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Title: Electrocatalytic reduction of nitrate by in situ generated cobalt nanoparticles
The cobalt pyridinophane complex [Co( H N4)Cl 2 ] + ( H N4 = 3,7-diaza-1,5(2,6)-dipyridinacyclooctaphane) is converted under catalytic conditions to an electrode-adsorbed species. Aqueous Co 2+ solutions similarly deposit a species under these conditions. Surface characterization reveals the formation of Co nanoparticles. These nanoparticles are active in the electrocatalytic redution of aqueous nitrate.  more » « less
Award ID(s):
2102442
NSF-PAR ID:
10320057
Author(s) / Creator(s):
; ;
Date Published:
Journal Name:
Chemical Communications
ISSN:
1359-7345
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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