous fluids, which flux mantle wedges contain variable amounts of dissolved carbon. However, constraints on the effects of H2O–CO2 fluids on mantle melting, particularly at mantle wedge P–T conditions, are limited. Here, we present new piston cylinder experiments on fertile and depleted peridotite compositions with 3.5 wt.% H2O and XCO2 [= molar CO2 / (CO2 + H2O)] of 0.04–0.17. Experiments were performed at 2–3 GPa and 1350°C to assess how temperature, peridotite fertility, and XCO2 of slab-derived fluid affects partial melting in mantle wedges. All experiments produce olivine + orthopyroxene +7 to 41 wt.% partial melt. Our new data, along with previous lower temperature data, show that as mantle wedge temperature increases, primary melts become richer in SiO2, FeO*, and MgO and poorer CaO, Al2O3, and alkalis when influenced by H2O–CO2 fluids. At constant P–T and bulk H2O content, the extent of melting in the mantle wedge is largely controlled by peridotite fertility and XCO2 of slab-fluid. High XCO2 depleted compositions generate ~7 wt.% melt, whereas, at identical P–T, low XCO2 fertile compositions generate ~30 to 40 wt.% melt. Additionally, peridotite fertility and XCO2 have significant effects on peridotite partial melt compositions. At a constant P–T–XCO2, fertile peridotites generate melts richer in CaO and Al2O3 and poorer in SiO2, MgO + FeO, and alkalis. Similar to previous experimental studies, at a constant P–T fertility condition, as XCO2 increases, SiO2 and CaO of melts systematically decrease and increase, respectively. Such distinctive effects of oxidized form of dissolved carbon on peridotite partial melt compositions are not observed if the carbon-bearing fluid is reduced, such as CH4-bearing. Considering the large effect of XCO2 on melt SiO2 and CaO concentrations and the relatively oxidized nature of arc magmas, we compare the SiO2/CaO of our experimental melts and melts from previous peridotite + H2O ± CO2 studies to the SiO2/CaO systematics of primitive arc basalts and ultra-calcic, silica-undersaturated arc melt inclusions. From this comparison, we demonstrate that across most P–T–fertility conditions predicted for mantle wedges, partial melts from bulk compositions with XCO2 ≥ 0.11 have lower SiO2/CaO than all primitive arc melts found globally, even when correcting for olivine fractionation, whereas partial melts from bulk compositions with XCO2 = 0.04 overlap the lower end of the SiO2/CaO field defined by natural data. These results suggest that the upper XCO2 limit of slab-fluids influencing primary arc magma formation is 0.04 < XCO2 < 0.11, and this upper limit is likely to apply globally. Lastly, we show that the anomalous SiO2/CaO and CaO/Al2O3 signatures observed in ultra-calcic arc melt inclusions can be reproduced by partial melting of either CO2-bearing hydrous fertile and depleted peridotites with 0 < XCO2 < 0.11 at 2–3 GPa, or from nominally CO2-free hydrous fertile peridotites at P > 3 GPa. 

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3. Mantle oxidation by sulfur drives the formation of giant gold deposits in subduction zones

   He, D-Y; Qui, K-F; Simon, AC; Deng, J; Pokrovski, GS; Yu, H-C; Connolly, JAD; Li, S-S; Turner, S; Wang, Q-F; et al (December 2024, PNAS Proceedings of the National Academy of Sciences of the United States of America.)

   Oxidation of the sub-arc mantle driven by slab-derived fluids has been hypothesized to contribute to the formation of gold deposits in magmatic arc environments that host the majority of metal resources on Earth. However, the mechanism by which the infiltration of slab-derived fluids into the mantle wedge changes its oxidation state and affects Au enrichment remains poorly understood. Here, we present the results of a numerical model that demonstrates that slab-derived fluids introduce large amounts of sulfate (S6+) into the overlying mantle wedge that increase its oxygen fugacity by up to 3 to 4 log units relative to the pristine mantle. Our model predicts that as much as 1 wt.% of the total dissolved sulfur in slab-derived fluids reacting with mantle rocks is present as the trisulfur radical ion, S3–. This sulfur ligand stabilizes the aqueous Au(HS)S3– complex, which can transport Au concentrations of several grams per cubic meter of fluid. Such concentrations are more than three orders of magnitude higher than the average abundance of Au in the mantle. Our data thus demonstrate that an aqueous fluid phase can extract 10 to 100 times more Au than in a fluid-absent rock-melt system during mantle partial melting at redox conditions close to the sulfide-sulfate boundary. We conclude that oxidation by slab-derived fluids is the primary cause of Au mobility and enrichment in the mantle wedge and that aqueous fluid-assisted mantle melting is a prerequisite for formation of Au-rich magmatic hydrothermal and orogenic gold systems in subduction zone settings. 

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4. The causes of continental arc flare ups and drivers of episodic magmatic activity in Cordilleran orogenic systems

   https://doi.org/doi.org/10.1016/j.lithos.2021.106307  

   Chapman, J. (July 2021, Lithos)

   null (Ed.)

