Abstract Understanding the mineralogy of the Earth's interior is a prerequisite for unravelling the evolution and dynamics of our planet. Here, we conducted high pressure-temperature experiments mimicking the conditions of the deep lower mantle (DLM, 1800–2890 km in depth) and observed surprising mineralogical transformations in the presence of water. Ferropericlase, (Mg, Fe)O, which is the most abundant oxide mineral in Earth, reacts with H2O to form a previously unknown (Mg, Fe)O2Hx (x≤1) phase. The (Mg, Fe)O2Hx has the pyrite structure and it coexists with the dominant silicate phases, bridgmanite and post-perovskite. Depending on Mg content and geotherm temperatures, the transformation may occur at 1800 km for (Mg0.6Fe0.4)O or beyond 2300 km for (Mg0.7Fe0.3)O. The (Mg, Fe)O2Hx is an oxygen excess phase that stores an excessive amount of oxygen beyond the charge balance of maximum cation valences (Mg2+, Fe3+, and H+). This important phase has a number of far-reaching implications including the extreme redox inhomogeneity, deep-oxygen reservoirs in the DLM, and an internal source for modulating oxygen in the atmosphere. 
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                            Lower mantle geotherms, flux, and power from incorporating new experimental and theoretical constraints on heat transport properties in an inverse model
                        
                    
    
            Abstract. An inverse method is devised to probe Earth's thermalstate without assuming its mineralogy. This constrains thermal conductivity(κ) in the lower mantle (LM) by combining seismologic models of bulkmodulus (B) and pressure (P) vs. depth (z) with a new result, ∂ln(κ) / ∂P ∼ 7.33/BT, and available high temperature (T) data onκ for lengths exceeding millimeters. Considering large samples accounts forthe recently revealed dependence of heat transport properties onlength scale. Applying separation of variables to seismologic ∂B/∂P vs. depth isolates changes with T. The resulting LM dT / dz dependson ∂2B/∂P2 and ∂B/∂T, whichvary little among dense phases. Because seismic ∂B/∂P isdiscontinuous and model dependent ∼ 200 km above the core,unlike the LM, our results are extrapolated through this tiny layer (D′′).Flux and power are calculated from dT / dz for cases of high (oxide) and low(silicate) κ. Geotherm calculations are independent of κ,and thus of LM mineralogy, but require specifying a reference temperature atsome depth: a wide range is considered. Limitations on deep melting are usedto ascertain which of our geotherm, flux, and power curves best representEarth's interior. Except for an oxide composition with miniscule ∂2B/∂P2, the LM heats the core, causing it to melt. Deepheating is attributed to cyclical stresses from > 1000 km dailyand monthly fluctuations of the barycenter inside the LM. 
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                            - Award ID(s):
- 2122296
- PAR ID:
- 10322114
- Date Published:
- Journal Name:
- European Journal of Mineralogy
- Volume:
- 34
- Issue:
- 1
- ISSN:
- 1617-4011
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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