During International Ocean Discovery Program (IODP) Expedition 367/368/368X, Holes U1504A and U1504B were cored on the continental shelf (2817–2843 meters below sea level) in the northern South China Sea (SCS). A total of 106 m of metamorphic basement was penetrated that consists of greenish gray, deformed mylonitic, epidote-chlorite to calc-silicate schists containing granofels clasts ("greenschist"). Here we report bulk-rock major and trace element data from 17 greenschist samples, from which a subset of 9 samples was additionally analyzed for Pb-Nd-Hf isotope ratios. Fluid-mobile elements (U, Li, Rb, K, and Cs) behave somewhat erratically, yet tectonic discrimination and primitive mantle–normalized multielement diagrams reveal signatures that are typical for enriched intraplate basalts. These include a negative Pb anomaly (Ce/Pb = 34 ± 10), relative enrichments of Nb and Ta (Nb/La = 1.5 ± 0.3; Th/Nb = 0.07 ± 0.01), and a steep rare earth element pattern (La/Sm = 3.7 ± 0.7; Ho/Lu = 2.9 ± 0.2). The high values of the uranogenic 206Pb/204Pb (21.2–25.9) and 207Pb/204Pb (15.7–16.0) and their strong correlation point to a postformation "U addition event" that took place at 329 Ma ± 2 My (late Carboniferous). 143Nd/144Nd and 176Hf/177Hf data are consistent with the origin from an enriched Paleozoic age mantle source. In summary, our data suggest that the protolith of the Site U1504 metamorphic basement was an ocean-island basalt–type igneous rock that deformed during the late Paleozoic and was part of the prerift crustal basement of the SCS Basin.
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Data report: major and trace element and Sr-Nd-Pb-Hf isotope composition of three granite clasts from Hole U1501D in the South China Sea (IODP Expedition 367/368/368X)
During International Ocean Discovery Program Expeditions 367/368/368X, Hole U1501D was cored on the continental shelf (2846 meters below sea level) in the northern South China Sea (SCS). In Hole U1501D, sediments were recovered from 433.5 to 644.3 meters below seafloor (mbsf) and the acoustic basement was penetrated at 598.91 mbsf. The acoustic basement is a stratigraphic boundary at which late Eocene Cenozoic sediments likely unconformably overlay heterolithic Mesozoic sandstones that are intercalated with rare siltstones and subordinate conglomerate with pebble- and cobble-sized igneous clasts of proximal provenance. Here, we present major and trace elements and Sr-Nd-Pb-Hf isotope data of a fine-grained granite pebble, a medium-grained granite cobble, and a porphyritic volcanic pebble. The data show that these clasts are relics of the Mesozoic subduction-related magmatism that was active along the southeast Asian margin prior to the Cenozoic rifting. The Pb isotope composition of the clasts partially overlaps with the enriched Cenozoic mid-ocean-ridge basalt type and intraplate basalts of the SCS. However, the clasts are distinct from the Cenozoic basalt volcanism in Sr-Nd-Hf isotope space. Thus, Sr-Nd-Hf isotope systematics of the Cenozoic basalts might be useful in detecting traces of crustal contamination in the earliest rift basalts of the SCS that may have erupted through the Mesozoic continental basement.
