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1. Evidence of Diminished WAIS and Open Interior Seaway, from Distinctive Dropstones in Amundsen Sea that Originated in the Ellsworth Mountains

   Siddoway, Christine; Thomson, Stuart; Hemming, Sidney; CURE undergraduates; Expedition 379 scientists; and Expedition 382 scientists (September 2022, 29th West Antarctic Ice Sheet Workshop)

   IODP Expedition 379 to the Amundsen Sea continental rise recovered latest Miocene-Holocene sediments from two sites on a drift in water depths >3900m. Sediments that are dominated by clay and silty clay host pebbles and cobbles of ice-rafted detritus (IRD) (Gohl et al. 2021, doi: 10.14379/iodp.proc.379.2021). Cobble-sized dropstones also appear as fall-in, in the top of cores recovered from sediments >5.3 Ma. The principle means to deposit abundant IRD and sparse dropstones in deep sea sediment is through melting of icebergs released by Antarctic ice-sheet calving events. We use petrological and age characteristics of clasts from the Exp379 sites to fingerprint their bedrock provenance to extend knowledge of subglacial bedrock, and with the intention to illuminate changes in icesheet extent between 7 – 3 Ma that lend credence to forecasts of extensive future change. Mapped onshore geology shows pronounced distinctions in bedrock age between tectonic provinces of West or East Antarctica (e.g. Cox et al. 2020, doi:10.21420/7SH7-6K05; Jordan et al. 2020, doi.org/10.1038/s43017-019-0013-6). This allows us to use geochronology and thermochronology of rock clasts and minerals for tracing their provenance, and hence ascertain whether IRD deposited at the 379 drillsites originated from proximal or distal Antarctic sources. We here report zircon and apatite U-Pb dates from several sand samples and dropstones taken from latest Miocene, early Pliocene, and Plio-Pleistocene-boundary sediments. Additional Hf isotope data, and apatite fission track and 40Ar/39Ar Kfeldspar ages for some of the same samples help to strengthen provenance interpretations. The study revealed three distinct zircon age populations at ca. 100, 175, and 250 Ma. Using Kolmogorov-Smirnov (K-S) statistical tests to compare our new igneous and detrital zircon (DZ) U-Pb results with previously published data, we found strong similarities to West Antarctic bedrock, but low correspondence to prospective sources in East Antarctica, implying a role for icebergs calved from the West Antarctic Ice Sheet (WAIS). The ~100 Ma age resembles plutonic ages from Marie Byrd Land and islands in Pine Island Bay. The ~250 and 175 Ma populations match published mineral dates from shelf sediments in the eastern Amundsen Sea Embayment as well as granite ages from the Antarctic Peninsula and the Ellsworth-Whitmore Mountains (EWM). The different derivation of coarse sediment sources requires changes in iceberg origin through the latest Miocene, early Pliocene, and Plio/Pleistocene, likely the result of changes in WAIS extent. One unique dropstone recovered from Exp379 Site U1533B is green quartz arenite, which yielded mostly 500-625 Ma detrital zircons. In visual appearance and dominant U-Pb age population, it resembles a sandstone dropstone recovered from Exp382 Site U1536 in the Scotia Sea (Hemming et al. 2020, https://gsa.confex.com/gsa/2020AM/meetingapp.cgi/Paper/357276). K-S tests yield high values (P ≥ 0.6), suggesting a common provenance for both dropstones recovered from late Miocene to Pliocene sediments, despite the 3270 km distance separating the sites. Comparisons to published data, in progress, narrow the group of potential on-land sources to exposures in the EWM or isolated ranges at far south latitudes in the Antarctic interior. If both dropstones originated from the same source area, they signify that dramatic shifts in the WAIS grounding line position do occur, along with periodic opening of a seaway connecting the Amundsen and Weddell Seas. 