   Continental arcs in Cordilleran orogenic systems display episodic changes in magma production rate, alternating between flare ups (70–90 km3 km􀀀 1 Myr􀀀 1) and lulls (< 20 km3 km􀀀 1 Myr􀀀 1) on timescales of tens of millions of years. Arc segments or individual magmatic suites may have even higher rates, up several 100 s of km3 km􀀀 1 Myr􀀀 1, during flare ups. These rates are largely determined by estimating volumes of arc crust, but do not reflect melt production from the mantle. The bulk of mantle-derived magmas are recycled back into the mantle by delamination of arc roots after differentiation in the deep crust. Mantle-derived melt production rates for continental arcs are estimated to be 140–215 km3 km􀀀 1 Myr􀀀 1 during flare ups and ≤ 15 km3 km􀀀 1 Myr􀀀 1 during lulls. Melt production rates averaged over multiple magmatic cycles are consistent with independent estimates for partial melting of the mantle wedge in subduction zones, however, the rates during flare ups and lulls are both anomalously high and anomalously low, respectively. The difference in mantle-derived melt production between flare ups and lulls is larger than predicted by petrologic and numerical models that explore the range of globally observed subduction parameters (e.g., convergence rate, height of the mantle wedge). This suggests that other processes are required to increase magmatism during flare ups and suppress magmatism during lulls. There are many viable explanations, but one possibility is that crystallized melts from the asthenospheric mantle wedge are temporarily stored in the deep lithosphere during lulls and then remobilized during flare ups. Basaltic melts may stall in the mantle lithosphere in inactive parts of the arc system, like the back-arc, refertilizing the mantle lithosphere and suppressing melt delivery to the lower crust. Subsequent landward arc migration (i.e., toward the interior of the continent) may encounter such refertilized mantle lithosphere magma source regions, contributing to magmatic activity during a flare up. A review of continental arcs globally suggests that flare ups commonly coincide with landward arc migration and that this migration may start tens of millions of years before the flare up occurs. The region of magmatic activity, or arc width, can also expand significantly during a flare up. Arc migration or expansion into different mantle source regions and across lithospheric and crustal boundaries can cause temporal shifts in the radiogenic isotopic composition of magmatism. In the absence of arc migration, temporal shifts are more muted. Isotopic studies of mantle xenoliths and exposures of deep arc crust suggest that that primary, mantle-derived magmas generated during flare ups reflect substantial contributions from the subcontinental mantle lithosphere. Arc migration may be caused by a variety of mechanisms, including slab anchoring or slab folding in the mantle transition zone that could generate changes in slab dip. Episodic slab shallowing is associated with many tectonic processes in Cordilleran orogenic systems, like alternations between shortening and extension in the upper plate. Studies of arc migration may help to link irregular magmatic production in continental arcs with geodynamic models for orogenic cyclicity. 

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5. Multiple Episodes of Rock-Melt Reaction at the Slab-Mantle Interface: Formation of High Silica Primary Magmas in Intermediate to Hot Subduction Zones

   https://doi.org/10.1093/petrology/egad011  

   Rebaza, Anna M; Mallik, Ananya; Straub, Susanne M (March 2023, Journal of Petrology)

   Abstract Siliceous slab-derived partial melts infiltrate the sub-arc mantle and cause rock-melt reactions, which govern the formation of diverse primary arc magmas and lithological heterogeneities. The effect of bulk water content, composition of reactants, and nature of melt infiltration (porous versus channelized) on the rock-melt reactions at sub-arc conditions have been investigated by previous studies. However, the effect of multiple episodes of rock-melt reactions in such scenarios has not been investigated before. Here, we explore mantle wedge modifications through serial additions of hydrous-silicic slab partial melts and whether such a process may ultimately explain the origin of high-Mg# andesites found in arcs worldwide. A series of piston-cylinder experiments simulate a serial addition of silicic slab melts in up to three stages (I through III) at 3 GPa and 800–1050°C, using rock-melt proportions of 75–25 and 50–50. A synthetic KLB-1 and a natural rhyolite (JR-1) represented the mantle and the slab components, respectively. Right from the first rock-melt interaction, the peridotite mantle transforms into olivine-free mica-rich pyroxenites ± amphibole ± quartz/coesite in equilibrium with rhyolitic-hydrous melts (72–80 wt% SiO2 and 40–90 Mg#). The formation of olivine-free pyroxenite seems to be controlled by complex functions of T, P, rock-melt ratio, wedge composition, and silica activity of the slab-melt. Remarkably, the pyroxenites approach a melt-buffered state with progressive stages of rock-melt reactions, where those rhyolitic melts inherit and preserve the major (alkalis, Fe, Mg, Ca) and trace element slab-signature. Our results demonstrate that lithological heterogeneities such as pyroxenites formed as products of rock-melt reactions in the sub-arc mantle may function as melt ‘enablers,’ implying that they may act as pathways that enable the infiltrating melt to retain their slab signature without undergoing modification. Moreover, the density contrast between the products of rock-melt reaction (melts and residues) and the average mantle wedge (~150 to 400 kg/m3) may help forming instabilities and diapiric rise of the slab components into the mantle wedge. However, the fate of the primitive slab-melts seems to be associated with the length of the pathway of mantle interaction which explains the evident wide magma spectrum as well as their degree of slab garnet-signature dilution. This work and the existence of high-Mg# Mexican-trondhjemites indicates that almost pristine slab-melts can make their way up to crustal levels and contribute to the arc magma diversity. 

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