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1. Data report: major and trace element and Sr-Nd-Pb-Hf isotope composition of three granite clasts from Hole U1501D in the South China Sea (IODP Expedition 367/368/368X)

   https://doi.org/10.14379/iodp.proc.367368.202.2022  

   Straub, S.M.; Gomez-Tuena, A.; Dorais, M.J. (April 2022, Proceedings of the International Ocean Discovery Program)

   During International Ocean Discovery Program Expeditions 367/368/368X, Hole U1501D was cored on the continental shelf (2846 meters below sea level) in the northern South China Sea (SCS). In Hole U1501D, sediments were recovered from 433.5 to 644.3 meters below seafloor (mbsf) and the acoustic basement was penetrated at 598.91 mbsf. The acoustic basement is a stratigraphic boundary at which late Eocene Cenozoic sediments likely unconformably overlay heterolithic Mesozoic sandstones that are intercalated with rare siltstones and subordinate conglomerate with pebble- and cobble-sized igneous clasts of proximal provenance. Here, we present major and trace elements and Sr-Nd-Pb-Hf isotope data of a fine-grained granite pebble, a medium-grained granite cobble, and a porphyritic volcanic pebble. The data show that these clasts are relics of the Mesozoic subduction-related magmatism that was active along the southeast Asian margin prior to the Cenozoic rifting. The Pb isotope composition of the clasts partially overlaps with the enriched Cenozoic mid-ocean-ridge basalt type and intraplate basalts of the SCS. However, the clasts are distinct from the Cenozoic basalt volcanism in Sr-Nd-Hf isotope space. Thus, Sr-Nd-Hf isotope systematics of the Cenozoic basalts might be useful in detecting traces of crustal contamination in the earliest rift basalts of the SCS that may have erupted through the Mesozoic continental basement. 

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2. Exhumed Serpentinites and Their Tectonic Significance in Non-Collisional Orogens

   Donoso-Tapia, Damián; Flores, Kennet E; Martin, Celine; Gazel, Esteban; Marsh, Jeffrey (February 2024, Geochemistry geophysics geosystems)

   Exhumed serpentinites are fragments of ancient oceanic lithosphere or mantle wedge that record deep fluid-rock interactions and metasomatic processes. While common in suture zones after closure of ocean basins, in non-collisional orogens their origin and tectonic significance are not fully understood. We study serpentinite samples from five river basins in a segment of the non-collisional Andean orogen in Ecuador (Cordillera Real). All samples are fully serpentinized with antigorite as the main polymorph, while spinel is the only relic phase. Watershed delineation analysis and in-situ B isotope data suggest four serpentinite sources, linked to mantle wedge (δ11B = ∼−10.6 to −0.03‰) and obducted ophiolite (δ11B = −2.51 to +5.73‰) bodies, likely associated with Triassic, Jurassic-Early Cretaceous, and potentially Late Cretaceous-Paleocene high-pressure (HP)–low-temperature metamorphic sequences. Whole-rock trace element data and in-situ B isotopes favor serpentinization by a crust-derived metamorphic fluid. Thermodynamic modeling in two samples suggests serpentinization at ∼550–500°C and pressures from 2.5 to 2.2 GPa and 1.0–0.6 GPa for two localities. Both samples record a subsequent overprint at ∼1.5–0.5 GPa and 680–660°C. In the Andes, regional phases of slab rollback have been reported since the mid-Paleozoic to Late Cretaceous. This tectonic scenario favors the extrusion of HP rocks into the forearc and the opening of back-arc basins. Subsequent compressional phases trigger short-lived subduction in the back-arc that culminates with ophiolite obduction and associated metamorphic rock exhumation. Thus, we propose that serpentinites in non-collisional orogens are sourced from extruded slivers of mantle wedge in the forearc or obducted ophiolite sequences associated with regional back-arc basins. 

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3. Exhumed Serpentinites and Their Tectonic Significance in Non-Collisional Orogens

   Donoso-Tapia, Damián; Flores, Kennet E; Martin, Celine; Gazel, Esteban; Marsh, Jeffrey (February 2024, Geochemistry geophysics geosystems)

   Exhumed serpentinites are fragments of ancient oceanic lithosphere or mantle wedge that record deep fluid-rock interactions and metasomatic processes. While common in suture zones after closure of ocean basins, in non-collisional orogens their origin and tectonic significance are not fully understood. We study serpentinite samples from five river basins in a segment of the non-collisional Andean orogen in Ecuador (Cordillera Real). All samples are fully serpentinized with antigorite as the main polymorph, while spinel is the only relic phase. Watershed delineation analysis and in-situ B isotope data suggest four serpentinite sources, linked to mantle wedge (δ11B = ∼−10.6 to −0.03‰) and obducted ophiolite (δ11B = −2.51 to +5.73‰) bodies, likely associated with Triassic, Jurassic-Early Cretaceous, and potentially Late Cretaceous-Paleocene high-pressure (HP)–low-temperature metamorphic sequences. Whole-rock trace element data and in-situ B isotopes favor serpentinization by a crust-derived metamorphic fluid. Thermodynamic modeling in two samples suggests serpentinization at ∼550–500°C and pressures from 2.5 to 2.2 GPa and 1.0–0.6 GPa for two localities. Both samples record a subsequent overprint at ∼1.5–0.5 GPa and 680–660°C. In the Andes, regional phases of slab rollback have been reported since the mid-Paleozoic to Late Cretaceous. This tectonic scenario favors the extrusion of HP rocks into the forearc and the opening of back-arc basins. Subsequent compressional phases trigger short-lived subduction in the back-arc that culminates with ophiolite obduction and associated metamorphic rock exhumation. Thus, we propose that serpentinites in non-collisional orogens are sourced from extruded slivers of mantle wedge in the forearc or obducted ophiolite sequences associated with regional back-arc basins. 