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- Award ID(s):
- 1326927
- NSF-PAR ID:
- 10323132
- Date Published:
- Journal Name:
- Proceedings of the International Ocean Discovery Program
- Volume:
- 367/368
- ISSN:
- 2377-3189
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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null (Ed.)The primary objectives of International Ocean Discovery Program (IODP) Expedition 367/368 to the northern South China Sea (SCS) margin were to (1) examine its history of continental breakup and (2) compare it with other nonvolcanic or magma-poor rifted margins with the broader goal of testing models for continental breakup. A secondary objective was to further our understanding of the paleoceanographic and environmental development of the SCS and southeast Asia during the Cenozoic. Four primary sites were selected for the overall program: one in the outer margin high (OMH) and three seaward of the OMH on distinct, margin-parallel basement ridges. These three ridges are informally labeled A, B, and C and are located in the continent–ocean transition (COT) zone ranging from the OMH to the interpreted steady-state oceanic crust (Ridge C) of the SCS. The main scientific objectives include the following: Determining the nature of the basement in crustal units across the COT of the SCS that are critical to constrain style of rifting, Constraining the time interval from initial crustal extension and plate rupture to the initial generation of igneous ocean crust, Constraining vertical crustal movements during breakup, and Examining the nature of igneous activity from rifting to seafloor spreading. In addition, the sediment cores from the drill sites targeting primarily tectonic and basement objectives will provide information on the Cenozoic regional environmental development of the Southeast Asia margin. Site U1499 on Ridge A and Site U1500 on Ridge B were drilled during Expedition 367. Expedition 368 was planned to drill at two primary sites (U1501 and U1503) at the OMH and Ridge C, respectively, but based on drilling results from Expedition 367, Expedition 368 chose to insert an alternate site on Ridge A (Site U1502). In addition, Expedition 368 added two more sites on the OMH (Sites U1504 and U1505). Expedition 367/368 completed operations at six of the seven sites (U1499–U1502, U1504, and U1505). Site U1503, however, was not completed beyond casing without coring to 990 m because of mechanical problems with the drilling equipment that prevented the expedition, after 25 May 2017, from operating with a drill string longer than 3400 m. New alternate Site U1504, proposed during Expedition 367, met this condition. Original Site U1505 also met the operational constraints of the 3400 m drill string (total) and was an alternate site for the already-drilled Site U1501. At Site U1499, we cored to 1081.8 m in 22.1 days with 52% recovery and then logged downhole data from 655 to 1020 m. In 31 days at Site U1500, we penetrated to 1529 m, cored a total of 1012.8 m with 37% recovery, and collected log data from 842 to 1133 m. At Site U1501, we cored to 697.1 m in 9.4 days with 78.5% recovery. We also drilled ahead for 433.5 m in Hole U1501D and then logged downhole data from 78.3 to 399.3 m. In 19.3 days at Site U1502, we penetrated 1679.0 m in Holes U1502A (758 m) and U1502B (921 m), set 723.7 m of casing and cored a total of 576.3 m with 53.5% recovery, and collected downhole log data from 785.3 to 875.3 m and seismic data through the 10¾ inch casing. At Site U1503, we penetrated 995.1 m and set 991.5 m of 10¾ inch casing, but no cores were taken because of a mechanical problem with the drawworks. At Site U1504, we took 40 rotary core barrel (RCB) cores over two holes. The cored interval between both holes was 277.3 m with 26.8% recovery. An 88.2 m interval was drilled in Hole U1504B. At Site U1505, we cored 668.0 m with 101.1% recovery. Logging data was collected from 80.1 to 341.2 m. Operations at this site covered 6.1 days. Except for Sites U1503 and U1505, all sites were drilled to acoustic basement. A total of 6.65 days were lost due to mechanical breakdown or waiting on spare supplies for repair of drilling equipment, but drilling options were severely limited from 25 May to the end of the expedition by the defective drawworks limiting deployment of drill string longer than 3400 m. At Site U1499, coring ~200 m into the interpreted acoustic basement sampled sedimentary rocks, possibly including early Miocene chalks underlain by Oligocene polymict breccias and poorly cemented gravels of unknown age comprising sandstone pebbles and cobbles. Preliminary structural and lithologic analysis suggests that the gravels might be early to late synrift sediment. At Site U1500, the main seismic reflector corresponds to the top of a basalt sequence at ~1379.1 m. We cored 149.90 m into this volcanic package and recovered 114.92 m (77%) of sparsely to moderately plagioclase-phyric basalt comprising numerous lava flows, including pillow lavas with glass, chilled margins, altered veins, hyaloclastites, and minor sediment. Preliminary geochemical analyses indicate that the basalt is tholeiitic. Sampling of the Pleistocene to lower Miocene sedimentary section at Sites U1499 and U1500 was not continuous for two reasons. First, there was extremely poor recovery in substantial intervals interpreted to be poorly lithified sands, possibly turbidites. Second, we chose to drill down without coring in some sections at Site U1500 to ensure sufficient time to achieve this site’s high-priority deep drilling objectives. The upper Miocene basin sequence, which consists of interbedded claystone, siltstone, and sandstone can be correlated between the two sites by seismic stratigraphic mapping and biostratigraphy. At Site U1501 on the OMH, coring ~45 m into the acoustic basement sampled prerift(?) deposits comprising sandstone to conglomerate of presumed Mesozoic age. These deposits are overlain by siliciclastic synrift sediments of Eocene to Oligocene age followed by primarily carbonaceous postrift sediments of early Miocene to Pleistocene age. Site U1502 on Ridge A was cased to 723.7 m. No coring was attempted shallower than 380 m to save operational time and because of low expectations for core recovery in the upper Plio–Pleistocene sequence. At this site, we recovered 180 m of hydrothermally altered brecciated basalts comprising sheet and pillow lavas below deep-marine sediments of Oligocene to late Miocene age. At Site U1503 on Ridge C, 991.5 m of casing was installed in preparation for the planned deep drilling to ~1800 m. No coring was performed due to mechanical failures, and the site was abandoned without further activity except for installation of a reentry cone. Coring at Site U1504 on the OMH, located ~45 km east of Site U1501, recovered mostly foliated, greenschist facies metamorphic rocks below late Eocene(?) carbonate rocks (partly reef debris) and early Miocene to Pleistocene sediments. At Site U1505, we cored to 480.15 m through Pleistocene to late Oligocene mainly carbonaceous ooze followed at depth by early Oligocene siliciclastic sediments. Efforts were made at every drill site to correlate the core with the seismic data and seismic stratigraphic unconformities interpreted in the Eocene to Plio–Pleistocene sedimentary sequence prior to drilling. The predrilling interpretation of ages of these unconformities was in general confirmed by drilling results, although some nontrivial corrections can be expected from detailed postexpedition work on integrating seismic stratigraphic interpretations with detailed bio- and lithostratigraphy. As a result of the limited length of drill string that could be deployed during the later part of Expedition 368, the secondary expedition objectives addressing the environmental history of the SCS and Southeast Asia received more focus than originally planned, allowing Site U1505 (alternate to Site U1501) to be included. Despite this change in focus, Expedition 367/368 provided solid evidence for a process of breakup that included vigorous synrift magmatism as opposed to the often-favored interpretation of the SCS margin as a magma-starved margin or a margin possibly overprinted at a much later stage by plume-related magmatism. In this broader perspective, Expedition 367/368 accomplished a fundamental objective of the two-expedition science program.more » « less
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Fresh samples of basalts were collected by dredging from the Nanyue intraplate seamount in the Southwest sub-basin of the South China Sea (SCS). These are alkali basalts displaying right-sloping, chondrite-normalized rare earth element (REE) profiles. The investigated basalts are characterized by low Os content (60.37–85.13 ppt) and radiogenic 187Os/188Os ratios (~0.19 to 0.21). Furthermore, 40Ar/39Ar dating of the Nanyue basalts showed they formed during the Tortonian (~8.3 Ma) and, thus, are products of (Late Cenozoic) post-spreading volcanism. The Sr–Nd–Pb–Hf isotopic compositions of the Nanyue basalts indicate that their parental melts were derived from an upper mantle reservoir possessing the so-called Dupal isotopic anomaly. Semiquantitative isotopic modeling demonstrates that the isotopic compositions of the Nanyue basalts can be reproduced by mixing three components: the average Pacific midocean ridge basalt (MORB), the lower continental crust (LCC), and the average Hainan ocean island basalt (OIB). Our preferred hypothesis for the genesis of the Nanyue basalts is that their parental magmas were produced from an originally depleted mantle (DM) source that was much affected by the activity of the Hainan plume. Initially, the Hainan diapir caused a thermal perturbation in the upper mantle under the present-day Southwest sub-basin of the SCS that led to erosion of the overlying LCC. Eventually, the resultant suboceanic lithospheric mantle (SOLM) interacted with OIB-type components derived from the nearby Hainan plume. Collectively, these processes contributed crustal- and plume-type components to the upper mantle underlying the Southwest sub-basin of the SCS. This implies that the Dupal isotopic signature in the upper mantle beneath the SCS was an artifact of in situ geological processes rather than a feature inherited from a Southern Hemispheric, upper mantle source.more » « less
