Paleomagnetic observations provide valuable evidence of the strength of magnetic fields present during evolution of the Solar System. Such information provides important constraints on physical processes responsible for rapid accretion of the protoplanetesimal disk. For this purpose, magnetic recordings must be stable and resist magnetic overprints from thermal events and viscous acquisition over many billions of years. A lack of comprehensive understanding of magnetic domain structures carrying remanence has, until now, prevented accurate estimates of the uncertainty of recording fidelity in almost all paleomagnetic samples. Recent computational advances allow detailed analysis of magnetic domain structures in iron particles as a function of grain morphology, size, and temperature. Our results show that uniformly magnetized equidimensional iron particles do not provide stable recordings, but instead larger grains containing single-vortex domain structures have very large remanences and high thermal stability—both increasing rapidly with grain size. We derive curves relating magnetic thermal and temporal stability demonstrating that cubes (>35 nm) and spheres (>55 nm) are likely capable of preserving magnetic recordings from the formation of the Solar System. Additionally, we model paleomagnetic demagnetization curves for a variety of grain size distributions and find that unless a sample is dominated by grains at the superparamagnetic size boundary, the majority of remanence will block at high temperatures ( ∼ 100 ° C of Curie point). We conclude that iron and kamacite (low Ni content FeNi) particles are almost ideal natural recorders, assuming that there is no chemical or magnetic alteration during sampling, storage, or laboratory measurement.
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Magnetic hysteresis of magnetite, pyrrhotite and hematite at high temperature
SUMMARY The magnetic properties of iron-bearing minerals at above-ambient temperatures control their magnetic expression at depth in the Earth and other planets, as well as the permanent memory they retain as thermoremanence or thermochemical remanence when brought to the surface and cooled. This paper reports magnetic hysteresis parameters measured at temperatures up to the Curie point TC for natural pyrrhotite and hematite and for suites of sized magnetites, both natural and synthesized. Domain structure changes can be inferred from the ratio of saturation remanence Mrs to saturation magnetization Ms. In almost all magnetites and pyrrhotites studied, Mrs decreases more rapidly with increasing measurement temperature T than Ms, indicating thermal unblocking or vortex development in single-domain grains and addition or remobilization of domain walls at high T in multidomain grains. During cooling of a rock, iron minerals might then denucleate domains or vortices. Coercive force Hc, a measure of stability against changing magnetic fields, also decreases with increasing measurement T, usually at a rate similar to that of Mrs, but often retains a finite value near the Curie point.
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- Award ID(s):
- 1642268
- NSF-PAR ID:
- 10318866
- Date Published:
- Journal Name:
- Geophysical Journal International
- Volume:
- 225
- Issue:
- 1
- ISSN:
- 0956-540X
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract Natural materials contain small grains of magnetic iron oxides that can record information about the magnetic field of the Earth when they form and can be used to document changes in the geomagnetic field through time. Thermoremanent magnetization is the most stable type of remanent magnetization in igneous rocks and can be carried by particle sizes above the upper size limit for single‐domain behavior. To better understand thermoremanent magnetization in particles larger than single domain, we imaged the thermal dependence of magnetic structures in ~1.5‐μm grains of titanomagnetite (Fe2.46Ti0.54O4) using variable‐temperature magnetic force microscopy. At room temperature, grains displayed single‐vortex and multivortex states. Upon heating, the single‐vortex state was found to be stable up to the Curie temperature (~215 °C), whereas multivortex states unblocked between 125 and 200 °C by transitioning into single‐vortex states. During cooling in a weak field (~0.1 mT), single‐vortex states nucleated just below the Curie temperature and remained unchanged to room temperature. The single‐vortex state was the only magnetic state observed at room temperature after weak field thermoremanent magnetization acquisition experiments. These observations indicate that single‐vortex states occur in titanomagnetite and, like single‐domain particles, have high thermal stability necessary for carrying stable paleomagnetic remanence.
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1093/gji/ggaa569
