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   https://doi.org/10.1021/jacs.9b12081  

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2. Spectroscopic characterization of metal ligation in trinuclear iron-μ 3 -oxo-based complexes and metal-organic frameworks

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   Hanna, Lauren ; Kucheryavy, Pavel ; Lahanas, Nicole ; Lockard, Jenny V. ( May 2019 , The Journal of Chemical Physics)
3. Water-soluble dinuclear iridium( iii ) and ruthenium( ii ) bis-terdentate complexes: photophysics and electrochemiluminescence

   https://doi.org/10.1039/D2DT02104H  

   Liu, Bingqing ; Yang, Xin ; Jabed, Mohammed ; Kilina, Svetlana ; Yang, Zhengchun ; Sun, Wenfang ( September 2022 , Dalton Transactions)

   The synthesis, photophysics, and electrochemiluminescence (ECL) of four water-soluble dinuclear Ir( iii ) and Ru( ii ) complexes (1–4) terminally-capped by 4′-phenyl-2,2′:6′,2′′-terpyridine (tpy) or 1,3-di(pyrid-2-yl)-4,6-dimethylbenzene (N^C^N) ligands and linked by a 2,7-bis(2,2′:6′,2′′-terpyridyl)fluorene with oligoether chains on C9 are reported. The impact of the tpy or N^C^N ligands and metal centers on the photophysical properties of 1–4 was assessed by spectroscopic methods including UV-vis absorption, emission, and transient absorption, and by time-dependent density functional theory (TDDFT) calculations. These complexes exhibited distinct singlet and triplet excited-state properties upon variation of the terminal-capping terdentate ligands and the metal centers. The ECL properties of complexes 1–3 with better water solubility were investigated in neutral phosphate buffer solutions (PBS) by adding tripropylamine (TPA) as a co-reactant, and the observed ECL intensity followed the descending order of 3 > 1 > 2. Complex 3 bearing the [Ru(tpy) 2 ] 2+ units displayed more pronounced ECL signals, giving its analogues great potential for further ECL study. 

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