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null (Ed.)International Ocean Discovery Program Expedition 368 is the second of two consecutive cruises that form the South China Sea Rifted Margin program. Expeditions 367 and 368 share the common key objectives of testing scientific hypotheses of breakup of the northern South China Sea (SCS) margin and comparing its rifting style and history to other nonvolcanic or magma-poor rifted margins. Four primary sites were selected for the overall program: one in the outer margin high (OMH) and three seaward of the OMH on distinct, margin-parallel basement ridges. These three ridges are informally labeled A, B, and C. They are located within the continent–ocean transition (COT) zone ranging from the OMH to the interpreted steady-state oceanic crust (Ridge C) of the SCS. The main scientific objectives include 1. Determining the nature of the basement within crustal units across the COT of the SCS that are critical to constrain style of rifting, 2. Constraining the time interval from initial crustal extension and plate rupture to the initial generation of igneous ocean crust, 3. Constraining vertical crustal movements during breakup, and 4. Examining the nature of igneous activity from rifting to seafloor spreading. In addition, the sediment cores from the drill sites targeting primarily tectonic and basement objectives will provide information on the Cenozoic regional environmental development of the Southeast Asia margin. Expedition 368 was planned to drill at two primary sites (U1501 and U1503) at the OMH and Ridge C, respectively. However, based on drilling results from Expedition 367, Expedition 368 chose to insert an alternate site on Ridge A (Site U1502). In total, the expedition completed operations at four sites (U1501, U1502, U1504, and U1505). Site U1503, however, was not completed beyond casing to 990 m because of mechanical problems with the drilling equipment that limited the expedition from 25 May 2017 to the end of the expedition to operate with a drill string not longer than 3400 m. New alternate Site U1504 proposed during Expedition 367 met this condition. Site U1505 also met the operational constraints of the 3400 m drill string (total) and was an alternate site for the already drilled Site U1501. At Site U1501, we cored to 697.1 m in 9.4 days, with 78.5% recovery. We also drilled ahead for 433.5 m in Hole U1501D and then logged downhole data from 78.3 to 399.3 m. In 19.3 days at Site U1502, we penetrated 1679.0 m, set 723.7 m of casing and cored a total of 576.3 m with 53.5% recovery, and collected downhole log data from 785.3 to 875.3 m and seismic data through the 10¾ inch casing. At Site U1503, we penetrated 995.1 m, setting 991.5 m of 10¾ inch casing, but no cores were taken. At Site U1504, we took 40 rotary core barrel (RCB) cores over two holes. The cored interval between both holes was 277.3 m with 26.8% recovery. An 88.2 m interval was drilled in Hole U1504B. At Site U1505, we cored 668.0 m with 101.1% recovery. Logging data was collected from 80.1 to 341.2 m. Operations at this site covered 6.1 days. Except for Site U1505, we drilled to acoustic basement, which prior to the expedition, except for Site U1501, had been interpreted to be crystalline basement. A total of 6.65 days were lost due to mechanical breakdown or waiting on spare supplies for repair of drilling equipment. At Site U1501 on the OMH, coring ~45 m into the acoustic basement sampled highly lithified sandstone to conglomerate of presumed Mesozoic age overlain by siliciclastic Eocene pre- to synrift sediments of Oligocene age and topped by primarily carbonaceous postrift sediments of early Miocene to Pleistocene age. Site U1502 on Ridge A was cased to 723.7 m. At this site, we recovered 180 m of hydrothermally altered brecciated basalts comprising sheet and pillow lavas below deep-marine sediments of Oligocene to late Miocene age. Coring was not performed within the upper 380 m (~Pliocene–Pleistocene) at Site U1502. At Site U1503 on Ridge C, 991.5 m of casing was installed in preparation for the planned deep drilling to ~1800 m, but no coring was performed due to mechanical failures, and the site was abandoned without further activity. Coring at Site U1504 on the OMH ~45 km east of Site U1501 recovered metamorphic schist to gneiss (greenschist facies) below late Eocene (?) carbonate rocks (partly reef debris) and early Miocene to Pleistocene sediments. At Site U1505, we cored to 480.15 m through Pleistocene to late Oligocene mainly carbonaceous ooze followed at depth by early Oligocene to late Eocene siliciclastic sediments. Efforts were made at every drill site to correlate the core with the seismic data and seismic stratigraphic unconformities interpreted within the Eocene to Plio–Pleistocene sedimentary sequence prior to drilling. The predrilling interpretation of ages of these unconformities was in general confirmed by drilling results. As a result of the constraints on the length of drill string that could be deployed during the later part of Expedition 368, the secondary expedition objectives addressing the environmental history of the SCS and Southeast Asia received more focus than planned because these sites are located in shallower water depths and required less penetration depth. This forced change in emphasis, however, was without fatal consequences for the primary tectonic objectives. The two expeditions together provided solid evidence for a process of breakup that included vigorous synrift magmatism as opposed to the often-favored interpretation of the SCS margin as a magma-starved margin.more » « less
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IODP Expedition 379 to the Amundsen Sea continental rise recovered latest Miocene-Holocene sediments from two sites on a drift in water depths >3900m. Sediments are dominated by clay and silty clay with coarser-grained intervals and ice-rafted detritus (IRD) (Gohl et al. 2021, doi:10.14379/iodp.proc.379.2021). Cobble-sized dropstones appear as fall-in, in cores recovered from sediments >5.3 Ma. We consider that abundant IRD and the sparse dropstones melted out of icebergs formed due to Antarctic ice-sheet calving events. We are using petrological and age characteristics of the clasts from the Exp379 sites to fingerprint their bedrock provenance. The results may aid in reconstruction of past changes in icesheet extent and extend knowledge of subglacial bedrock. Mapped onshore geology shows pronounced distinctions in bedrock age between tectonic provinces of West or East Antarctica (e.g. Cox et al. 2020, doi:10.21420/7SH7-6K05; Jordan et al. 2020, doi.org/10.1038/s43017-019-0013-6). This allows us to use geochronology and thermochronology of rock clasts and minerals for tracing their provenance, and ascertain whether IRD deposited at IODP379 drillsites originated from proximal or distal Antarctic sources. We here report zircon and apatite U-Pb dates from four sand samples and five dropstones taken from latest Miocene, early Pliocene, and Plio-Pleistocene-boundary sediments. Additional Hf isotope data, and apatite fission track and 40Ar/39Ar Kfeldspar ages for some of the same samples help to strengthen provenance interpretations. The study revealed three distinct zircon age populations at ca. 100, 175, and 250 Ma. Using Kolmogorov-Smirnov (K-S) statistical tests to compare our new igneous and detrital zircon (DZ) U-Pb results with previously published data, we found strong similarities to West Antarctic bedrock, but low correspondence to prospective sources in East Antarctica, implying a role for icebergs calved from the West Antarctic Ice Sheet (WAIS). The ~100 Ma age resembles plutonic ages from Marie Byrd Land and islands in Pine Island Bay. The ~250 and 175 Ma populations match published mineral dates from shelf sediments in the eastern Amundsen Sea Embayment as well as granite ages from the Antarctic Peninsula and the Ellsworth-Whitmore Mountains (EWM). The different derivation of coarse sediment sources requires changes in iceberg origin through the latest Miocene, early Pliocene, and Plio/Pleistocene, likely the result of changes in WAIS extent. One unique dropstone recovered from Exp379 Site U1533B is green quartz arenite, which yielded mostly 500-625 Ma detrital zircons. In visual appearance and dominant U-Pb age population, it resembles a sandstone dropstone recovered from Exp382 Site U1536 in the Scotia Sea (Hemming et al. 2020, https://gsa.confex.com/gsa/2020AM/meetingapp.cgi/Paper/357276). K-S tests yield high values (P ≥ 0.6), suggesting a common provenance for both dropstones recovered from late Miocene to Pliocene sediments, despite the 3270 km distance separating the sites. Comparisons to published data, in progress, narrow the group of potential on-land sources to exposures in the EWM or isolated ranges at far south latitudes in the Antarctic interior. If both dropstones originated from the same source area, they could signify dramatic shifts in the WAIS grounding line position, and the possibility of the periodic opening of a seaway connecting the Amundsen and Weddell Seas. https://meetingorganizer.copernicus.org/EGU21/EGU21-9151.htmlmore » « less
- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.14379/iodp.proc.367368.202.2022