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4. Exhumed Serpentinites and Their Tectonic Significance in Non‐Collisional Orogens

   https://doi.org/10.1029/2023GC011072  

   Donoso‐Tapia, Damián; Flores, Kennet E; Martin, Celine; Gazel, Esteban; Marsh, Jeffrey (February 2024, Geochemistry, Geophysics, Geosystems)

   Abstract Exhumed serpentinites are fragments of ancient oceanic lithosphere or mantle wedge that record deep fluid‐rock interactions and metasomatic processes. While common in suture zones after closure of ocean basins, in non‐collisional orogens their origin and tectonic significance are not fully understood. We study serpentinite samples from five river basins in a segment of the non‐collisional Andean orogen in Ecuador (Cordillera Real). All samples are fully serpentinized with antigorite as the main polymorph, while spinel is the only relic phase. Watershed delineation analysis and in‐situ B isotope data suggest four serpentinite sources, linked to mantle wedge (δ¹¹B = ∼−10.6 to −0.03‰) and obducted ophiolite (δ¹¹B = −2.51 to +5.73‰) bodies, likely associated with Triassic, Jurassic‐Early Cretaceous, and potentially Late Cretaceous‐Paleocene high‐pressure (HP)–low‐temperature metamorphic sequences. Whole‐rock trace element data and in‐situ B isotopes favor serpentinization by a crust‐derived metamorphic fluid. Thermodynamic modeling in two samples suggests serpentinization at ∼550–500°C and pressures from 2.5 to 2.2 GPa and 1.0–0.6 GPa for two localities. Both samples record a subsequent overprint at ∼1.5–0.5 GPa and 680–660°C. In the Andes, regional phases of slab rollback have been reported since the mid‐Paleozoic to Late Cretaceous. This tectonic scenario favors the extrusion of HP rocks into the forearc and the opening of back‐arc basins. Subsequent compressional phases trigger short‐lived subduction in the back‐arc that culminates with ophiolite obduction and associated metamorphic rock exhumation. Thus, we propose that serpentinites in non‐collisional orogens are sourced from extruded slivers of mantle wedge in the forearc or obducted ophiolite sequences associated with regional back‐arc basins. 

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5. Tyrrhenian Continent–Ocean Transition

   https://doi.org/10.14379/iodp.proc.402.2025  

   Zitellini, N; Malinverno, A; Estes, ER (April 2025, International Ocean Discovery Program)

   In the classical view of tectonic rifting, divergent lithospheric plates cause the asthenospheric mantle to ascend, decompress, and melt, eventually producing new magmatic crust. This view has been updated by drilling results that found exhumed mantle at the continent–ocean transition (COT), leading to the definition of magma-poor rifted margins. Obtaining geologic samples from COTs to directly constrain the diversity of rifting processes is a challenge because the igneous crust and mantle rocks are typically buried under a thick sediment cover. The Tyrrhenian Sea provides an optimal location to test COT formation models by drilling because it has a comparatively thin sediment cover, allows for studying a conjugate pair of COT margins in a single drilling expedition, and has been mapped in unprecedented detail with recent geophysical measurements. The key objective of International Ocean Discovery Program Expedition 402 was to determine the nature of the geologic basement in the central Vavilov Basin, where exhumed mantle peridotites were expected, and in the conjugate margins to the west (Cornaglia Terrace) and east (Campania Terrace). In the Vavilov Basin, Sites U1614 and U1616 recovered an exceptional variety of mantle rocks, including lherzolites, harzburgites, plagioclase-bearing lherzolites and harzburgites, dunites, and minor amounts of pyroxenites and magmatic intrusions. The mantle peridotites are significantly hydrated and weathered, resulting in the formation of serpentine and carbonate veins. In contrast, Site U1612 recovered at the sediment/basement interface an unconsolidated breccia with clasts of basalt, peridotite, and granite, followed by variably deformed mylonitic gneisses that transition downhole to granitoid quartz-diorite rocks. On the western Tyrrhenian margin (Cornaglia Terrace), Site U1613 sampled a sediment sequence dating back to the Messinian (Late Miocene), resting on much older sedimentary rocks akin to the Triassic–Paleozoic successions outcropping in Sardinia, supporting the hypothesis that the margin consists of extended continental crust. On the conjugate margin to the east (Campania Terrace), Site U1617 did not reach the basement but recovered a complete sequence of Messinian evaporites, including halite. The samples and data collected during Expedition 402 provide an extensive new data set to determine the heterogeneity of the mantle, the nature and history of melt production and impregnation, and the extent and evolution of mantle serpentinization and carbonation; to constrain the geometry and timing of the deformation that led to mantle exhumation; to study the fluid-rock interactions between seawater, sediment, and mantle peridotites; and to constrain geodynamic models of rifting and COT formation. 

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