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2. U-Pb zircon geochronology of dropstones and IRD in the Amundsen Sea, applied to the question of bedrock provenance and Miocene-Pliocene ice sheet extent in West Antarctica

   https://doi.org/10.5194/egusphere-egu21-9151  

   Siddoway, C.; Thomson, S.; Hemming, S.; Buchband, H.; Furlong, H.; Hilderman, R.; Robinson, D.; Watkins, C.; Cox, S.; Licht, K.; et al (April 2021, EGU General Assembly 2021)

   IODP Expedition 379 to the Amundsen Sea continental rise recovered latest Miocene-Holocene sediments from two sites on a drift in water depths >3900m. Sediments are dominated by clay and silty clay with coarser-grained intervals and ice-rafted detritus (IRD) (Gohl et al. 2021, doi:10.14379/iodp.proc.379.2021). Cobble-sized dropstones appear as fall-in, in cores recovered from sediments >5.3 Ma. We consider that abundant IRD and the sparse dropstones melted out of icebergs formed due to Antarctic ice-sheet calving events. We are using petrological and age characteristics of the clasts from the Exp379 sites to fingerprint their bedrock provenance. The results may aid in reconstruction of past changes in icesheet extent and extend knowledge of subglacial bedrock. Mapped onshore geology shows pronounced distinctions in bedrock age between tectonic provinces of West or East Antarctica (e.g. Cox et al. 2020, doi:10.21420/7SH7-6K05; Jordan et al. 2020, doi.org/10.1038/s43017-019-0013-6). This allows us to use geochronology and thermochronology of rock clasts and minerals for tracing their provenance, and ascertain whether IRD deposited at IODP379 drillsites originated from proximal or distal Antarctic sources. We here report zircon and apatite U-Pb dates from four sand samples and five dropstones taken from latest Miocene, early Pliocene, and Plio-Pleistocene-boundary sediments. Additional Hf isotope data, and apatite fission track and 40Ar/39Ar Kfeldspar ages for some of the same samples help to strengthen provenance interpretations. The study revealed three distinct zircon age populations at ca. 100, 175, and 250 Ma. Using Kolmogorov-Smirnov (K-S) statistical tests to compare our new igneous and detrital zircon (DZ) U-Pb results with previously published data, we found strong similarities to West Antarctic bedrock, but low correspondence to prospective sources in East Antarctica, implying a role for icebergs calved from the West Antarctic Ice Sheet (WAIS). The ~100 Ma age resembles plutonic ages from Marie Byrd Land and islands in Pine Island Bay. The ~250 and 175 Ma populations match published mineral dates from shelf sediments in the eastern Amundsen Sea Embayment as well as granite ages from the Antarctic Peninsula and the Ellsworth-Whitmore Mountains (EWM). The different derivation of coarse sediment sources requires changes in iceberg origin through the latest Miocene, early Pliocene, and Plio/Pleistocene, likely the result of changes in WAIS extent. One unique dropstone recovered from Exp379 Site U1533B is green quartz arenite, which yielded mostly 500-625 Ma detrital zircons. In visual appearance and dominant U-Pb age population, it resembles a sandstone dropstone recovered from Exp382 Site U1536 in the Scotia Sea (Hemming et al. 2020, https://gsa.confex.com/gsa/2020AM/meetingapp.cgi/Paper/357276). K-S tests yield high values (P ≥ 0.6), suggesting a common provenance for both dropstones recovered from late Miocene to Pliocene sediments, despite the 3270 km distance separating the sites. Comparisons to published data, in progress, narrow the group of potential on-land sources to exposures in the EWM or isolated ranges at far south latitudes in the Antarctic interior. If both dropstones originated from the same source area, they could signify dramatic shifts in the WAIS grounding line position, and the possibility of the periodic opening of a seaway connecting the Amundsen and Weddell Seas. https://meetingorganizer.copernicus.org/EGU21/EGU21-9151.html 

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3. Interpreting detrital modes and geochemistry of sandstones from the late Paleozoic Tepuel-Genoa Basin: Paleogeographic implications (Patagonia, Argentina)

   https://doi.org/https://doi.org/10.1016/j.jsames.2020.102858  

   Ciccioli, P. L.; Limarino, C. O.; Isbell, J.L.; Taboada, A. C.; Pagani, M. A.; Gulbranson, E.L. (September 2020, Journal of South American earth sciences)

   null (Ed.)

