skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.

Explore Research Products in the PAR
It may take a few hours for recently added research products to appear in PAR search results.


Title: Recent developments in reactivity testing of supplementary cementitious materials
Identification and rapid characterization of novel supplementary cementitious materials (SCMs) is a critical need, driven by shortfalls in conventional SCMs. In this study, we present a discussion of recently developed reactivity tests – the R3 test, the modified R3 test, the lime strength test, and the bulk resistivity index test. These tests measure reactivity parameters such as heat release, bound water, calcium hydroxide consumption, strength, and bulk resistivity. All tests can screen inert from reactive materials. To additionally differentiate pozzolanic and latent hydraulic materials, two parameters, for example, calcium hydroxide consumption and heat release, are needed. The influences of SCM bulk chemistry, amorphous content, and fineness on measured reactivity are outlined. Reactivity test outputs can predict strength and durability of cement paste/mortar/concrete; however, caution must be exercised as these properties are influenced by a variety of other factors independent of reactivity. Thoughts are provided on using reactivity tests to screen materials for concrete durability.  more » « less
Award ID(s):
2101961
PAR ID:
10314736
Author(s) / Creator(s):
Date Published:
Journal Name:
RILEM Technical Letters
Volume:
6
ISSN:
2518-0231
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. ; ; (, Designs)
    The alkali–silica reaction (ASR) is a critical concern for concrete durability, yet its assessment remains challenging and directly impacts mixture design decisions. This review shows that the inconsistencies are more prevalent in mitigation evaluations compared to aggregate reactivity assessments, mainly due to the chemical variations in supplementary cementitious materials (SCMs). A validated framework is suggested to determine the optimal SCM replacement levels for ASR mitigation based on extensive field data, offering direct guidance for mix design decisions involving potentially reactive aggregates. The combination of the accelerated mortar bar test (AMBT) and the miniature concrete prism test (MCPT) is shown to be a reliable alternative for the concrete prism test (CPT) in aggregate reactivity. Also, their extended versions, AMBT (28-day) and MCPT (84-day), can be applied for SCMs mitigation evaluation. Given the slower reactivity of SCMs compared to ordinary Portland cement (OPC), the importance of incorporating indirect test methods, such as the modified R3 test and bulk resistivity is underscored. In addition, emerging sustainability shifts further complicate ASR assessment, including the adoption of Portland limestone cement (PLC), the use of seawater in concrete, and the declining availability of fly ash (FA) and slag. These changes call for updated ASR testing specifications and increased research into natural pozzolans (NPs) as promising SCMs for future ASR mitigation. 
    more » « less
  2. ; ; ; ; ; (, Transportation Research Record: Journal of the Transportation Research Board)
    This study characterized and evaluated the use of reclaimed fly ash (RFA) and reclaimed ground bottom ash (GBA) as alternative sources of supplementary cementitious materials (SCMs) for the production of concrete mixtures. Conventional Class F fly ash (FA) was also evaluated for comparison. The effects of SCM content on fresh and hardened properties of concrete were investigated by replacing 10%, 20%, and 30% of cement by mass. Characterization results showed that all three ashes met ASTM C618 chemical requirements (i.e., sum of SiO 2  + Al 2 O 3  + Fe 2 O 3 , CaO, SO 3 , moisture content, and loss of ignition) and 7- and 28-days strength activity index (SAI) requirements for Class F FA. In addition, RFA exhibited slightly higher SAI at 28 days of curing, followed by GBA and FA. In relation to fresh concrete properties, FA increased the concrete slump compared with the control mixture, whereas RFA and GBA decreased the concrete slump. However, GBA produced more significant slump decrements than RFA, which was attributed to the irregular angular particles of GBA. Generally, all the coal ashes produced decrements in air content compared with the control mixture. Comparatively, among the three ashes, GBA exhibited the highest 28- and 90-days compressive strength and surface resistivity (SR) at all cement replacement levels. Furthermore, at 90 days of curing, RFA and GBA concrete mixtures outperformed the FA concrete mixtures in relation to compressive strength and SR. Consequently, both RFA and GBA are promising SCMs for concrete materials. 
    more » « less
  3. ; ; ; ; ; ; ; (, Third RILEM International Conference on Concrete and Digital Fabrication. DC 2022.)