   The provenance of sandstones deposited in the late Paleozoic Tepuel-Genoa Basin is analyzed in this paper. Five sections were sampled in Esquel, Sierra de Tepuel, Sierra de Tecka, El Molle, and Río Genoa areas for petrographic and geochemical studies. The sandstones in the Tepuel-Genoa Basin are dominated by feldspathic litharenites and litharenites, showing lithic fragments of volcanic and sedimentary rocks in the Valle Chico Formation and medium-to high-grade metamorphic rock clasts in the rest of the units. Detrital modes of seventy-five sandstones samples from the Valle Chico, Pampa de Tepuel, Moj´on de Hierro, and Río Genoa formations were counted and analyzed. Seven modal components have discriminant value for identifying provenance areas (Qm, Qi, Lv, Lmm-h, Lm-Lp, Lm, Qpm). These modal components allow identification of three petrofacies: 1. Quartzose-lithic (Qm69Lv2Lm29), 2. Quartzose (Qm89Lv4Lm7) and 3. Volcanic-sedimentary (Qm60Lv38Lm1). The quartzose-lithic petrofacies is mainly composed of monocrystalline quartz, medium- and high-grade metamorphic clasts and polycrystalline quartz with cataclastic texture, this assemblage is interpreted as being derived from the crystalline rocks that form the Deseado Massif. The quartzose petrofacies is composed of monocrystalline quartz with scarce contributions of metamorphic clasts and traces of volcanic fragments; the provenance area is ascribed to sedimentary terrains, which most likely covered part of the Deseado Massif. The volcanic-sedimentary petrofacies is comprised of volcanic (acidic and intermediate rocks) and sedimentary (sandstone and mudstone) clasts, with discrete amounts of quartz grains with idiomorph shapes and embayments. This assemblage may correspond to material supply from the Devonian-Early Carboniferous accretionary complex developed in Chile or the unroofing of the western volcanic arc located in the central part of Patagonia. The validity of the three defined petrofacies was evaluated using Principal Component Analysis and triangular compositional diagrams; both methods show good separation and lack of overlap between the three petrofacies. Major (Si, Al, Fe, Na, K) and trace-REE elements (Zr, Th, Sc, Hf) were used to improve the petrographic information. The relation SiO2 against K2O/Na2O indicates that the Pampa de Tepuel and the Moj´on de Hierro formations correspond to a passive margin, while the Valle Chico and Río Genoa formations represent different types of active continental margins. The Th/Sc and Zr/Sc ratios and the Th-Hf-Co distributions indicate that the sandstones of the Tepuel Group were formed from rocks compatibles with the average composition of the upper continental crust. 

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4. Regional Antarctic snow accumulation over the past 1000 years

   https://doi.org/10.5194/cp-13-1491-2017  

   Thomas, Elizabeth R.; van Wessem, J. Melchior; Roberts, Jason; Isaksson, Elisabeth; Schlosser, Elisabeth; Fudge, Tyler J.; Vallelonga, Paul; Medley, Brooke; Lenaerts, Jan; Bertler, Nancy; et al (January 2017, Climate of the Past)

   null (Ed.)

   Abstract. Here we present Antarctic snow accumulation variability at the regional scale over the past 1000 years. A total of 79 ice core snow accumulation records were gathered and assigned to seven geographical regions, separating the high-accumulation coastal zones below 2000 m of elevation from the dry central Antarctic Plateau. The regional composites of annual snow accumulation were evaluated against modelled surface mass balance (SMB) from RACMO2.3p2 and precipitation from ERA-Interim reanalysis. With the exception of the Weddell Sea coast, the low-elevation composites capture the regional precipitation and SMB variability as defined by the models. The central Antarctic sites lack coherency and either do not represent regional precipitation or indicate the model inability to capture relevant precipitation processes in the cold, dry central plateau. Our results show that SMB for the total Antarctic Ice Sheet (including ice shelves) has increased at a rate of 7 ± 0.13 Gt decade−1 since 1800 AD, representing a net reduction in sea level of ∼ 0.02 mm decade−1 since 1800 and ∼ 0.04 mm decade−1 since 1900 AD. The largest contribution is from the Antarctic Peninsula (∼ 75 %) where the annual average SMB during the most recent decade (2001–2010) is 123 ± 44 Gt yr−1 higher than the annual average during the first decade of the 19th century. Only four ice core records cover the full 1000 years, and they suggest a decrease in snow accumulation during this period. However, our study emphasizes the importance of low-elevation coastal zones, which have been under-represented in previous investigations of temporal snow accumulation. 