    The rising interest in 3D-printing of concrete structures for use in marine environments requires development of concrete mixtures with adequate mechanical and durability characteristics. The incorporation of alternative cementitious materials, combined with careful selection of printing parameters has emerged as an effective way of controlling not only the fresh properties and printability of mixtures, but also their mechanical and durability properties. This paper presents the results of various durability related tests performed on 3D-printed mortars, including density, porosity, rate of water absorption and resistance to chloride penetration. Results of these tests indicate that the performance of mortar elements 3D-printed using controlled overlap process was similar to the performance of conventionally cast mortar elements with the same composition. Moreover, the results of the chloride transport related tests obtained from all specimens evaluated during the course of the study indicate low chloride ion penetrability, thus re-affirming that combination of the proposed material and 3D-printing method of fabrication have a potential for producing structural elements for applications in marine environments. 
    more » « less
  4. ; ; ; (, RILEM Technical Letters)
    Strategic blending of supplementary cementitious materials (SCMs) into ordinary portland cement (OPC) helps reduce energy use and greenhouse gas emissions from concrete production. Expanding thermodynamic databases to include new reaction products from blended cements improves computational approaches used to understand the impact of blending SCMs with cement. Determination of thermodynamic parameters of cement reaction products based on temperature-dependent solubility is widely used in cement research; however, assumptions, limitations, and potential errors due to intercorrelation of the thermodynamic parameters in these calculation methods are rarely discussed. Here, methods for obtaining thermodynamic parameters are critically reviewed, including discussion of experimental validation. The discussion herein provides useful guidance to improve and validate the process of determining thermodynamic parameters of new reaction products from SCM-OPC reactions. 
    more » « less
  5. ; ; ; ; (, Journal of Testing and Evaluation)
    Abstract Glass fiber reinforced polymer (GFRP) bars are composite materials that, in the field of civil engineering, serve as an alternative for the internal steel reinforcement of concrete structures. The study and development of these material systems in construction are relatively new, requiring targeted research and development to achieve greater adoption. In this scenario, research and standardization play crucial roles. The development and publication of new test methods, material specifications, and other standards, as well as the improvement of the existing ones, allow for quality control, validation, and acceptance. One of these improvements is the evaluation of precision statements of the different ASTM standards related to the physical-mechanical and durability characterization of GFRP bars used as internal concrete reinforcement. Precision refers to how closely test results obtained under specific conditions agree with each other. A precision statement allows potential users to assess the test method’s general suitability for their intended applications. It should provide guidance on the type of variation that can be expected between test results when the method is used in one or more competent laboratories. The present study aims to enhance the precision statements in ASTM standards pertaining to the geometric, material, mechanical, and physical properties required for GFRP bars in concrete reinforcement, including ASTM standards like ASTM D7205M-21, Standard Test Method for Tensile Properties of Fiber Reinforced Polymer Matrix Composite Bars; ASTM D7617M-11(2017), Standard Test Method for Transverse Shear Strength of Fiber-Reinforced Polymer Matrix Composite Bars; and ASTM D7913M-14(2020), Standard Test Method for Bond Strength of Fiber-Reinforced Polymer Matrix Composite Bars to Concrete by Pullout Testing, while in accordance with the statistical procedures and calculation methods outlined in ASTM Practices ASTM E177-20, Standard Practice for Use of the Terms Precision and Bias in ASTM Test Methods, and ASTM E691-22, Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method. 
    more » « less
  • Citation Formats
  • MLA
  • APA
  • Chicago
  • BibTeX
  • Save / Share this Record
  • Send to Email