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5. Inventory of ice-rafted clasts and sediment constituents that track with dynamic ice-margin processes and biological productivity, Amundsen Sea region, Antarctica

   Siddoway, Christine S. (April 2023, EGU General Assembly 2023)

   Marine sediments, obtained from cores and captures from deep sea and continental shelf sites of West Antarctica, contain rich records of latest Miocene to Present glacial and deglacial processes and conditions at the margin of the West Antarctic ice sheet (WAIS). The materials we are investigating were recovered from a) Resolution Drift on the Amundsen Sea continental rise (water depths >3900m), b)the continental shelf in the Amundsen Sea, Wrigley Gulf, and Sultzberger Bay (water depths <1000m). Resolution Drift cores were drilled by IODP Expedition 379 (Gohl et al., doi:10.14379/iodp.proc.379.2021) in sediments dominated by compacted clay and silty clay, with conglomeratic intervals of ice-rafted detritus (IRD) and downslope deposits. The shelf sediments were recovered by piston core, trigger core, and Smith McIntyre Grab (SMG) during USA research cruises of the RVIB Nathaniel B Palmer (1999, 2000, 2007) and USCGC Glacier (1983). The shelf samples are non-compacted clay, containing abundant cobbles, pebbles and biogenic fragments. Our research focuses upon rock clasts, detrital apatite and zircon, felsic volcanic tephra, and micro-manganese nodules separated from marine and glaciomarine clay. The rock clasts and detrital minerals represent samples of continental crust that we characterise according to rock type, petrology, geochemistry, and geo-thermochronology [U-Pb, (U-Th)/He, and fission track methods]. These characteristics illuminate solid Earth processes, including the development of subglacial topography . We compared clasts’ petrology and age data to the exposed onshore geology and thermochronology of bedrock, and determined that ≥90% of clasts likely originated in West Antarctica. Therefore the materials can be used to assign roughness, erodibility, and heat production factors for subglacial bedrock, which constitute boundary conditions used by ice sheet modelers. Rhyolite ash and fragments provide new evidence for explosive eruptions (dated ca. 2.55 to 2.92 Ma; feldspar 40Ar/39Ar) delivered to sea as airfall, IRD, and possible subglacial water transport. Silicic eruptions produce ash and aerosols that may screen solar energy, and provide bio-available nutrients that produce phytoplankton blooms leading to sequestration of carbon. The rhyolite dates coincide with the end of a Pliocene warm period recorded in IODP379 cores (Gille-Petzoldt et al., 10.3389/feart.2022.976703). Our work in progress seeks to obtain higher resolution geochronology in order to determine whether silicic continental volcanism occurred in response to ice unloading due to deglaciation (cf. Lin et al., 10.5194/cp-18-485-2022) and whether erupted products contributed to latest Pliocene significant cooling and WAIS re-glaciation. Another distinctive sediment constituent is micro-manganese nodules of unusual form. Whereas typical micro-MN nodules are dark, formed of concentric layers, this form is pale in color, ‘barbell’ shaped, and transparent in transmitted light. Scanning electron microscopy shows these to be microcrystalline Mn-oxide with embedded grains of quartz and feldspar, which likely served as seed material. Mn-oxides form by authigenesis at/near the seafloor surface, requiring high oxygen concentrations in the bottom water and low sedimentation rates, generally associated with the end of glacials/during interglacials (Hillenbrand et al. 2021, 10.1029/2021GL093103). Work is in progress to determine whether Mn oxides formed through passive accretion upon seed grains or microbially-mediated precipitation from Mn-oxyhydroxides or colloids, of possible relevance for coastal carbon budgets. https://doi.org/10.5194/egusphere-egu23-9728 

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